N,N,N',N'-tetrakis(4-isopropylphenyl)chrysene-6,12-diamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N,N',N'-tetrakis(4-isopropylphenyl)chrysene-6,12-diamine
• 英文别名: 6-N,6-N,12-N,12-N-tetrakis(4-propan-2-ylphenyl)chrysene-6,12-diamine
• 化学式: C₅₄H₅₄N₂
• 分子量: 731.036
• InChiKey: ADPTUNPKYGZJMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.7
• 重原子数：
  56
• 可旋转键数：
  10
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  双-(4-异丙基-苯基)-胺 、 6,12-二溴屈 在 palladium diacetate 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以95%的产率得到N,N,N',N'-tetrakis(4-isopropylphenyl)chrysene-6,12-diamine
  参考文献：
  名称：

  Material for organic electroluminescent device and organic electroluminescent device using same

  摘要：

  本发明提供了一种有机电致发光器件材料，由具有特定结构的芳香胺衍生物组成，其中胺基与萘并单元相连；以及一种有机电致发光器件，包括阴极、阳极和介于阴极和阳极之间的一个或多个有机薄膜层，其中有机薄膜层至少包括一个发光层，其中至少一个有机薄膜层以单一组分材料或多组分混合物的形式包含有机电致发光器件材料。该有机电致发光器件材料和包含该材料的有机电致发光器件具有长寿命和高发射效率的优点，可以发出高色纯度的蓝光。

  公开号：

  US20060052641A1

文献信息

• POLYCYCLIC AROMATIC COMPOUND, MATERIAL FOR AN ORGANIC DEVICE, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY APPARATUS AND LIGHTING APPARATUS
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US20200207787A1

  公开（公告）日：2020-07-02

  A polycyclic aromatic compound in which a plurality of aromatic rings are connected by a boron atom and an oxygen atom, a sulfur atom or a selenium atom and substituted by a specific aryl such as anthracene, is useful as a material for an organic device. By the polycyclic aromatic compound, an organic EL device having at least one of efficiency and device life can be provided.

  一种多环芳香化合物，其中多个芳香环通过硼原子和氧原子、硫原子或硒原子连接，并以特定的芳基（如蒽）取代，可用作有机器件的材料。通过这种多环芳香化合物，可以提供至少在效率和器件寿命方面具有优势的有机EL器件。
• POLYCYCLIC AROMATIC COMPOUND
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US20180069182A1

  公开（公告）日：2018-03-08

  By providing a novel polycyclic aromatic compound in which a plurality of aromatic rings are linked via a boron atom, a nitrogen atom, or the like, options of a material for an organic EL element are increased. In addition, by using the novel polycyclic aromatic compound as a material for an organic electroluminescent element, an excellent organic EL element is provided.

  通过提供一种新型的多环芳香化合物，其中多个芳香环通过硼原子、氮原子或类似物连接，增加了有机EL元件材料的选择。此外，通过将新型多环芳香化合物用作有机电致发光元件的材料，提供了优秀的有机EL元件。
• Organic electroluminescence device and organic light emitting medium
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10243145B2

  公开（公告）日：2019-03-26

  An organic electroluminescence device having a layer of an organic light emitting medium which comprises (A) a specific arylamine compound and (B) at least one compound selected from specific anthracene derivatives, spirofluorene derivatives, compounds having condensed rings and metal complex compounds and is disposed between a pair of electrodes and an organic light emitting medium comprising the above components (A) and (B) are provided. The organic electroluminescence device exhibits a high purity of color, has excellent heat resistance and a long life and efficiently emits bluish to yellowish light. The organic light emitting medium can be advantageously used for the organic electroluminescence device.

  本发明提供了一种有机电致发光器件，该器件具有一层有机发光介质，该有机发光介质包括 (A) 特定芳胺化合物和 (B) 至少一种选自特定蒽衍生物、螺芴衍生物、具有缩合环的化合物和金属络合物的化合物，并置于一对电极和由上述成分 (A) 和 (B) 组成的有机发光介质之间。这种有机电致发光器件颜色纯度高，耐热性能好，使用寿命长，能有效地发出偏蓝至偏黄的光。这种有机发光介质可以很好地用于有机电致发光器件。
• Polycyclic aromatic compound
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US10374166B2

  公开（公告）日：2019-08-06

  A novel polycyclic aromatic compound in which plural aromatic rings are linked via boron atoms, oxygen atoms and the like is provided, and therefore, the range of selection of the material for organic electroluminescent elements can be widened. Also, an excellent organic electroluminescent element is provided by using the novel polycyclic aromatic compound as a material for an organic electroluminescent element.

  本发明提供了一种新型多环芳香族化合物，其中多个芳香环通过硼原子、氧原子等连接，因此可以扩大有机电致发光元件材料的选择范围。此外，通过使用新型多环芳香族化合物作为有机电致发光元件的材料，还可提供一种优异的有机电致发光元件。
• Polycyclic aromatic compound and light emitting layer-forming composition
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US10680186B2

  公开（公告）日：2020-06-09

  The present invention addresses the problem of providing a polycyclic aromatic compound which has improved solubility in solvents, film formability, wet coatability and in-plane orientation. The above-described problem is solved by a composition for forming a light emitting layer, which contains, as a first component, at least one compound selected from the group consisting of compounds represented by general formula (A-1) and compounds represented by general formula (A-2), as a second component, at least one compound that has a triplet energy (ET) of 1.8-3.0 eV, and as a third component, at least one organic solvent. In the formulae, R represents a hydrogen atom, an aryl group, a heteroaryl group, a diarylamino group, a diheteroarylamino group or an aryl heteroarylamino group.

  本发明要解决的问题是提供一种多环芳香族化合物，它在溶剂中的溶解性、成膜性、湿涂层性和面内取向性都有所改善。本发明通过一种用于形成发光层的组合物来解决上述问题，该组合物作为第一组分，含有至少一种从通式（A-1）和通式（A-2）所代表的化合物组成的组中选出的化合物；作为第二组分，含有至少一种三重能（ET）为 1.8-3.0 eV 的化合物；作为第三组分，含有至少一种有机溶剂。 式中，R 代表氢原子、芳基、杂芳基、二芳基氨基、二杂芳基氨基或芳基杂芳基氨基。