(6-乙酰基菲-3-基)乙酸酯 | 5346-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: (6-乙酰基菲-3-基)乙酸酯
• 英文名称: 1-(6-acetoxy-[3]phenanthryl)-ethanone
• 英文别名: 1-(6-Acetoxy-[3]phenanthryl)-aethanon；6-Acetylphenanthren-3-yl acetate；(6-acetylphenanthren-3-yl) acetate
• CAS: 5346-01-0
• 化学式: C₁₈H₁₄O₃
• 分子量: 278.307
• InChiKey: XKSUOAMGEJABCF-UHFFFAOYSA-N

物化性质

• 熔点：
  152-155 °C
• 沸点：
  472.6±18.0 °C(Predicted)
• 密度：
  1.226±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (6-乙酰基菲-3-基)乙酸酯 生成 1-(6-acetoxy-[3]phenanthryl)-ethanone semicarbazone
  参考文献：
  名称：

  Studies in the Phenanthrene Series. III. Hydroxy Aldehydes and Hydroxy Ketones¹

  摘要：

  DOI：

  10.1021/ja01334a062
• 作为产物：
  描述：

  3-菲醇 、 乙酰氯 在 三氯化铝 、 硝基苯 作用下， 生成 (6-乙酰基菲-3-基)乙酸酯
  参考文献：
  名称：

  Studies in the Phenanthrene Series. III. Hydroxy Aldehydes and Hydroxy Ketones¹

  摘要：

  DOI：

  10.1021/ja01334a062

文献信息

• Personality disorders and psychoses form two distinct subgroups of homicide among female offenders
  作者：Hanna Putkonen、Jutta Collander、Marja-Liisa Honkasalo、Jouko Lönnqvist

  DOI：10.1080/09585180122116

  日期：2001.1

  This study examined circumstances of homicide by women in relation to their subsequent diagnoses. We investigated the written reports of forensic psychiatric examinations on 125 Finnish women who committed murder, attempted murder, manslaughter, or attempted manslaughter during 1982-92. In 86% of the cases the victims were adults, in 15% children. Intimate partners were the victims in 54% of the cases. Stabbing was the most frequent method and a quarrel the most frequent motive. The diagnoses of personality disorders and psychoses formed distinct subgroups. Psychotic women attacked proportionally more children than the personality disordered, who mainly attacked adults. Personality disordered women were more likely to have been intoxicated with alcohol at the time. Future treatment programmes and studies are suggested.
• Studies in the Phenanthrene Series. III. Hydroxy Aldehydes and Hydroxy Ketones¹
  作者：Erich Mosettig、Alfred Burger

  DOI：10.1021/ja01334a062

  日期：1933.7
• Studies in the Phenanthrene Series. VII. 3-Hydroxyacetylphenanthrenes and Amino Ketones and Alcohols Derived from Them. Hydroxyaminophenanthrenes¹
  作者：Alfred Burger、Erich Mosettig

  DOI：10.1021/ja01323a028

  日期：1934.8