9-methyl-3-(N-methylanilino)carbazole | 86885-08-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-methyl-3-(N-methylanilino)carbazole
• 英文别名: N,9-dimethyl-N-phenylcarbazol-3-amine
• CAS: 86885-08-7
• 化学式: C₂₀H₁₈N₂
• 分子量: 286.376
• InChiKey: PUKNCTHYOOPMQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-methyl-3-(N-methylanilino)carbazole 在 air 作用下， 以 乙醚 为溶剂， 反应 8.0h， 以51%的产率得到5,11-dimethylindolo<3,2-b>-carbazole
  参考文献：
  名称：

  An Expedient Synthesis of 5,11-Dimethylindolo[3,2-b]-carbazole, A Potent Ligand for the Receptor for TCDD

  摘要：

  A new and efficient synthesis has been developed for the title indolocarbazole which has been indicated by a recent computer-aided study to be a potent ligand for the receptor for the naturally occurring carcinogen, TCDD.

  DOI：

  10.1080/00397919608004606
• 作为产物：
  描述：

  9-甲基咔唑-3-胺 在 氢氧化钾 、 铜 、 sodium cyanoborohydride 、 potassium carbonate 作用下， 以 吡啶 、 溶剂黄146 、 乙腈 为溶剂， 反应 35.0h， 生成 9-methyl-3-(N-methylanilino)carbazole
  参考文献：
  名称：

  An Expedient Synthesis of 5,11-Dimethylindolo[3,2-b]-carbazole, A Potent Ligand for the Receptor for TCDD

  摘要：

  A new and efficient synthesis has been developed for the title indolocarbazole which has been indicated by a recent computer-aided study to be a potent ligand for the receptor for the naturally occurring carcinogen, TCDD.

  DOI：

  10.1080/00397919608004606

文献信息

• Anthracene Derivatives and Light-Emitting Devices Using the Anthracene Derivatives
  申请人：Nomura Hiroko

  公开号：US20090004506A1

  公开（公告）日：2009-01-01

  The present invention provides novel anthracene derivatives. In particular, the present invention provides light-emitting elements with high luminous efficiency, and light-emitting elements with long lifetime. Further, the present invention provides light-emitting devices and electronic devices having long lifetime by using these light-emitting elements. An anthracene derivative represented by the general formula (1) is provided. In addition, since the anthracene derivative represented by the general formula (1) has high luminous efficiency, a light-emitting element using the anthracene derivative represented by the general formula (1) can also have high luminous efficiency. By using the anthracene derivative represented by the general formula (1), light-emitting elements with long lifetime can be provided.

  本发明提供了新型蒽衍生物。特别是，本发明提供了具有高发光效率和长寿命的发光元件，以及利用这些发光元件的具有长寿命的发光器件和电子器件。提供了由通用式（1）表示的蒽衍生物。此外，由于通用式（1）表示的蒽衍生物具有高发光效率，使用通用式（1）表示的蒽衍生物的发光元件也可以具有高发光效率。通过使用通用式（1）表示的蒽衍生物，可以提供具有长寿命的发光元件。
• Oxadiazole derivative, and light emitting element, light emitting device, and electronic device using the oxadiazole derivative
  申请人：Murata Hiroko

  公开号：US20070149784A1

  公开（公告）日：2007-06-28

  An oxadiazole derivative represented by the following general formula (G1) is synthesized and applied to the light emitting element, wherein A m is a substituent represented by a general formula (Am1), (Am2), or (Am3); each of α, β 1 , and β 2 represents an arylene group having 6 to 25 carbon atoms; each of A r 1 to A r 6 represents an aryl group having 6 to 25 carbon atoms; each of R 1 to R 3 represents hydrogen, an alkyl group having 1 to 4 carbon atoms, or an aryl group having 6 to 25 carbon atoms; and R 4 represents an alkyl group having 1 to 4 carbon atoms or an aryl group having 6 to 25 carbon atoms.

  由以下一般式（G1）表示的一种噁二唑衍生物被合成并应用于发光元件，其中Am是由一般式（Am1）、（Am2）或（Am3）表示的取代基；α、β1和β2分别表示具有6至25个碳原子的芳基基团；Ar1至Ar6分别表示具有6至25个碳原子的芳基基团；R1至R3分别表示氢、具有1至4个碳原子的烷基基团或具有6至25个碳原子的芳基基团；R4表示具有1至4个碳原子的烷基基团或具有6至25个碳原子的芳基基团。
• Anthracene Derivative, and Light Emitting Element, Light Emitting Device, Electronic Device Using Anthracene Derivative
  申请人：Egawa Masakazu

  公开号：US20080103315A1

  公开（公告）日：2008-05-01

  A novel anthracene derivative represented by General Formula (1) is provided, which enables the production of a light-emitting element with high luminous efficiency and a long lifetime. A high-performance light-emitting device and electronic device in which the anthracene derivative is employed are also disclosed. The anthracene derivative of the present invention is represented by General Formula (1), in which the unit A represents any one of substituents represented by General Formulae (1-1) to (1-3). The variables shown in Formulae (1) and (1-1) to (1-3) are defined in the specification.

  提供了一种由一般式（1）表示的新型蒽衍生物，可实现具有高发光效率和长寿命的发光元件的生产。还公开了使用蒽衍生物的高性能发光器件和电子器件。本发明的蒽衍生物由一般式（1）表示，其中单元A代表一般式（1-1）至（1-3）所表示的取代基中的任意一种。一般式（1）和（1-1）至（1-3）中显示的变量在规范中定义。
• Anthracene Derivative, And Light Emitting Element, Light Emitting Device, And Electronic Device Using the Anthracene Derivative
  申请人：Egawa Masakazu

  公开号：US20080086012A1

  公开（公告）日：2008-04-10

  It is an object to provide a noble anthracene derivative, a light emitting element with a high luminous efficiency, and further a light emitting element with a long lifetime. It is another object to provide a light emitting device and electronic device with a long lifetime by using the light emitting element. An anthracene derivative represented by General Formula (1) is provided. Since the anthracene derivative represented by General Formula (1) has a high luminous efficiency, when the anthracene derivative is used for a light emitting element, the light emitting element can have a high luminous efficiency. Further, when the anthracene derivative represented by General Formula (1) is used for a light emitting element, the light emitting element can have a long lifetime.

  本发明的目的是提供一种高贵的蒽衍生物、具有高发光效率的发光元件，以及具有长寿命的发光元件。另一个目的是通过使用发光元件提供具有长寿命的发光装置和电子装置。提供了一种由通式（1）表示的蒽衍生物。由于由通式（1）表示的蒽衍生物具有高发光效率，因此当将该蒽衍生物用于发光元件时，发光元件可以具有高发光效率。此外，当使用由通式（1）表示的蒽衍生物用于发光元件时，发光元件可以具有长寿命。
• Stilbene Derivatives, Light-Emitting Element, Display Device, and Electronic Device
  申请人：Egawa Masakazu

  公开号：US20080091030A1

  公开（公告）日：2008-04-17

  A novel stilbene derivative is provided with motivation of providing a blue emissive material showing excellent color purity. The use of the stilbene derivative of the present invention allows the fabrication of a blue-emissive light-emitting element with excellent color purity. The invention also includes an electronic device equipped with a display portion in which the stilbene derivative is employed. The stilbene derivative of the present invention is represented by formula (1), in which Ar 1 and Ar 2 may form a 5-membered ring by being directly bonded to each other. In formula (1), A 11 represents any one of substituents represented by general formulas (1-1) to (1-3). The variables shown in formula (1) and (1-1) to (1-3) are as defined in the specification.

  本发明提供一种新颖的苯乙烯衍生物，旨在提供一种显示出优异色纯度的蓝色发光材料。使用本发明中的苯乙烯衍生物可以制造具有优异色纯度的蓝色发光元件。本发明还包括一种装备有显示部分的电子设备，其中采用了苯乙烯衍生物。本发明的苯乙烯衍生物由式（1）表示，其中Ar1和Ar2可以通过直接键结合形成5-成员环。在式（1）中，A11表示通式（1-1）至（1-3）中的任意一种取代基。式（1）和（1-1）至（1-3）中所示的变量如规范中所定义。