12-methylbenzo[d]phenanthro[9,10-b]furan | 131003-64-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 12-methylbenzo[d]phenanthro[9,10-b]furan
• 英文别名: 17-Methyl-21-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2,4,6,8,10,12,15(20),16,18-decaene
• CAS: 131003-64-0
• 化学式: C₂₁H₁₄O
• 分子量: 282.342
• InChiKey: POSWCBBKHCCPLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-甲基-2,3-二苯基-1-苯并呋喃 生成 12-methylbenzo[d]phenanthro[9,10-b]furan
  参考文献：
  名称：

  2,3-双-（对甲氧基苯基）苯并呋喃的新型光异构化为2,6-二甲氧基-9-（2-羟苯基）蒽

  摘要：

  除预期的菲衍生物（6），新型重排蒽（5）外，使用汞灯或日光照射，在N 2下用汞灯或日光光解苯中的2,3-双-（对甲氧基苯基）苯并呋喃。

  DOI：

  10.1039/c39840000613

文献信息

• Synthesis and photochromic properties of benzofuran–phenanthrene and benzofuran–pyrene hybrids
  作者：H. Surya Prakash Rao、Satish Vijjapu

  DOI：10.1039/c4ra02435d

  日期：——

  Iron(iii) chloride mediated condensation of phenanthrene-9,10-dione and pyrene-4,5-dione with cyclohexanone and its derivatives furnish benzofuran–phenanthrene and benzofuran–pyrene hybrids.

  铁（III）氯催化下，苯并二酮和芘-4,5-二酮与环己酮及其衍生物的缩合反应生成苯并呋喃-苯并二氢萘和苯并呋喃-芘的混合物。
• Organic Compound, Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, Display Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20210139445A1

  公开（公告）日：2021-05-13

  A novel organic compound is provided. Alternatively, an organic compound that exhibits light emission with favorable chromaticity is provided. Alternatively, an organic compound that exhibits blue light emission with favorable chromaticity is provided. Alternatively, a light-emitting device with favorable emission efficiency is provided. Alternatively, an organic compound having a high carrier-transport property is provided. Alternatively, an organic compound with favorable reliability is provided. An organic compound having at least one amino group in which any one of a substituted or unsubstituted dibenzofuranyl group, a substituted or unsubstituted dibenzothiophenyl group, and a substituted or unsubstituted carbazolyl group is bonded to any one of a substituted or unsubstituted naphthobisbenzofuran skeleton, a substituted or unsubstituted naphthobisbenzothiophene skeleton, and a substituted or unsubstituted naphthobenzothienobenzofuran skeleton is provided.

  提供了一种新型有机化合物。或者提供一种表现出有利色度的光发射的有机化合物。或者提供一种表现出有利色度的蓝光发射的有机化合物。或者提供一种具有良好发射效率的发光装置。或者提供一种具有高载流子传输性能的有机化合物。或者提供一种具有良好可靠性的有机化合物。提供了一种有机化合物，其中任何一种取代或未取代的二苯并呋喃基团，取代或未取代的二苯并噻吩基团和取代或未取代的咔唑基团中的至少一个氨基与取代或未取代的萘并苯并呋喃骨架、取代或未取代的萘并苯并噻吩骨架和取代或未取代的萘苯并噻吩苯并呋喃骨架中的任何一个键合。
• Rapid Synthesis of Fused Polycyclic Heteroaromatics through Successive Vinylic/Aromatic C−F Bond Activation
  作者：Takeshi Fujita、Takuya Fukuda、Naoto Suzuki、Junji Ichikawa

  DOI：10.1002/ejoc.202200600

  日期：2022.10.7

  The synthesis of fused polycyclic heteroaromatics was achieved via successive vinylic/aromatic C−F bond activation. The Suzuki-Miyaura coupling of bromodifluoroalkenes with 2-hydroxy- or 2-aminophenylboronic acids (esters) followed by defluorinative 5-endo-trig cyclization afforded 2-fluorobenzoheteroles bearing a biaryl moiety in one-pot operation. Subsequent acid-mediated intramolecular C−F/C−H coupling

  通过连续的乙烯基/芳族C-F 键活化实现稠合多环杂芳烃的合成。溴二氟烯烃与 2-羟基或 2-氨基苯基硼酸（酯）的 Suzuki-Miyaura 偶联，然后进行脱氟 5-内三环化，在一锅操作中提供带有联芳基部分的 2-氟苯并杂环。随后的酸介导的分子内 C-F/C-H 偶联提供了四环、五环和六环杂环芳烃。
• COUTURE, AXEL;LABLACHE-COMBJER, ALAIN;POLLET, ALAIN;OFENBERG, HARRY, REV. ROUM. CHIM., 34,(1989) N1-12, C. 2087-2091
  作者：COUTURE, AXEL、LABLACHE-COMBJER, ALAIN、POLLET, ALAIN、OFENBERG, HARRY

  DOI：——

  日期：——
• WEST, P. R.;CHAUDHARY, S. K.;VERNON, J. M.;MITCHELL, R. H., J. CHEM. SOC. CHEM. COMMUN., 1984, N 9, 613-614
  作者：WEST, P. R.、CHAUDHARY, S. K.、VERNON, J. M.、MITCHELL, R. H.

  DOI：——

  日期：——