2-(4-(6-(4-nitrophenoxy)hexyloxy)styryl)pyridine | 1257420-06-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-(6-(4-nitrophenoxy)hexyloxy)styryl)pyridine
• CAS: 1257420-06-6
• 化学式: C₂₅H₂₆N₂O₄
• 分子量: 418.492
• InChiKey: UBODHRMOZLJFHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.18
• 重原子数：
  31.0
• 可旋转键数：
  12.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  74.49
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  2-(4-(6-(4-nitrophenoxy)hexyloxy)styryl)pyridine 在 氢气 作用下， 以 甲醇 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 反应 0.5h， 以80%的产率得到4-(6-(4-(2-(2-pyridinyl)vinyl)phenoxy)hexyloxy)aniline
  参考文献：
  名称：

  Comparative Syntheses of Arylamine Monomer with Styrylpyridyl Photo-Crosslinker of Polyarylamine for OLED Hole-Injection Material

  摘要：

  A new arylamine monomer with photo-crosslinkable styrylpyridinyl moiety of conjugated polyarylamine for OLED hole injection material was synthesized through two synthetic routes, BOC-amine protection/deprotection and nitro group reduction methods. Both synthetic routes yielded practically pure amine product by standard aqueous workup and crystallization in 61% overall yield from pyridinylvinylphenol 2. Their reaction efficiencies were comparatively studied in views of practicality and reaction scale. Also, the synthetic conditions of key compound of photo-crosslinker, pyridinylvinylphenol 2 was reinvestigated and established for the reproducible and reliable preparation.

  DOI：

  10.1080/15421406.2010.499316
• 作为产物：
  描述：

  对羟基苯甲醛 在 potassium carbonate 、 溶剂黄146 、 potassium hydroxide 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 56.5h， 生成 2-(4-(6-(4-nitrophenoxy)hexyloxy)styryl)pyridine
  参考文献：
  名称：

  Comparative Syntheses of Arylamine Monomer with Styrylpyridyl Photo-Crosslinker of Polyarylamine for OLED Hole-Injection Material

  摘要：

  A new arylamine monomer with photo-crosslinkable styrylpyridinyl moiety of conjugated polyarylamine for OLED hole injection material was synthesized through two synthetic routes, BOC-amine protection/deprotection and nitro group reduction methods. Both synthetic routes yielded practically pure amine product by standard aqueous workup and crystallization in 61% overall yield from pyridinylvinylphenol 2. Their reaction efficiencies were comparatively studied in views of practicality and reaction scale. Also, the synthetic conditions of key compound of photo-crosslinker, pyridinylvinylphenol 2 was reinvestigated and established for the reproducible and reliable preparation.

  DOI：

  10.1080/15421406.2010.499316