N-dodecyltryptophan | 60654-13-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-dodecyltryptophan
• 英文别名: (S)-2-(dodecylamino)-3-(1H-indol-3-yl)propanoic acid；(2S)-2-(dodecylamino)-3-(1H-indol-3-yl)propanoic acid
• CAS: 60654-13-9
• 化学式: C₂₃H₃₆N₂O₂
• 分子量: 372.551
• InChiKey: CBLOWQITVSLGAK-QFIPXVFZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  27
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  65.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-dodecyltryptophan 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 6.0h， 生成 sodium N-dodecyltryptophan
  参考文献：
  名称：

  Thermodynamic, kinetic and mechanistic approach to the corrosion inhibition of carbon steel by new synthesized amino acids-based surfactants as green inhibitors in neutral and alkaline aqueous media

  摘要：

  The inhibiting power of three synthesized amino acids based-surfactant molecules, namely, sodium N-dodecyl asparagines (AS), sodium N-dodecylhistidine (HS) and sodium N-dodecyltryptophan (TS) on the dissolution of carbon steel was inspected in 0.5 M NaCI and 05 M NaOH solutions at 25 degrees C. The methods employed in this work were weight-loss (WL), potentiodynamic polarization (PP) and electrochemical impedance spectroscopy (EIS). The chemical structures of the synthesized surfactants were confirmed by FT-IR and (HNMR)-H-1. The inhibition efficiencies were found to increase as the surfactants concentrations increase, while decreasing with increasing the concentration of the corrosive media (NaCI & NaOH) and temperature. Results obtained from the different techniques revealed that the inhibition efficiency of the compound TS was higher than those of both AS and HS. The inhibition efficiencies of the synthesized surfactants were declined in terms of strong adsorption of surfactants on the surface of carbon steel and forming a protective film and such adsorption was found to obey Langmuir isotherm. Both thermodynamic and kinetic parameters were evaluated which support the mechanism of physical adsorption of the inhibitors. The tested surfactants were found to act as mixed-type inhibitors with anodic predominance. The surface morphology of the carbon steel surface was examined by scanning electron microscopy (SEM). The inhibitory mechanism of carbon steel corrosion was suggested. Results obtained from all employed methods are consistent with each other. (C) 2018 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2018.05.140
• 作为产物：
  描述：

  十二醛 在 platinum(IV) oxide sodium hydroxide 、 氢气 作用下， 以 甲醇 、 水 、 苯 为溶剂， 反应 2.08h， 生成 N-dodecyltryptophan
  参考文献：
  名称：

  N-substituted amino acid derivatives with hyperalphalipoproteinaemic activity

  摘要：

  DOI：

  10.1016/0223-5234(88)90095-5