adipic acid bis-isopropylidenehydrazide | 35532-27-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: adipic acid bis-isopropylidenehydrazide
• 英文别名: N.N'-Diisopropyliden-adipinsaeuredihydrazid；Adipinsaeure-bis-isopropylidenhydrazid；N,N'-bis(propan-2-ylideneamino)hexanediamide
• CAS: 35532-27-5
• 化学式: C₁₂H₂₂N₄O₂
• 分子量: 254.332
• InChiKey: CTZJJJJQYPHZGV-UHFFFAOYSA-N

物化性质

• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  82.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  己二酸二乙酯 在 一水合肼 作用下， 生成 adipic acid bis-isopropylidenehydrazide
  参考文献：
  名称：

  Curtius, Journal fur praktische Chemie (Leipzig 1954), 1915, vol. <2> 91, p. 23

  摘要：

  DOI：

文献信息

• AQUEOUS CROSS-LINKING COMPOSITIONS AND METHODS
  申请人：Yang Yong

  公开号：US20120142847A1

  公开（公告）日：2012-06-07

  Water-borne cross-linking polymeric compositions and related embodiments, such as methods of making and using the compositions, as well as products formed with said compositions are described. For example, the water-borne composition may comprise polymers incorporating cross-linking functionality such as, but not limited to, carbonyl or epoxy functionality, and a blocked cross-linking agent, for example, a hydrazone. The cross-linking functionality does not react with the blocked cross-linking agent; however, the blocked cross-linking agent is capable of reacting with the alternative form cross-linking agent such as, but not limited to, a hydrazide, to yield a cross-linked polymer. The alternative form cross-linking agent may be formed in an equilibrium reaction including the blocked cross-linking agent.

  本文描述了水性交联聚合物组合物及相关实施例，例如制备和使用该组合物的方法，以及使用该组合物形成的产品。例如，水性组合物可以包括聚合物，其中包含交联功能，例如但不限于羰基或环氧功能，以及被阻断的交联剂，例如肼。交联功能不与被阻断的交联剂反应；然而，被阻断的交联剂能够与另一种形式的交联剂反应，例如但不限于肼酸酯，从而产生交联聚合物。另一种形式的交联剂可以在包括被阻断的交联剂的平衡反应中形成。
• Aqueous Cross-linking Compositions and Methods
  申请人：COLUMBIA INSURANCE COMPANY

  公开号：US20140228509A1

  公开（公告）日：2014-08-14

  Water-borne cross-linking polymeric compositions and related embodiments, such as methods of making and using the compositions, as well as products formed with said compositions are described. The water-borne composition may comprise one or more polymers formulated from one or more monomers of which at least one is a monomer that yields acetaldehyde as a hydrolysis product, and incorporating cross-linking functionality such as, but not limited to, carbonyl or epoxy functionality, and a blocked cross-linking agent, for example, a hydrazone. Neither the cross-linking functionality nor the acetaldehyde reacts with the blocked cross-linking agent; however, the blocked cross-linking agent is capable of conversion to an alternative form cross-linking agent such as, but not limited to, a hydrazide, to yield a cross-linked polymer. The alternative form cross-linking agent may be formed in an equilibrium reaction including the blocked cross-linking agent.

  本文描述了水基交联聚合物组合物及其相关实施例，例如制备和使用该组合物的方法，以及使用该组合物形成的产品。水基组合物可以包含一个或多个聚合物，这些聚合物由一个或多个单体配制而成，其中至少一个单体产生乙醛作为水解产物，并且具有交联功能，例如但不限于酮或环氧功能，以及一个阻断的交联剂，例如一个肼。交联功能和乙醛均不与阻断的交联剂反应；然而，阻断的交联剂能够转化为交联聚合物的另一种形式的交联剂，例如但不限于肼脲，以产生交联聚合物。另一种形式的交联剂可以在包括阻断的交联剂的平衡反应中形成。
• POLYACETAL RESIN COMPOSITION, AND RESIN MOLDED ARTICLE
  申请人：Mitsubishi Engineering-Plastics Corporation

  公开号：EP3101067A1

  公开（公告）日：2016-12-07

  Provided is a polyacetal resin composition in which at least one dihydrazone compound (B) selected from the group selected from a dihydrazone compound (B1) represented by the following General Formula (1) and a dihydrazone compound (B2) represented by the following General Formula (2) is blended in 0.02 to 5 parts by mass with respect to 100 parts by mass of a polyacetal resin (A). (In the above formula, R1 represents an aliphatic hydrocarbon group having 4 to 20 carbon atoms, or the like; R2 to R5 each independently represent an alkyl group having 1 or 2 carbon atoms, or the like; at least one of R2 and R3 represents an alkyl group having 1 or 2 carbon atoms; and at least one of R4 and R5 represents an alkyl group having 1 or 2 carbon atoms.) (In the above formula, R8 represents an aliphatic

  本发明提供了一种聚缩醛树脂组合物，其中至少有一种二氢腙化合物（B）选自以下通式（1）表示的二氢腙化合物（B1）和以下通式（2）表示的二氢腙化合物（B2）组，与 100 份聚缩醛树脂（A）的质量比为 0.02 至 5 份。 (在上式中，R1 代表具有 4 至 20 个碳原子的脂肪族烃基；R2 至 R5 各自独立地代表具有 1 或 2 个碳原子的烷基；R2 和 R3 中至少有一个代表具有 1 或 2 个碳原子的烷基；R4 和 R5 中至少有一个代表具有 1 或 2 个碳原子的烷基）。 (在上式中，R8 代表脂肪族
• Modified latent crosslinker in polymeric systems
  申请人：THE SHERWIN-WILLIAMS COMPANY

  公开号：US10676634B2

  公开（公告）日：2020-06-09

  A self-crosslinking compound and coating compositions including the same as well as compositions capable of forming a ketone or carbonyl-hydrazide crosslink at ambient temperatures that utilizes a modified latent cross linker capable of forming a polymer networked in an applied coating.

  一种自交联化合物和包括该化合物的涂料组合物，以及能在常温下形成酮或羰酰肼交联的组合物，该组合物利用改性潜伏交联剂，能在涂覆的涂层中形成聚合物网络。
• POLYACETAL RESIN COMPOSITION AND POLYACETAL RESIN MOLDED ARTICLE
  申请人：Mitsubishi Engineering-Plastics Corporation

  公开号：EP3330317B1

  公开（公告）日：2021-10-06