aquomalatocopper | 67770-36-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羟基酸及其衍生物
• 英文名称: aquomalatocopper
• CAS: 67770-36-9
• 化学式: C₄H₄O₅*Cu*H₂O
• 分子量: 213.634
• InChiKey: FSKMJJMWGIMBCL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.59
• 重原子数：
  11.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  131.99
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  aquomalatocopper 以 neat (no solvent) 为溶剂， 生成 Copper(2+) but-2-enedioate 、 水
  参考文献：
  名称：

  The possibility of resolving overlapping decomposition reactions by the kinetic plots of thermogravimetric data

  摘要：

  DOI：

  10.1016/0040-6031(83)80238-x
• 作为产物：
  描述：

  copper(II) carbonate 、 苹果酸 在 水 作用下， 以 not given 为溶剂， 生成 aquomalatocopper
  参考文献：
  名称：

  THE SALTS OF MALEIC, FUMARIC AND INACTIVE MALIC ACIDS

  摘要：

  DOI：

  10.1021/ja01663a015

文献信息

• Electrochemical Synthesis of Complex Compounds of Transition Elements with Carboxyl- and Carbonyl-containing Ligands
  作者：V. Yu. Frolov、S. N. Bolotin、V. T. Panyshkin

  DOI：10.1007/s11167-005-0416-7

  日期：2005.6

  Complex compounds of d- and f-elements with carboxyl- and carbonyl-containing ligands were synthesized by the electrochemical method. The influence exerted by a number of factors on the process course was studied. The dependence of the electrosynthesis parameters on the composition of the forming compounds was established. The composition of these compounds was determined. A new method for anodic synthesis of these compounds was developed.

  采用电化学方法合成了 d 元素和 f 元素与含羧基和羰基配体的复合物。研究了多种因素对合成过程的影响。确定了电合成参数对形成的化合物组成的依赖性。确定了这些化合物的组成。开发了阳极合成这些化合物的新方法。
• Supramolecular networks through second-sphere coordination based on 1D metal-4,4′-dipyridyldisulfide coordination polymers and hydrogenfumarate or sulfonate anions
  作者：Rosa Carballo、Nuria Fernández-Hermida、Ana B. Lago、Sabina Rodríguez-Hermida、Ezequiel M. Vázquez-López

  DOI：10.1016/j.poly.2011.09.008

  日期：2012.1

  Four hydrogen-bonded assemblies of formula [M(dpds)(2)(OH2)(2)]A(2)center dot nH(2)O (A = anion) are described. These assemblies result from the second-sphere coordination interactions between the 1D coordination polymers [M(dpds)(2)(OH2)(2)](2+), M = Zn(II) and Cu(II). dpds = 4,4'-dipyridyldisulfide, and the pyridine-3-sulfonate (3pySO(3)(-)) or hydrogenfumarate (Hfum(-)) anions. Significantly, supramolecular structural variations are observed depending on the presence of water lattice molecules, which formed discrete aggregates when the Hfum(-) anion was used. The effects of geometrical variations in the building blocks are also evident on using Jahn-Teller-distorted divalent Cu(II) ions or regular octahedral species based on Zn(II) ions. The second-sphere effects on the stabilization of the compounds are illustrated by TGA experiments. (C) 2011 Elsevier Ltd. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B2, 67, page 768 - 772
  作者：

  DOI：——

  日期：——