4'-戊基-[1,1'-联苯]-4-甲酰氯 | 59748-37-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4'-戊基-[1,1'-联苯]-4-甲酰氯
• 中文别名: 1-哌啶羧酸,3-[[(3-氟苯基)甲基]氨基]-,1,1-二甲基乙基酯；反式-4-戊基双环己基甲酰氯
• 英文名称: 4'-n-pentyl-<1,1'-biphenyl>-4-carboxylic acid chloride
• 英文别名: 4'-pentylbiphenyl-4-carboxylic acid chloride；4'-pentylbiphenyl-4-carbonyl chloride；4-(4-n-pentylphenyl)benzoyl chloride；4-pentylbiphenyl acid chloride；4-(4-n-pentylphenyl)-benzoyl chloride；4'-n-Pentyl-biphenyl-4-carbonsaeurechlorid；[1,1'-Biphenyl]-4-carbonyl chloride, 4'-pentyl-；4-(4-pentylphenyl)benzoyl chloride
• CAS: 59748-37-7
• 化学式: C₁₈H₁₉ClO
• 分子量: 286.801
• InChiKey: PAXFBGZCRAEDBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4'-戊基-[1,1'-联苯]-4-甲酰氯 在 sodium carbonate 、 lithium diisopropyl amide 作用下， 以 甲苯 为溶剂， 反应 0.67h， 生成
  参考文献：
  名称：

  A new class of chiral smectic liquid crystals: substituted biphenylylcyclohexylidene ethanols having an axial chirality

  摘要：

  DOI：

  10.1021/jo00221a020
• 作为产物：
  描述：

  4'-正戊基-4-氰基联苯 在 氯化亚砜 、 硫酸 作用下， 以 溶剂黄146 为溶剂， 反应 1.0h， 生成 4'-戊基-[1,1'-联苯]-4-甲酰氯
  参考文献：
  名称：

  一些具有两个侧向腈基功能的新型向列材料

  摘要：

  已经制备了五十多种3-烷基-6-羟基-1,2-苯二甲腈的酯。新酯表现出高负介电各向异性的稳定向列相。酯的澄清点与它们所结合的各种环之间的关系与对于正介电各向异性的向列材料通常观察到的关系相同。

  DOI：

  10.1002/hlca.19830660625

文献信息

• Biphenyl esters and liquid crystalline mixtures comprising them
  申请人：Merck Patent Gesellschaft mit beschrankter Haftung

  公开号：US04065489A1

  公开（公告）日：1977-12-27

  Biphenyl esters of the formula ##STR1## wherein X is --CO--O-- or --O--CO-- and R.sub.1 and R.sub.2 each are alkyl or alkoxy of 1 - 8 carbon atoms, enlarge significantly the temperature range of the nematic phase of liquid-crystalline compositions without adversely affecting other properties.

  苯并酯的化学式为##STR1##，其中X为--CO--O--或--O--CO--，R.sub.1和R.sub.2分别为1-8个碳原子的烷基或烷氧基，显著扩大了液晶组合物向列相的温度范围，而不会对其他性质产生不利影响。
• Liquid Crystalline Ionic Dendrimers Containing Luminescent Oxadiazole Moieties
  作者：Silvia Hernández-Ainsa、Joaquín Barberá、Mercedes Marcos、José Luis Serrano

  DOI：10.1021/ma202051c

  日期：2012.1.24

  Series II results from the ionic junction of the dendrimers to 1,2,4-oxadiazole-containing acids. The liquid crystalline behavior has been investigated by means of differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and X-ray diffractometry (XRD). The liquid crystal properties are significantly improved in the dendrimers compared to the mesogenic precursors. The structural

  通过离子接枝聚（丙烯亚胺）PPI-（NH 2）x（x = 4，8，16，16，32，64）和聚（酰氨基胺）PAMAM-（NH 2）x（x＝ 64）已经合成了带有带有恶二唑环的羧酸，并且已经研究了它们的液晶性质。系列I是通过树枝状聚合物与含1,3,4-恶二唑的酸之间的离子附着而产生的。系列II由树枝状聚合物与含1,2,4-恶二唑酸的离子连接产生。已经通过差示扫描量热法（DSC），偏振光学显微镜（POM）和X射线衍射法（XRD）研究了液晶行为。与介晶前体相比，树枝状聚合物的液晶性质得到了显着改善。通过X射线衍射确定的结构参数反映了每种引入的含恶二唑酸所建立的不同的超分子组织。根据这些实验结果，提出了一种基于微观偏析现象和介晶单元之间相互交错程度可变的堆积模型。还研究了化合物的吸收和发射性质。据我们所知，这些是迄今为止结合恶二唑单元和液晶性质的第一批树枝状大分子。
• Extended liquid-crystalline oligofluorenes with photo- and electroluminescence
  作者：Jesús del Barrio、Luiz Silvino Chinelatto Jr.、José Luis Serrano、Luis Oriol、Milagros Piñol、Henk J. Bolink

  DOI：10.1039/c0nj00404a

  日期：——

  we report the synthesis and characterization of a series of low-molecular weight light-emitting molecules based on short oligofluorene cores, from one to three 9,9-dioctylfluorene units, elongated at the 2- and 7-positions by means of promesogenic units. The effect of this structural modification on the mesomorphic properties, as well as on the optical and electrochemical properties, is studied. The

  在本文中，我们报道了一系列基于短寡芴核的低分子量发光分子的合成和表征，从一到三个 9,9-二辛基芴单位，通过促生单位在2位和7位上拉长。研究了这种结构修饰对介晶性能以及光学和电化学性能的影响。已经探索了将这些分子用作发光二极管（LED）和偏振光致发光层中的发射体的可能性。
• Some Novel Nematic Materials Bearing Two Lateral Nitrile Functions
  作者：Stephen M. Kelly、Tuong Huynh-Ba

  DOI：10.1002/hlca.19830660625

  日期：1983.9.21

  More than fifty esters of 3-alkyl-6-hydroxy-1,2-benzenedicarbonitrile have been prepared. The new esters exhibit stable nematic phases of high negative dielectric anisotropy. The relationship between the clearing points of the esters and the various rings they incorporate is the same as that normally observed for nematic materials of positive dielectric anisotropy.

  已经制备了五十多种3-烷基-6-羟基-1,2-苯二甲腈的酯。新酯表现出高负介电各向异性的稳定向列相。酯的澄清点与它们所结合的各种环之间的关系与对于正介电各向异性的向列材料通常观察到的关系相同。
• Synthesis of Multiring Azo-Benzoic Acid Liquid Crystalline Molecules and Their Special Photosensitive Property
  作者：Min-Yan Zheng、Yong-Sheng Wei、Wei Geng、Nai-Ni Guo、Ping Zhang

  DOI：10.1080/15421406.2014.949591

  日期：2015.2.11

  10 new rod-like azo benzoic acid liquid crystals belonged to three series have been prepared, in which trans-cyclohexyl benzene, biphenyl or bi-trans-cyclohexyl carboxylic acid mesogenic cores with ethyl, n-propyl, n-butyl or n-pentyl substituents were connected with azo benzoic acid. Meantime, a simple method was developed in synthesizing compounds bearing both ester and carboxyl groups in one-step reaction. All these compounds have been characterized on the basis of their spectral data, differential scanning calorimeter (DSC) and hot stage polarizing optical microscope (HS-POM). All these compounds have higher thermo-stability. 8 of these compounds have liquid crystalline properties. Their temperature ranges of mesophase have not been obtained, resulting from all the compounds decomposed before their clearing points. Although these compounds are photosensitive in solution under illumination of UV light (365nm), they can't do trans-cis isomerization in their mesophses, indicating the super stabilities of the trans isomer in mesophase.