6-Iodo-9-p-tolyl-9H-[3,9']bicarbazolyl | 859627-72-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 6-Iodo-9-p-tolyl-9H-[3,9']bicarbazolyl
• CAS: 859627-72-8
• 化学式: C₃₁H₂₁IN₂
• 分子量: 548.426
• InChiKey: BPZDBZHPMAXZFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.79
• 重原子数：
  34.0
• 可旋转键数：
  2.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  9.86
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  6-Iodo-9-p-tolyl-9H-[3,9']bicarbazolyl 在 bis-triphenylphosphine-palladium(II) chloride 、 氢氧化钾 、 copper(l) iodide 、 三乙胺 作用下， 以 异丙醇 为溶剂， 反应 39.0h， 生成
  参考文献：
  名称：

  Carbazole–pyrene-based organic emitters for electroluminescent device

  摘要：

  Carbazole-pyrene-based compounds were synthesized and fully characterized. Their photoluminescence properties were studied. Fluorescence quantum yield was improved dramatically by inserting pyrene as electron-acceptor. Blending 9-(3-(2-(1-(2-(3-(9H-carbazol-9-yl)-9-p-tolyl-9H-carbazol-6-yl)ethynyl)pyren-6-yl)ethynyl)-9-p-tolyl-9H-carbazol-6-yl)-9H-carbazole (16) with poly(N-vinylcarbazole) (PVK), simplified electroluminescent (EL) device with green emission was fabricated. Maximum luminance reached 1000 cd/m(2). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2005.04.019
• 作为产物：
  描述：

  3,6-二碘-9-(4-甲基苯基)-9H-咔唑 、 咔唑 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 6-Iodo-9-p-tolyl-9H-[3,9']bicarbazolyl
  参考文献：
  名称：

  Carbazole–pyrene-based organic emitters for electroluminescent device

  摘要：

  Carbazole-pyrene-based compounds were synthesized and fully characterized. Their photoluminescence properties were studied. Fluorescence quantum yield was improved dramatically by inserting pyrene as electron-acceptor. Blending 9-(3-(2-(1-(2-(3-(9H-carbazol-9-yl)-9-p-tolyl-9H-carbazol-6-yl)ethynyl)pyren-6-yl)ethynyl)-9-p-tolyl-9H-carbazol-6-yl)-9H-carbazole (16) with poly(N-vinylcarbazole) (PVK), simplified electroluminescent (EL) device with green emission was fabricated. Maximum luminance reached 1000 cd/m(2). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2005.04.019

文献信息

• Blue light-emitting, electron-transporting materials based on ethynyl-linked D–A systems
  作者：Zujin Zhao、Peng Zhang、Fang Wang、Zixing Wang、Ping Lu、Wenjin Tian

  DOI：10.1016/j.cplett.2006.03.095

  日期：2006.6

  Two ethynyl-linked pi-conjugated compounds with bright blue photoluminescence property were designed, synthesized and fully characterized. The main structures of them contain a pyrene as electron acceptor, a carbazole as electron donor linked by an ethynyl unit. This D-A system has increased electron mobility and high quantum yields. One of the compounds was sandwiched as luminescent in single- and double-layer devices. By incorporating Alq as electron transport layer, the double-layer device exhibits dramatically improved performances compared with the single-layer device. The compounds are promising blue light-emitting and electron-transport materials. (c) 2006 Elsevier B.V. All rights reserved.