bis(2-mercaptobenzene)dimethylsilane | 117526-69-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: bis(2-mercaptobenzene)dimethylsilane
• 英文别名: bis(2-mercaptophenyl)dimethylsilane；2-[Dimethyl-(2-sulfanylphenyl)silyl]benzenethiol
• CAS: 117526-69-9
• 化学式: C₁₄H₁₆S₂Si
• 分子量: 276.499
• InChiKey: OPDYOJOLRCBQOQ-UHFFFAOYSA-N

物化性质

• 沸点：
  360.6±42.0 °C(Predicted)
• 密度：
  1.12±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.09
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(2-mercaptobenzene)dimethylsilane 在 二甲基亚砜 作用下， 反应 20.0h， 以91%的产率得到11,11-dimethyl-11H-dibenzo<1,2,5>dithiasilepin
  参考文献：
  名称：

  o-Lithiothiophenol equivalents. Generation, reactions and applications in synthesis of hindered thiolate ligands

  摘要：

  DOI：

  10.1021/ja00184a039
• 作为产物：
  描述：

  苯硫酚 、 二氯二甲基硅烷 在 正丁基锂 作用下， 生成 bis(2-mercaptobenzene)dimethylsilane
  参考文献：
  名称：

  o-Lithiothiophenol equivalents. Generation, reactions and applications in synthesis of hindered thiolate ligands

  摘要：

  DOI：

  10.1021/ja00184a039

文献信息

• Block, Eric; Brito, Maria; Gernon, Michael, Inorganic Chemistry, 1990, vol. 29, # 17, p. 3172 - 3181
  作者：Block, Eric、Brito, Maria、Gernon, Michael、McGowty, Deborah、Kang, Hyunkyu、Zubieta, Jon

  DOI：——

  日期：——
• Syntheses and structures of transition metal thiolate complexes containing the new bis(tetramethylguanidine) ligand btmgp
  作者：Siegfried Pohl、Michael Harmjanz、Jörg Schneider、Wolfgang Saak、Gerald Henkel

  DOI：10.1016/s0020-1693(00)00310-8

  日期：2000.12

  Phe syntheses. spectroscopic and structural characterizations of the first iron and copper thiolate guanidine complexes are described. Reactions of the neutral complexes [Cu[(btmgp)] and [FeI2(btmgp)] [btmgp = 1,3-bis(N,N,N',N'-tetramethyl-guanidino)propane] with different uni- and bi-dentate thiolate ions yield the three-coordinate complex [Cu(S-2,4,6-(Bu3C6H2)-Bu-1)(btmgp)] (1) and the four-coordinate complexes [Fe(S-2,4,6-(Pr3C6H2)-Pr-1)(2)(btmgp)] (2) and [Fe(SiMe2(C6H4S)(2))(btmgp)] (3) respectively. Starting with [Fe(N(SiMe3)(2))(2)], btmgp and the dithiol SiMe2(C6H4SH)(2), an alternative procedure for the preparation of 3 is reported, demonstrating a useful synthetic approach towards neutral, N S mixed coordinated Fe(II) complexes. The X-ray structure analyses of 1 - 3 reveal trigonal planar (2N 1S) (1) and tetrahedral (2N 2S) (2, 3) coordination environments around the metal centers. (C) 2000 Elsevier Science B.V. All rights reserved.
• o-Lithiothiophenol equivalents. Generation, reactions and applications in synthesis of hindered thiolate ligands
  作者：Eric Block、Venkatachalam Eswarakrishnan、Michael Gernon、Gabriel Ofori-Okai、Chantu Saha、Kaluo Tang、Jon Zubieta

  DOI：10.1021/ja00184a039

  日期：1989.1