(E)-3-(3,5-ditert-butyl-4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: (E)-3-(3,5-ditert-butyl-4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one
• 化学式: C₂₄H₃₀O₂
• 分子量: 350.501
• InChiKey: PERNZPOPTPPPJZ-JLHYYAGUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  对甲基苯乙酮 、 3,5-二叔丁基-4-羟基苯甲醛 在 盐酸 作用下， 以 乙醇 为溶剂， 以20%的产率得到(E)-3-(3,5-ditert-butyl-4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one
  参考文献：
  名称：

  亚苄基苯乙酮的合成及其对脂质过氧化的抑制作用。

  摘要：

  已经合成了一系列的亚苄基苯乙酮衍生物，并发现它们在大鼠肝微粒体中显示出对脂质过氧化作用（LPO）的有效抑制作用。该系列制备的所有19种化合物都是LPO抑制剂。在具有两个间叔丁基取代基的对羟基衍生物中发现了最高的活性。

  DOI：

  10.1016/s0223-5234(00)00137-9

文献信息

• HYDROXYL-FUNCTIONAL UNSATURATED POLYAMINE SILICONE LIGAND SUITABLE FOR QUANTUM DOT COMPOSITIONS AND ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200216752A1

  公开（公告）日：2020-07-09

  A quantum dot article comprises (a) a first barrier layer, (b) a second barrier layer, and (c) a quantum dot layer between the first barrier layer and the second barrier layer, the quantum dot layer comprises light-emitting nanoparticles dispersed in a cured matrix; wherein the quantum dot layer further comprises a hydroxyl-functional unsaturated polyamine silicone ligand that is the reaction product of a polyamine silicone ligand and an unsaturated monofunctional epoxy compound.
• HYDROXYL-FUNCTIONAL POLYAMINE SILICONE LIGAND SUITABLE FOR QUANTUM DOT COMPOSITIONS AND ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200262979A1

  公开（公告）日：2020-08-20

  A quantum dot article is described comprising a first barrier layer, a second barrier layer, and a quantum dot layer between the first and second barrier layer. The quantum dot layer comprises light-emitting nanoparticles dispersed in a cured matrix. The quantum dot layer further comprises a hydroxyl-iunctional polyamine silicone ligand that is the reaction product of a polyamine silicone ligand and a monofunctional epoxy compound. Also described is a hydroxyl-functional polyamine silicone that is the reaction product of a polyamine silicone and a monofunctional epoxy compound, as well as quantum dot compositions comprising light-emitting nanoparticles and the described hydroxyl-functional polyamine silicone.
• QUANTUM DOT COMPOSITIONS AND ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200369954A1

  公开（公告）日：2020-11-26

  A quantum dot composition is described comprising light-emitting nanoparticles comprising a polyamine silicone ligand dispersed in a polymerizable resin composition comprising at least one polythiol, at least one polyene, wherein the polyene lacks functional groups that are amine-reactive, at least one amine-reactive ethylenically unsaturated component in an amount ranging from 2 to 15 wt.%, based on the total wt. % solids of the composition, and a hindered phenolic antioxidant. Also described are quantum dot (e.g. film) articles.
• Synthesis of benzylideneacetophenones and their inhibition of lipid peroxidation
  作者：I Arty

  DOI：10.1016/s0223-5234(00)00137-9

  日期：2000.4

  A series of benzylideneacetophenone derivatives have been synthesized and found to show potent inhibition of the lipid peroxidation (LPO) in rat liver microsomes. All 19 compounds prepared in this series are LPO inhibitors. The highest activity was found in para hydroxy derivatives with two meta tert-butyl substituents.

  已经合成了一系列的亚苄基苯乙酮衍生物，并发现它们在大鼠肝微粒体中显示出对脂质过氧化作用（LPO）的有效抑制作用。该系列制备的所有19种化合物都是LPO抑制剂。在具有两个间叔丁基取代基的对羟基衍生物中发现了最高的活性。