4,4'-bis(3-hydroxymethyl-4-methoxyphenyl)diphenyl sulfone | 1349856-61-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(3-hydroxymethyl-4-methoxyphenyl)diphenyl sulfone
• 英文别名: [5-[4-[4-[3-(Hydroxymethyl)-4-methoxyphenyl]phenyl]sulfonylphenyl]-2-methoxyphenyl]methanol
• CAS: 1349856-61-6
• 化学式: C₂₈H₂₆O₆S
• 分子量: 490.577
• InChiKey: FEXQVFXGKHOCRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  101
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4,4'-bis(3-hydroxymethyl-4-methoxyphenyl)diphenyl sulfone 在 吡啶 、 甲醇 、 4-二甲氨基吡啶 、 sodium hydride 、 对甲苯磺酸 、 4-甲氧基苯酚 作用下， 以 四氢呋喃 、 氯仿 、 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 31.0h， 生成 4,4'-bis((3-(2-methacryloyloxyethoxy)methyl)-4-methoxyphenyl)diphenyl sulfone
  参考文献：
  名称：

  OPTICAL ELEMENT COMPOUND, OPTICAL MATERIAL, AND OPTICAL ELEMENT

  摘要：

  提供具有以下特征的光学材料有机化合物：折射率的色散特性（阿贝数（νd））和二次色散特性（θg,F）高，可见光区域的透射率高，色差校正功能性能高，其通用公式（1）或（2）表示。

  公开号：

  US20110288330A1
• 作为产物：
  描述：

  2,2'-磺酰基二苯酚 在 四(三苯基膦)钯 甲醇 、 sodium tetrahydroborate 、 碳酸氢钠 、 三乙胺 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 氯仿 、 水 为溶剂， 反应 11.0h， 生成 4,4'-bis(3-hydroxymethyl-4-methoxyphenyl)diphenyl sulfone
  参考文献：
  名称：

  OPTICAL ELEMENT COMPOUND, OPTICAL MATERIAL, AND OPTICAL ELEMENT

  摘要：

  提供具有以下特征的光学材料有机化合物：折射率的色散特性（阿贝数（νd））和二次色散特性（θg,F）高，可见光区域的透射率高，色差校正功能性能高，其通用公式（1）或（2）表示。

  公开号：

  US20110288330A1

文献信息

• (METH)ACRYLATE COMPOUND, OPTICAL COMPOSITION, MOLDED ARTICLE, AND OPTICAL ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150175731A1

  公开（公告）日：2015-06-25

  An optical element including a molded article is provided, the molded article being prepared by molding a polymer prepared by polymerizing a (meth)acrylate compound represented at least by the following general formula (1): wherein a and b are each an integer of 1 or 2; X and Y are each —S— or —O—; R 1 and R 2 are each an alkyl group having 1 or 2 carbon atoms or a hydrogen atom; and Z 1 and Z 2 are each an alkyl group having 1 or 2 carbon atoms, having a substituent and represented by the following general formula (2): wherein m is selected from 0 and 1; W is a hydrogen atom or a methyl group; and V is selected from substituents represented by the following: *—O—C n H 2n —O—**; *—S—C n H 2n —S—**; and *—S—C n H 2n —O—**, wherein * represents a bond with an alkyl group; ** represents a bond with a (meth)acryloyl group; n is selected from 2, 3 and 4; and at least one hydrogen atom of —C n H 2n — is replaced by a methyl group.

  提供一种包括模压件的光学元件，所述模压件是通过模压聚合至少由以下一般式（1）所表示的（甲基）丙烯酸酯化合物制备的聚合物而制备的：其中a和b均为1或2的整数；X和Y均为—S—或—O—；R1和R2均为具有1或2个碳原子的烷基或氢原子；Z1和Z2均为具有1或2个碳原子的烷基，具有取代基且由以下一般式（2）表示：其中m从0和1中选取；W为氢原子或甲基基团；V从以下所表示的取代基中选取：*—O—CnH2n—O—**；*—S—CnH2n—S—**；和*—S—CnH2n—O—**，其中*表示与烷基的键；**表示与（甲基）丙烯酰基的键；n从2、3和4中选取；并且—CnH2n—的至少一个氢原子被甲基基团取代。
• Optical element compound, optical material, and optical element
  申请人：Canon Kabushiki Kaisha

  公开号：EP2390684A2

  公开（公告）日：2011-11-30

  An optical material organic compound having characteristics that the dispersion characteristic (Abbe number) and the secondary dispersion characteristic (θg,F) of the refractive index are high, the transmittance in the visible light region is high, and the chromatic aberration correction function delivers high performance, which represented by the general formula (1) or (2) is provided.

  提供了一种光学材料有机化合物，它具有折射率色散特性（阿贝数）和二次色散特性（θg,F）高、可见光区域透射率高、色差校正功能性能高的特点，由通式（1）或（2）表示。
• Optical composition, cured product, and optical element
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10370474B2

  公开（公告）日：2019-08-06

  Provided is a cured product having the following characteristics: the dispersion characteristic and secondary dispersion characteristic of refractive indices are high, the cured product hardy crystallizes, and a chromatic aberration-correcting function is high. The cured product contains at least a structure represented by the general formula (4) and a structure represented by the general formula (5), in which a content of the structure represented by the general formula (5) in the cured product is 0.01 or more and 0.10 or less in terms of a substance amount ratio with respect to the structure represented by the general formula (4).

  本发明提供了一种具有以下特性的固化物：折射率的色散特性和二次色散特性高，固化物不易结晶，色差校正功能高。固化物至少包含通式（4）表示的结构和通式（5）表示的结构，其中通式（5）表示的结构在固化物中的含量为 0.01 或以上，而通式（4）表示的结构的物质的量比为 0.10 或以下。
• Method of Treating Kcnq Related Disorders Using Organozinc Compounds
  申请人：Li Min

  公开号：US20110257146A1

  公开（公告）日：2011-10-20

  The instant invention describes methods of treating KCNQ related diseases and disorders using organozinc compounds. In certain embodiments, pain is treated using Zinc Pyrithione.
• OPTICAL COMPOSITION, CURED PRODUCT, AND OPTICAL ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170320984A1

  公开（公告）日：2017-11-09

  Provided is a cured product having the following characteristics: the dispersion characteristic and secondary dispersion characteristic of refractive indices are high, the cured product hardy crystallizes, and a chromatic aberration-correcting function is high. The cured product contains at least a structure represented by the general formula (4) and a structure represented by the general formula (5), in which a content of the structure represented by the general formula (5) in the cured product is 0.01 or more and 0.10 or less in terms of a substance amount ratio with respect to the structure represented by the general formula (4).