2-(3,3,4,4,5,5,6,6,6-nonafluorohexylthio) ethyl acrylate | 866208-89-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(3,3,4,4,5,5,6,6,6-nonafluorohexylthio) ethyl acrylate
• 英文别名: 2-[(3,3,4,4,5,5,6,6,6-Nonafluorohexyl)sulfanyl]ethyl prop-2-enoate；2-(3,3,4,4,5,5,6,6,6-nonafluorohexylsulfanyl)ethyl prop-2-enoate
• CAS: 866208-89-1
• 化学式: C₁₁H₁₁F₉O₂S
• 分子量: 378.259
• InChiKey: WXSKBLDZTUFRII-UHFFFAOYSA-N

物化性质

• 沸点：
  273.2±40.0 °C(Predicted)
• 密度：
  1.391±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  Sodium thiosulfate pentahydrate 、 2-(3,3,4,4,5,5,6,6,6-nonafluorohexylthio) ethyl acrylate 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以63.1%的产率得到2-(3,3,4,4,5,5,6,6,6-nonafluorohexylsulfonyl)ethyl acrylate
  参考文献：
  名称：

  SURFACE TREATING AGENT, FLUORINE-CONTAINING MONOMER AND FLUORINE-CONTAINING POLYMER

  摘要：

  公开号：

  EP1739143B1
• 作为产物：
  描述：

  对叔丁基邻苯二酚 、 2-[(3,3,4,4,5,5,6,6,6-nonafluorohexyl)sulfanyl]ethanol 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以85.7%的产率得到2-(3,3,4,4,5,5,6,6,6-nonafluorohexylthio) ethyl acrylate
  参考文献：
  名称：

  SURFACE TREATING AGENT, FLUORINE-CONTAINING MONOMER AND FLUORINE-CONTAINING POLYMER

  摘要：

  公开号：

  EP1739143B1

文献信息

• FLUOROPOLYMER AND SOIL REMOVER
  申请人：Uesugi Norimasa

  公开号：US20090256102A1

  公开（公告）日：2009-10-15

  A fluorocopolymer formed from, as essential ingredients, (a) a fluoromonomer represented by the general formula: CH 2 ═C(—X)—C(—O)—Y—[—(CH 2 ) m -Z-] p -(CH 2 ) n —Rf  (1) [wherein X is hydrogen, C 1-21 linear or branched alkyl, fluorine, chlorine, bromine, iodine, —CFX 1 X 2 (wherein X 1 and X 2 each is hydrogen, fluorine, chlorine, bromine, or iodine), cyano, C 1-21 linear or branched fluoroalkyl, (un)substituted benzyl, or (un)substituted phenyl; Y is —O— or —NH—; Z is —S— or —SO 2 —; Rf is C 1-21 fluoroalkyl; m is 1-10; n is 0-10; and p is 0 or 1] and (b) a polyalkylene glycol (meth)acrylate. A soil remover containing this fluorocopolymer imparts to a woven fabric, etc. excellent oil repellency, unsusceptibility to fouling, and the property of releasing stains therefrom, while maintaining durability in washing.

  由(a)一种由通式CH2═C(—X)—C(—O)—Y—[—(CH2)m-Z-]p-(CH2)n—Rf  (1)[其中X为氢、C1-21线性或支链烷基、氟、氯、溴、碘、—CFX1X2（其中X1和X2分别为氢、氟、氯、溴或碘）、氰基、C1-21线性或支链氟烷基、（未）取代苄基或（未）取代苯基；Y为—O—或—NH—；Z为—S—或—SO2—；Rf为C1-21氟烷基；m为1-10；n为0-10；p为0或1]组成的氟共聚物和(b)一种聚烷基乙二醇（甲基）丙烯酸酯。含有这种氟共聚物的除污剂赋予织物等优异的防油性、不易污染的性质和释放污渍的性质，同时保持耐洗涤性。
• Surface treating agent, fluorine-containing monomer and fluorine-containing polymer
  申请人：Yamamoto Ikuo

  公开号：US20070173148A1

  公开（公告）日：2007-07-26

  Disclosed is a surface treating agent containing fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing compound which is represented by the following formula: CH 2 ═C(—X)—C(═O)—Y—[—(CH 2 ) m -Z-] p —(CH 2 ) n —Rf  (I) (wherein X is a hydrogen atom or a methyl group), (B) a repeating unit derived from a monomer containing no fluorine atom, if necessary and (C) a repeating unit derived from a crosslinkable monomer, if necessary. This surface treating agent has excellent water repellency, oil repellency and antifouling property.
• US7638575B2
  申请人：——

  公开号：US7638575B2

  公开（公告）日：2009-12-29
• SURFACE TREATING AGENT, FLUORINE-CONTAINING MONOMER AND FLUORINE-CONTAINING POLYMER
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1739143B1

  公开（公告）日：2012-01-11