(E)-3-(3,5-ditert-butyl-4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: (E)-3-(3,5-ditert-butyl-4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one
• 化学式: C₂₄H₃₀O₂
• 分子量: 350.501
• InChiKey: PERNZPOPTPPPJZ-JLHYYAGUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  对甲基苯乙酮 、 3,5-二叔丁基-4-羟基苯甲醛 在 盐酸 作用下， 以 乙醇 为溶剂， 以20%的产率得到(E)-3-(3,5-ditert-butyl-4-hydroxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one
  参考文献：
  名称：

  亚苄基苯乙酮的合成及其对脂质过氧化的抑制作用。

  摘要：

  已经合成了一系列的亚苄基苯乙酮衍生物，并发现它们在大鼠肝微粒体中显示出对脂质过氧化作用（LPO）的有效抑制作用。该系列制备的所有19种化合物都是LPO抑制剂。在具有两个间叔丁基取代基的对羟基衍生物中发现了最高的活性。

  DOI：

  10.1016/s0223-5234(00)00137-9

文献信息

• HYDROXYL-FUNCTIONAL UNSATURATED POLYAMINE SILICONE LIGAND SUITABLE FOR QUANTUM DOT COMPOSITIONS AND ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200216752A1

  公开（公告）日：2020-07-09

  A quantum dot article comprises (a) a first barrier layer, (b) a second barrier layer, and (c) a quantum dot layer between the first barrier layer and the second barrier layer, the quantum dot layer comprises light-emitting nanoparticles dispersed in a cured matrix; wherein the quantum dot layer further comprises a hydroxyl-functional unsaturated polyamine silicone ligand that is the reaction product of a polyamine silicone ligand and an unsaturated monofunctional epoxy compound.
• HYDROXYL-FUNCTIONAL POLYAMINE SILICONE LIGAND SUITABLE FOR QUANTUM DOT COMPOSITIONS AND ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200262979A1

  公开（公告）日：2020-08-20

  A quantum dot article is described comprising a first barrier layer, a second barrier layer, and a quantum dot layer between the first and second barrier layer. The quantum dot layer comprises light-emitting nanoparticles dispersed in a cured matrix. The quantum dot layer further comprises a hydroxyl-iunctional polyamine silicone ligand that is the reaction product of a polyamine silicone ligand and a monofunctional epoxy compound. Also described is a hydroxyl-functional polyamine silicone that is the reaction product of a polyamine silicone and a monofunctional epoxy compound, as well as quantum dot compositions comprising light-emitting nanoparticles and the described hydroxyl-functional polyamine silicone.
• QUANTUM DOT COMPOSITIONS AND ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200369954A1

  公开（公告）日：2020-11-26

  A quantum dot composition is described comprising light-emitting nanoparticles comprising a polyamine silicone ligand dispersed in a polymerizable resin composition comprising at least one polythiol, at least one polyene, wherein the polyene lacks functional groups that are amine-reactive, at least one amine-reactive ethylenically unsaturated component in an amount ranging from 2 to 15 wt.%, based on the total wt. % solids of the composition, and a hindered phenolic antioxidant. Also described are quantum dot (e.g. film) articles.