12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,21-henicosafluorohenicosanoic acid | 865-89-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,21-henicosafluorohenicosanoic acid
• 英文别名: 12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,21-Heneikosafluor-trikosansaeure-(1)；11--undecansaeure；11-(Perfluordecyl)-undecansaeure
• CAS: 865-89-4
• 化学式: C₂₁H₂₁F₂₁O₂
• 分子量: 704.363
• InChiKey: LXIIDXQMTRGFRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  44
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  23

反应信息

• 作为产物：
  描述：

  methyl 12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,21-henicosafluoro-10-iodohenicosanoate 在 palladium on activated charcoal 氢氧化钾 、 氢气 、 碳酸氢钠 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 42.0h， 生成 12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,21-henicosafluorohenicosanoic acid
  参考文献：
  名称：

  The structure and properties of hybrid fluorous-hydrocarbon fatty acids

  摘要：

  A series of long chain fatty acids is prepared with alternating blocks of fluorocarbon and hydrocarbon. This hybrid construction provides three domains (fluorous, hydrocarbon, hydrophilic) on the same molecule. The ability of the monocarboxylic acids to form monolayers on water is explored and, in selected cases, X-ray structure analysis of the dicarboxylic acids provides information on the conformation and solid state organisation of these molecules. The hybrid molecules display surface behaviour and show packing distances which are intermediate between alkyl and perfluoroalkyl chains. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2005.03.017

文献信息

• Long Chain Alkanoic and Alkenoic Acids with Perfluoroalkyl Terminal Segments¹
  作者：Neal O. Brace

  DOI：10.1021/jo01059a090

  日期：1962.12
• Ink-jet recording ink set and ink-jet recording method
  申请人：Umebayashi Tsutomu

  公开号：US20070206045A1

  公开（公告）日：2007-09-06

  An ink-jet recording ink set, comprising at least one recording liquid containing a colorant and a polymerizable compound and an ink spread suppressing liquid containing at least one surfactant and substantially no colorant, wherein all of the following conditions (A), (B) and (C) are satisfied, and an ink-jet recording method using the same: (A) the surface tension of the ink spread suppressing liquid is smaller than that of at least one recording liquid contained in the ink-jet recording ink set; (B) at least one of the surfactants contained in the ink spread suppressing liquid satisfies the following relationship: γ s (0)−γ s (saturated)>1 mN/m; and (C) the surface tension of the ink spread suppressing liquid satisfies the following relationship: γ s <(γ s (0)+γ s (saturated) max )/ 2.
• US3957672A
  申请人：——

  公开号：US3957672A

  公开（公告）日：1976-05-18
• US7645036B2
  申请人：——

  公开号：US7645036B2

  公开（公告）日：2010-01-12