thioacrylic acid S-dodecyl ester | 86887-94-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: thioacrylic acid S-dodecyl ester
• 英文别名: Thioacrylsaeure-S-dodecylester；S-dodecyl prop-2-enethioate
• CAS: 86887-94-7
• 化学式: C₁₅H₂₈OS
• 分子量: 256.453
• InChiKey: VPLWJTISKJELNZ-UHFFFAOYSA-N

物化性质

• 沸点：
  174-178 °C(Press: 11 Torr)
• 密度：
  0.908±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  17
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  thioacrylic acid S-dodecyl ester 在 clay supported ammonium nitrate "Clayan" 作用下， 反应 0.07h， 以95%的产率得到二月桂基二硫醚
  参考文献：
  名称：

  Microwave Thermolysis VII: Oxidative Coupling of Thiol Acetates and Esters Using “Clayan” in Dry Media

  摘要：

  Disulfide bond formation by the oxidative cleavage of thiol acetates and thiol esters using "Clayan" under microwave irradiation is described. The non-metallic and inexpensive nature of the reagent are the important features of the procedure.

  DOI：

  10.1080/00397919908086432
• 作为产物：
  描述：

  乙炔 、 十二硫醇 、 alkaline earth salt of/the/ methylsulfuric acid 在 溶剂黄146 、 甲苯 、 1-(Alpha-萘基)-吡咯烷 作用下， 生成 thioacrylic acid S-dodecyl ester
  参考文献：
  名称：

  Reppe,W., Acetylene Chemistry S.160

  摘要：

  DOI：

文献信息

• Michael Reactions of Titanium Enolates of Glycolic Acid Derivatives with the Weinreb and Morpholine Amides of Acrylic Acid
  作者：Anna Olivella、Carles Rodríguez-Escrich、Fèlix Urpí、Jaume Vilarrasa

  DOI：10.1021/jo702240n

  日期：2008.2.1

  The conjugate additions of titanium enolates of glycolate-derived chiral oxazolidin-2-ones to various Michael acceptors have been evaluated as an entry to enantiopure 1,2,5-trioxygenated and related synthons. α,β-unsaturated Weinreb and morpholine amides do react under suitable conditions and their adducts can be converted to diverse C1−C5 chiral fragments.

  已经评估了乙醇酸酯衍生的手性恶唑烷丁-2-酮的烯醇钛钛酸酯向各种迈克尔受体的共轭加成，作为对映体纯的1,2,5-三加氧和相关合成子的入口。α，β-不饱和Weinreb和吗啉酰胺在合适的条件下会发生反应，并且它们的加合物可以转化为不同的C1-C5手性片段。
• Multifunctional viscosity index improver derived from amido amine exhibiting low temperature viscometric properties
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0400871A1

  公开（公告）日：1990-12-05

  Composition of matter useful as a multifunctional viscosity index improver for lubricating oil comprising reaction product of: (i) (a) copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of Mw/Mn of less than 2 and a ratio of Mz/Mw of less than 1.8, and wherein at least two portions of an individual intramolecularly heterogeneous chain, each portion comprising at least 5 weight percent of said chain, differ in composition from one another by at least 7 weight percent ethylene, said copolymer grafted with (b) ethylenically monounsaturated carboxylic acid material having 1 to 2 carboxylic acid groups or anhydride group to form grafted ethylene copolymer: and (ii) amido-amine or thioamido-amine comprising reaction product of (a) polyamine, and (b) alpha, beta-unsaturated compound represented by the formula wherein X is oxygen or sulfur, Y is OR4 , -SR4, or and R1, R2, R3. R4 and R5 are independently selected from hydrogen, hydrocarbyl. and substituted hydrocarbyl.

  可用作润滑油多功能粘度指数改进剂的物质组合物，由以下物质的反应产物组成： (i) (a) 乙烯和至少另一种α-烯烃单体的共聚物，所述共聚物包括分子内异构共聚物链，其中至少含有一个亚甲基单元的可结晶段和至少一个低结晶度的乙烯-α-烯烃共聚物段、其中所述至少一个可结晶段占所述共聚物链的至少约 10 重量％，并含有至少约 57 重量％的乙烯，其中所述低结晶度段含有不大于约 53 重量％的乙烯，并且所述共聚物具有分子量分布，其特征为 Mw/Mn 之比小于 2 和 Mz/Mw 之比小于 1 中的至少一种。(b) 具有 1 至 2 个羧酸基团或酸酐基团的乙烯基单不饱和羧酸材料接枝，形成接枝乙烯共聚物：和 (ii) 氨基胺或硫代氨基胺，包括(a)多胺和(b)α、β-不饱和化合物的 反应产物，其式为 其中 X 是氧或硫，Y 是 OR4 、-SR4 或 以及 R1、R2、R3.R4 和 R5 独立选自氢、烃基和取代的烃基。
• Reppe, Justus Liebigs Annalen der Chemie, 1953, vol. 582, p. 1,13, 31
  作者：Reppe

  DOI：——

  日期：——
• US5053151A
  申请人：——

  公开号：US5053151A

  公开（公告）日：1991-10-01
• US5252238A
  申请人：——

  公开号：US5252238A

  公开（公告）日：1993-10-12