5,10-dihydro-N,N'-dimethylindolo-<3,2-b>indole | 38292-64-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5,10-dihydro-N,N'-dimethylindolo-<3,2-b>indole
• 英文别名: 5,10-dimethyl-5,10-dihydroindolo[3,2-b]indole；5,10-dimethyl-5,10-dihydro-indolo[3,2-b]indole；N,N'-Dimethyl-5,10-dihydroindolo<3,2-b>indol；5,10-Dimethylindolo[3,2-b]indole
• CAS: 38292-64-7
• 化学式: C₁₆H₁₄N₂
• 分子量: 234.301
• InChiKey: GWTYNLPRXXLYFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5,10-dihydro-N,N'-dimethylindolo-<3,2-b>indole 在 吡啶 、 溴 作用下， 以 四氯化碳 为溶剂， 反应 1.0h， 以350 mg的产率得到
  参考文献：
  名称：

  一种双吡咯衍生物及其制备方法和有机发光器件

  摘要：

  本发明提供一种双吡咯衍生物及其制备方法和有机发光器件，属于有机光电材料技术领域。本发明通过对两个吡咯与杂环进行稠合，使得到的材料具有高玻璃化转变温度并且能够防止结晶作用；合成方法简单易操作，使用该双吡咯衍生物制备的有机发光器件具有良好的发光效率和寿命表现。

  公开号：

  CN108250212A
• 作为产物：
  描述：

  2-((2-aminophenyl)ethynyl)-N,N-dimethylaniline 在 copper(II) hexafluoroacetylacetonate hydrate 、 氧气 、 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以80%的产率得到5,10-dihydro-N,N'-dimethylindolo-<3,2-b>indole
  参考文献：
  名称：

  N-甲基转移诱导的炔烃铜介导氧化氧化

  摘要：

  在Cu（hfacac）下开发了一种新颖的双（2-氨基苯基）乙炔分子内氧化加氨方法，用于合成结构吸引人的π-共轭多杂环骨架5,10-二氢吲哚[3,2- b ]吲哚（DHII）。 ）2 / O 2氧化系统。带有N，N-二甲基胺和伯胺基团的双（2-氨基苯基）乙炔的结构设计对于构建相应的DHII支架至关重要。值得注意的是，分子间ñ -甲基从氮原子转移Ñ，Ñ-将二甲胺转化为伯胺，这对于成功实施本发明的成环方法是至关重要的步骤。

  DOI：

  10.1021/acs.orglett.6b01067

文献信息

• ORGANIC OPTOELECTRIC DEVICE AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20160163995A1

  公开（公告）日：2016-06-09

  An organic optoelectric device includes an anode and a cathode facing each other, an emission layer between the anode and the cathode, a hole transport layer between the anode and the emission layer, and a hole transport auxiliary layer between the hole transport layer and the emission layer, wherein the emission layer includes at least one of a first compound including moieties represented by Chemical Formulae 1 to 3 sequentially linked and at least one of a second compound represented by Chemical Formula 4, and the hole transport auxiliary layer includes at least one of a third compound represented by Chemical Formula 5, and a display device including the organic optoelectric device is also provided.

  一种有机光电器件，包括面对彼此的阳极和阴极，发射层位于阳极和阴极之间，空穴传输层位于阳极和发射层之间，空穴传输辅助层位于空穴传输层和发射层之间，其中发射层包括至少一种第一化合物，其包括按化学式1至3依次连接的基团，以及至少一种第二化合物，其由化学式4表示，空穴传输辅助层包括至少一种由化学式5表示的第三化合物，还提供了包括该有机光电器件的显示器件。
• ORGANIC ELECTROLUMINESCENT MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：BOE Technology Group Co., Ltd.

  公开号：EP3444257A1

  公开（公告）日：2019-02-20

  The present disclosure relates to organic electroluminescent materials and organic electroluminescent devices, in particular, discloses a compound of formula (1), wherein R1, R2, R3 and R4 are each independently selected from hydrogen, a substituted or unsubstituted C1-20 alkyl, a substituted or unsubstituted C3-20 cycloalkyl, a substituted or unsubstituted aromatic hydrocarbyl, or a substituted or unsubstituted aromatic heterocyclic group; and at least one of R1, R2, R3 and R4 contains a group having a hole-transporting ability; and at least one of R1, R2, R3 and R4 contains a group having an electron-transporting ability; A and B each independently represent hydrogen, a substituted or unsubstituted, fused aromatic ring, or a substituted or unsubstituted, fused heteroaromatic ring containing a heteroatom(s) selected from O, N and S.

  本公开涉及有机电致发光材料和有机电致发光器件，尤其公开了一种式(1)化合物，其中R1、R2、R3和R4各自独立地选自氢、取代或未取代的C1-20烷基、取代或未取代的C3-20环烷基、取代或未取代的芳香烃基或取代或未取代的芳香杂环基；R1、R2、R3 和 R4 中至少有一个含有具有空穴传输能力的基团；R1、R2、R3 和 R4 中至少有一个含有具有电子传输能力的基团；A 和 B 各自独立地代表氢、取代或未取代的融合芳环或含有选自 O、N 和 S 的杂原子的取代或未取代的融合杂芳环。
• Organic electroluminescent materials and organic electroluminescent devices
  申请人：BOE TECHNOLOGY GROUP CO., LTD.

  公开号：US10886475B2

  公开（公告）日：2021-01-05

  The present disclosure relates to organic electroluminescent materials and organic electroluminescent devices, in particular, discloses a compound of formula (1), wherein R1, R2, R3 and R4 are each independently selected from hydrogen, a substituted or unsubstituted C1-20 alkyl, a substituted or unsubstituted C3-20 cycloalkyl, a substituted or unsubstituted aromatic hydrocarbyl, or a substituted or unsubstituted aromatic heterocyclic group; and at least one of R1, R2, R3 and R4 contains a group having a hole-transporting ability; and at least one of R1, R2, R3 and R4 contains a group having an electron-transporting ability; A and B each independently represent hydrogen, a substituted or unsubstituted, fused aromatic ring, or a substituted or unsubstituted, fused heteroaromatic ring containing a heteroatom(s) selected from O, N and S.

  本公开涉及有机电致发光材料和有机电致发光器件，尤其公开了一种式(1)化合物，其中R1、R2、R3和R4各自独立地选自氢、取代或未取代的C1-20烷基、取代或未取代的C3-20环烷基、取代或未取代的芳香烃基或取代或未取代的芳香杂环基；R1、R2、R3 和 R4 中至少有一个含有具有空穴传输能力的基团；R1、R2、R3 和 R4 中至少有一个含有具有电子传输能力的基团；A 和 B 各自独立地代表氢、取代或未取代的融合芳环或含有选自 O、N 和 S 的杂原子的取代或未取代的融合杂芳环。
• COMPOSITION AND ORGANIC OPTOELECTRIC DEVICE AND DISPLAY DEVICE
  申请人：MIN Soo-Hyun

  公开号：US20150001488A1

  公开（公告）日：2015-01-01

  A composition includes a first host compound including moieties represented by Chemical Formulae 1 to 3 that are sequentially bonded with each other, and a second host compound including at least one carbazole group with a substituent having hole characteristics,
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20160111663A1

  公开（公告）日：2016-04-21

  An organic light-emitting device includes a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; and a hole transport region between the first electrode and the emission layer. The emission layer includes an organometallic compound represented by Formula 1, and the hole transport region includes a first compound represented by Formula 2.