6-((tert-butoxycarbonyl)amino)hexyl acrylate | 255375-06-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 6-((tert-butoxycarbonyl)amino)hexyl acrylate
• 英文别名: 6-[(2-Methylpropan-2-yl)oxycarbonylamino]hexyl prop-2-enoate；6-[(2-methylpropan-2-yl)oxycarbonylamino]hexyl prop-2-enoate
• CAS: 255375-06-5
• 化学式: C₁₄H₂₅NO₄
• 分子量: 271.357
• InChiKey: LXCLFEYXEXCZET-UHFFFAOYSA-N

物化性质

• 沸点：
  373.9±25.0 °C(Predicted)
• 密度：
  1.002±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-((tert-butoxycarbonyl)amino)hexyl acrylate 在 碳酸氢钠 、 对苯二酚 、 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 生成 Acrylic acid 6-[(R)-4-((3R,5S,7R,8R,9S,10S,12S,13R,14S,17R)-3,7,12-trihydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-yl)-pentanoylamino]-hexyl ester
  参考文献：
  名称：

  Polymer-catalyzed aminolysis of covalently imprinted cholic acid derivative

  摘要：

  A cholic acid template bearing an acrylate functional group was copolymerized with acrylamides to generate a series of cross-linked imprint polymers. Subsequent release from the matrix by means of an aminolysis reaction showed a remarkable catalysis by the polymer surface. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01937-1
• 作为产物：
  描述：

  6-氨基-1-己醇 在 三乙胺 、 sodium hydroxide 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 为溶剂， 反应 24.0h， 生成 6-((tert-butoxycarbonyl)amino)hexyl acrylate
  参考文献：
  名称：

  Cationic amphiphilic non-hemolytic polyacrylates with superior antibacterial activity

  摘要：

  丙烯酸共聚物中含有适当成分的具有阳离子电荷的偶联体和 2 碳和 6 碳间隔臂，可显示出卓越的抗菌活性，同时具有极低的溶血效应。这些两亲共聚物是已报道的最有前途的合成聚合物抗菌体系之一。

  DOI：

  10.1039/c4cc01583e

文献信息

• FOAMED PRODUCT IN A SHEET FORM AND METHOD FOR PRODUCTION THEREOF
  申请人：OJI PAPER CO., LTD.

  公开号：EP1647570A1

  公开（公告）日：2006-04-19

  The present invention discloses a foam sheet and its production process comprising the formation of a plurality of independent cells and/or a plurality of continuous cells. The foam sheet is produced from a foamable composition that contains an acid generator that generates an acid or a base generator that generates a base due to the action of an active energy beam and a compound that has a decomposing foamable functional group that decomposes and eliminates one or more types of low boiling point volatile substances by reacting with the acid or base.

  本发明公开了一种泡沫板及其生产工艺，包括形成多个独立单元和/或多个连续单元。泡沫板由一种可发泡组合物生产而成，该组合物含有一种酸发生器（在活性能量束的作用下产生一种酸）或一种碱发生器（在活性能量束的作用下产生一种碱），以及一种化合物，该化合物具有一种可分解泡沫的官能团，通过与酸或碱反应，分解并消除一种或多种低沸点挥发性物质。
• Foamed product in a sheet form and method for production thereof
  申请人：Takada Tomoyuki

  公开号：US20060210785A1

  公开（公告）日：2006-09-21

  The present invention discloses a foam sheet and its production process comprising the formation of a plurality of independent cells and/or a plurality of continuous cells. The foam sheet is produced from a foamable composition that contains an acid generator that generates an acid or a base generator that generates a base due to the action of an active energy beam and a compound that has a decomposing foarmable functional group that decomposes and eliminates one or more types of low boiling point volatile substances by reacting with the acid or base.

  本发明公开了一种泡沫板及其生产工艺，包括形成多个独立单元和/或多个连续单元。泡沫板由一种可发泡组合物生产而成，该组合物含有一种酸发生器（在活性能量束的作用下产生一种酸）或一种碱发生器（在活性能量束的作用下产生一种碱），以及一种化合物，该化合物具有一种可分解泡沫的官能团，通过与酸或碱反应，分解并消除一种或多种低沸点挥发性物质。
• A Selectivity-Driven Supramolecular Polymerization of an AB Monomer
  作者：Oren A. Scherman、G. B. W. L. Ligthart、Rint P. Sijbesma、E. W. Meijer

  DOI：10.1002/anie.200504192

  日期：2006.3.20
• FOAM SHEET AND PRODUCTION PROCESS THEREOF
  申请人：Takada Tomoyuki

  公开号：US20090130419A1

  公开（公告）日：2009-05-21

  A foam sheet produced from a foamable composition containing an acid generator that generates acid or a base generator that generates base due to the action of an active energy beam, and containing a compound having decomposing foamable functional group that decomposes and eliminates at least one type of low boiling point volatile substance by reacting with acid or base, makes it possible to obtain a microcellular thin foam that was considered to be difficult to produce thus far, thereby greatly expanding the range of fields in which foams can be used and significantly contributing to industry.
• POLYMER WITH ANTIBACTERIAL ACTIVITY
  申请人：Research Foundation of the City University of New York

  公开号：US20150105526A1

  公开（公告）日：2015-04-16

  A polymer with antibacterial activity is provided. The polymer has multiple groups of cationic amines, each group spaced from the polymer backbone by alkylene spacers of different lengths. The resulting polymer maintains significant antibacterial activity while having reduced hemolytic activity relative to a homopolymer that uses hexylene spacers.