meso-tri-p-anisyltetrabenzoporphinato zinc | 137164-81-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: meso-tri-p-anisyltetrabenzoporphinato zinc
• CAS: 137164-81-9
• 化学式: C₅₇H₃₈N₄O₃Zn
• 分子量: 892.344
• InChiKey: MESBZAWSOBLPBW-JBKFIJAOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  potassium phtalimide 、 zinc p-anisylacetate 以 solid 为溶剂， 生成 Zn(cresoxyacetylhydrazino)2 、 Zinc 29H,31H-tetrabenzo[b,g,l,q]porphine 、 copper meso-tetrakis(p-methoxyphenyl)tetrabenzoporphyrin 、 meso-tri-p-anisyltetrabenzoporphinato zinc 、 meso-mono-p-anisyltetrabenzoporphinato zinc
  参考文献：
  名称：

  Formation of tetrabenzoporphine skeleton by the reactions of phthalimide with zinc carbonates

  摘要：

  The high temperature reactions of phthalimide potassium salt (PIK) with various zinc carbonates were carried out. The reaction of PIK with zinc acetate yielded tetrabenzoporphinato zinc (ZnTBP). Tetra-tert-butyltetrabenzoporphinato zinc (ZntBu4TBP), whose four tert-butyl substituents were positioned on the TBP periphery, was also prepared in a similar way using the 4-tert-butylphthalimide potassium salt (4-tBuPIK). These results were explained on the basis of the function of zinc acetate as the meso-methine carbon source of the TBP structure. The use of zinc phenylacetate instead of zinc acetate in the reaction of PIK led to the production of meso-phenyl substituted ZnTBPs, although they were different in the number of meso-phenyl substituent(s). The attempt to introduce alkyl residues at the meso-position(s) by the reaction of PIK in the presence of zinc alkylacetate having a long alkyl chain was not successful, except for the substitution of the methyl group using zinc propionate.

  DOI：

  10.1016/s0020-1693(00)87937-2