copper meso-tetrakis(p-methoxyphenyl)tetrabenzoporphyrin | 80529-85-7

• 分子结构分类: 有机化合物
• 英文名称: copper meso-tetrakis(p-methoxyphenyl)tetrabenzoporphyrin
• 英文别名: tetra-p-anisyltetrabenzoporphyrin zinc
• CAS: 80529-85-7
• 化学式: C₆₄H₄₄N₄O₄Zn
• 分子量: 998.468
• InChiKey: BETXHBLBLCUSOQ-BMECERBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-[(4-methoxyphenyl)methylidene]-2,3-dihydro-1H-isoindol-1-one 、 zinc diacetate 生成 copper meso-tetrakis(p-methoxyphenyl)tetrabenzoporphyrin
  参考文献：
  名称：

  Reinvestigation of synthetic methods for zinc meso-tetraphenyltetrabenzoporphyrin

  摘要：

  DOI：

  10.1016/s0020-1693(00)85087-2

文献信息

• Formation of tetrabenzoporphine skeleton by the reactions of phthalimide with zinc carbonates
  作者：Kunihiro Ichimura、Masako Sakuragi、Hisayuki Morii、Madoka Yasuike、Yasumasa Toba、Masaru Fukui、Osamu Ohno

  DOI：10.1016/s0020-1693(00)87937-2

  日期：1991.8

  The high temperature reactions of phthalimide potassium salt (PIK) with various zinc carbonates were carried out. The reaction of PIK with zinc acetate yielded tetrabenzoporphinato zinc (ZnTBP). Tetra-tert-butyltetrabenzoporphinato zinc (ZntBu4TBP), whose four tert-butyl substituents were positioned on the TBP periphery, was also prepared in a similar way using the 4-tert-butylphthalimide potassium salt (4-tBuPIK). These results were explained on the basis of the function of zinc acetate as the meso-methine carbon source of the TBP structure. The use of zinc phenylacetate instead of zinc acetate in the reaction of PIK led to the production of meso-phenyl substituted ZnTBPs, although they were different in the number of meso-phenyl substituent(s). The attempt to introduce alkyl residues at the meso-position(s) by the reaction of PIK in the presence of zinc alkylacetate having a long alkyl chain was not successful, except for the substitution of the methyl group using zinc propionate.