ethyl 2-cyano-3-ethyloctanoate | 132640-59-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: ethyl 2-cyano-3-ethyloctanoate
• CAS: 132640-59-6
• 化学式: C₁₃H₂₃NO₂
• 分子量: 225.331
• InChiKey: VSISOUGUYVVPDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  16.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  50.09
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  2-辛烯 、 氰乙酸乙酯 在 manganese(II) acetate sodium acetate 作用下， 以 溶剂黄146 、 乙酸乙酯 为溶剂， 生成 2-氰基-3-甲基壬酸乙酯 、 ethyl 2-cyano-3-ethyloctanoate
  参考文献：
  名称：

  Carbon—carbon bond formation using manganese(iii) acetate as an electrochemical mediator

  摘要：

  Anodic oxidation in a solution containing a variety of olefins and a small amount of Mn(OAc)2.4H2O brought about Mn+3-mediated carbon-carbon bond formation, such as efficient carboxymethylation of styrene derivatives to the corresponding gamma-aryl-gamma-butyrolactones, and selective coupling of active methylene compounds with non-activated monoolefins, unconjugated dienes or 5-arylpent-1-enes.

  DOI：

  10.1016/s0040-4020(01)87071-x

文献信息

• Shundo, Ryushi; Nishiguchi, Ikuzo; Matsubara, Yoshiharu, Chemistry Letters, 1990, # 12, p. 2285 - 2288
  作者：Shundo, Ryushi、Nishiguchi, Ikuzo、Matsubara, Yoshiharu、Hirashima, Tsuneaki

  DOI：——

  日期：——
• SHUNDO, RYUSHI;NISHIGUCHI, IKUZO;MATSUBARA, YOSHIHARU;HIRASHIMA, TSUNEAKI, CHEM. LETT.,(1990) N2, C. 2285-2288
  作者：SHUNDO, RYUSHI、NISHIGUCHI, IKUZO、MATSUBARA, YOSHIHARU、HIRASHIMA, TSUNEAKI

  DOI：——

  日期：——
• Carbon—carbon bond formation using manganese(iii) acetate as an electrochemical mediator
  作者：Ryushi Shundo、Ikuzo Nishiguchi、Yoshiharu Matsubara、Tsuneaki Hirashima

  DOI：10.1016/s0040-4020(01)87071-x

  日期：——

  Anodic oxidation in a solution containing a variety of olefins and a small amount of Mn(OAc)2.4H2O brought about Mn+3-mediated carbon-carbon bond formation, such as efficient carboxymethylation of styrene derivatives to the corresponding gamma-aryl-gamma-butyrolactones, and selective coupling of active methylene compounds with non-activated monoolefins, unconjugated dienes or 5-arylpent-1-enes.