1-(2-(vinyloxy)ethyl)pyrrolidin-2-one | 86366-53-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 1-(2-(vinyloxy)ethyl)pyrrolidin-2-one
• 英文别名: 1-(2-vinyloxy-ethyl)-pyrrolidin-2-one；1-(2-Vinyloxy-aethyl)-pyrrolidin-2-on；1-(2-Vinyloxy-ethyl)-pyrrolid-2-on；1-[2-(Ethenyloxy)ethyl]pyrrolidin-2-one；1-(2-ethenoxyethyl)pyrrolidin-2-one
• CAS: 86366-53-2
• 化学式: C₈H₁₃NO₂
• 分子量: 155.197
• InChiKey: UJKDKIDWVIVAAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(2-(vinyloxy)ethyl)pyrrolidin-2-one 、 1,4-萘醌 在 Pd(opiv)2 、 silver(I) acetate 作用下， 以 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以70%的产率得到2-(2-(2-oxopyrrolidin-1-yl)ethoxy)anthracene-9,10-dione
  参考文献：
  名称：

  钯催化的烯烃直接交叉偶联取代苯环的构建：快速合成1,4-萘醌及其衍生物的途径

  摘要：

  应对变化：缺电子的1,4-苯醌或其衍生物与富电子的烷基乙烯基醚的直接交叉偶联以串联方式进行，以产生具有良好选择性和良好至极佳收率的取代苯环（请参见方案） ）。该反应具有快速合成各种取代的苯环的潜力，因为它不受取代基作用的限制。

  DOI：

  10.1002/anie.201103380
• 作为产物：
  描述：

  N-羟乙基-2-吡咯烷酮 、 乙炔 在 氢氧化钾 、 正丁醇 作用下， 生成 1-(2-(vinyloxy)ethyl)pyrrolidin-2-one
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• ULTRAVIOLET ABSORBING POLYMER, CELLULOSE ESTER OPTICAL FILM, METHOD OF PRODUCING CELLULOSE ESTER OPTICAL FILM, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：Suzuki Takayuki

  公开号：US20100104775A1

  公开（公告）日：2010-04-29

  Disclosed is an ultraviolet absorbing polymer which is characterized by being derived from an ethylenically unsaturated monomer having a partial structure represented by Formula (A) below in a molecule, and a monomer represented by Formula (B) below:

  本发明涉及一种紫外线吸收聚合物，其特征在于其由分子中具有以下式(A)所表示的部分结构的乙烯基不饱和单体和以下式(B)所表示的单体衍生而来：
• Sidel'kowskaja et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958, p. 1111,1114; engl.Ausg.S.1078,1081
  作者：Sidel'kowskaja et al.

  DOI：——

  日期：——
• CELLULOSE ESTER OPTICAL FILM, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY USING THE CELLULOSE ESTER OPTICAL FILM, AND METHOD FOR PRODUCING CELLULOSE ESTER OPTICAL FILM
  申请人：Suzuki Takayuki

  公开号：US20100040806A1

  公开（公告）日：2010-02-18

  Disclosed is a cellulose ester optical film characterized by containing a cellulose ester, a polymer (a) defined below and a compound (b) defined below. (a) a polymer obtained by copolymerizing an ethylenically unsaturated monomer having a partial structure represented by the general formula (1) below in a molecule and at least one ethylenically unsaturated monomer (b) at least one compound selected from the group consisting of carbon radical scavengers, phenol compounds and phosphorus compounds. (In the formula, R 1 , R 2 and R 3 independently represent an optionally substituted aliphatic group, an optionally substituted aromatic group or an optionally substituted heterocyclic group; or alternatively any two of R 1 , R 2 and R 3 may combine and form a ring structure together with a nitrogen atom or with a nitrogen atom and a carbon atom to which they are bonded to.)
• Cellulose Ester Optical Film, Polarizing Plate and Liquid Crystal Display Using the Same, Method of Manufacturing Cellulose Ester Optical Film, and Copolymer.
  申请人：Suzuki Takayuki

  公开号：US20100069535A1

  公开（公告）日：2010-03-18

  Disclosed is a cellulose ester optical film containing cellulose ester, a polymer (a) below and a compound (b) below: (a) a polymer obtained by copolymerization of an ethylenically unsaturated monomer having in the molecule a partial structure represented by formula (1) below with at least one ethylenically unsaturated monomer, and (b) at least one compound selected from the group consisting of a compound represented by formula (2) below and a compound represented by formula (3) below,
• OPTICAL COMPENSATION FILM, AND POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY EMPLOYING THE SAME
  申请人：SERA Takashi

  公开号：US20100221457A1

  公开（公告）日：2010-09-02

  The present invention provides an optical compensation film, which has excellent visibility such as light leakage, uneven color tone and front contrast, and can simultaneously realize retardation and wavelength dispersion. The optical compensation film is characterized by containing a cellulose ester, the following polymer (a), and the following compound (b). (a) A polymer produced by copolymerizing an ethylenically unsaturated monomer having in its molecule a partial structure represented by Formula (1) with at least one ethylenically unsaturated monomer. (b) An esterified compound produced by esterifying all or a part of OH groups in a compound (A) having one furanose structure or one pyranose structure, or an esterified compound produced by esterifying all of or a part of OH groups in a compound (B) containing nor less than 2 and not more than 12 structures of at least one of a furanose structure or a pyranose structure.