2,2-二氯-3,3-二甲基环丙烷-1-羧酸 | 39871-97-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2,2-二氯-3,3-二甲基环丙烷-1-羧酸
• 英文名称: 2,2-dimethyl-3,3-dichlorocyclopropanecarboxylic acid
• 英文别名: 2,2-dichloro-3,3-dimethylcyclopropanecarboxylic acid；2,2-Dimethyl-3,3-dichlorcyclopropancarbonsaeure；Cyclopropanecarboxylic acid, 2,2-dichloro-3,3-dimethyl-；2,2-dichloro-3,3-dimethylcyclopropane-1-carboxylic acid
• CAS: 39871-97-1
• 化学式: C₆H₈Cl₂O₂
• 分子量: 183.034
• InChiKey: YUBCVMNXGPVXID-UHFFFAOYSA-N

物化性质

• 熔点：
  131 °C
• 沸点：
  228.3±30.0 °C(Predicted)
• 密度：
  1.42±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  梨醇酯 在 sodium hydroxide 、 potassium permanganate 、 苄基三乙基氯化铵 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 4.17h， 生成 2,2-二氯-3,3-二甲基环丙烷-1-羧酸
  参考文献：
  名称：

  A new pathway for the synthesis of 2,2-dimethyl-3,3-dichlorocyclopropanecarboxylic acid

  摘要：

  DOI：

  10.1007/bf00955858

文献信息

• 6-phenyl-pyrazolopyrimidines
  申请人：BASF Corporation

  公开号：US20020049318A1

  公开（公告）日：2002-04-25

  6-Phenyl-Pyrazolopyrimidines of formula I 1 wherein R 1 is alkyl, alkenyl, alkynyl, alkadienyl or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, where these radicals may be unsubstituted or substituted as defined in the specification, Y is oxygen, sulfur, NR 2 or a single bond; wherein R 2 is defined in the specification; and R 1 and R 2 together with the interjacent nitrogen atom may represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted by one or more R C radicals; m is 0 or an integer from 1 to 4; L each independently is halogen, nitro, alkyl, alkoxy, and X is halogen; processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic fungi are described.

  式I1中的6-苯基吡唑吡嘧啶，其中R1是烷基、烯基、炔基、烯二烯基或卤代烷基、环烷基、双环烷基、苯基、萘基，或含有一到四个氮原子或一个到三个氮原子和一个硫或氧原子的5-或6-成员杂环基，这些基团可以未取代或根据规范中定义的取代，Y是氧、硫、NR2或单键；其中R2在规范中定义；R1和R2连同相邻的氮原子可以代表一个含有一到四个氮原子或一个到三个氮原子和一个硫或氧原子的5-或6-成员杂环环，可以被一个或多个RC基团取代；m为0或1到4的整数；L各自独立地是卤素、硝基、烷基、烷氧基，X是卤素；描述了制备这些化合物的方法和中间体，包含它们的组合物及其用于控制植物病原真菌的用途。
• Fungicidal 5-phenyl substituted 2-(cyanoamino) pyrimidines
  申请人：BASF Aktiengesellschaft

  公开号：US20030088096A1

  公开（公告）日：2003-05-08

  Pyrimidines of formula I 1 in which R 1 represents hydrogen or alkyl, haloalkyl, alkenyl, alkynyl, alkadienyl, alkoxy, cycloalkyl, phenyl, or 5- or 6-membered heteroaryl or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or tri-alkyl-silyl, formyl or alkoxycarbonyl, wherein R 1 groups are unsubstituted or substituted as defined in the specification; R 2 represents phenyl, cycloalkyl or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which are unsubstituted or substituted; R 3 represents hydrogen, halogen or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino; which are unsubstituted or substituted; R 4 represents hydrogen or alkyl, alkenyl or alkynyl; which are unsubstituted or substituted; and x represents O, S, NRS or a single bond, wherein R 5 represents hydrogen or alkyl; or R 1 and R 5 together with the interjacent nitrogen atom form a heterocyclic ring; processes and intermediates for preparing these compounds, to compositions comprising them and to their use for controlling harmful fungi.

  式I1中的嘧啶，其中R1代表氢或烷基，卤代烷基，烯基，炔基，烷二烯基，烷氧基，环烷基，苯基，或含有一到四个氮原子或一到三个氮原子和一个硫或氧原子的5-或6-成员杂芳基或5-或6-成员杂环烷基，或三烷基硅基，甲酰基或烷氧羰基，其中R1基团未取代或如规范中所定义的取代；R2代表苯基，环烷基或含有一到四个氮原子或一到三个氮原子和一个硫或氧原子的5-或6-成员杂芳基，未取代或取代；R3代表氢，卤素或烷基，烷氧基，烷硫基，烷基氨基或二烷基氨基；未取代或取代；R4代表氢或烷基，烯基或炔基；未取代或取代；x代表O，S，NRS或单键，其中R5代表氢或烷基；或R1和R5与相邻的氮原子一起形成杂环环；用于制备这些化合物的方法和中间体，包括它们的组合物以及用于控制有害真菌的用途。
• Enhancement of the efficacy of benzoylbenzenes
  申请人：——

  公开号：US20020028778A1

  公开（公告）日：2002-03-07

  The invention relates to method for the enhancement of the activity and/or systemicity of fungicidal compositions containing at least one benzoylbenzene of formula I 1 wherein R 1 through R 7 , m and n are as defined in claim 1 , with the aid of one or more adjuvants selected from the group consisting of (a) alkylpolyglycosides, alkenyl succinic acid derivatives, dialkyl sulfosuccinates, polyvinylpyrrolidones, perfluoroalkyl acids derivatives, perfluoro(C 3-20 )alkyl esters of carboxylic acids, and mixtures thereof; (b) alkoxylated alcohols, amines or acids; (c) water-immiscible polar aprotic solvents; and to the use of such a composition as a fungicide.

  本发明涉及一种用于增强含有至少一种I1式苯甲酰苯的杀菌剂组合物的活性和/或系统性的方法，其中R1至R7，m和n如权利要求1所定义，借助于从以下组中选择的一种或多种助剂：（a）烷基多糖苷，烯丙基琥珀酸衍生物，二烷基磺酸酯，聚乙烯吡咯烷酮，全氟烷基酸衍生物，全氟（C3-20）羧酸酯和其混合物；（b）烷氧基化的醇，胺或酸；（c）不溶于水的极性无水溶剂；以及将这样的组合物用作杀菌剂的用途。
• Aqueous suspension concentrate
  申请人：BASF Aktiengesellschaft

  公开号：US20030060514A1

  公开（公告）日：2003-03-27

  The invention relates to an aqueous, concentrated suspension (SC) for crop protection active compounds which comprises (a) 50 to 400 g/L of at least one crop protection active compound; (b) 50 to 500 g/L of at least one adjuvant, which reduces the surface tension in the spray dilution 40 mN/m or less and does not promote the particle growth of the crop protection active compound; (c) at least one surfactant selected from the groups (c1) and (c2): (c1) 5 to 75 g/L of one or more non-ionic dispersants, (c2) 10 to 100 g/L of one or more anionic dispersants, (d) up to 150 g/L of one or more anti-freezing agents, (e) up to 25 g/L of one or more defoamers, (f) up to 25 g/L of one or more preservatives, and (g) 200 to 800 g/L of water, wherein the adjuvant (b) is selected from the group consisting of amine alkoxylates, polyoxyalkylene triglycerides, alkylpolyglycosides, alkenyl succinic anhydride derivatives, polyvinylpyrrolidones, perfluoroalkyl acids derivatives, and mixtures thereof; and to the use of such a concentrate suspension as a pesticide.

  本发明涉及一种用于农作物保护活性化合物的水性浓缩悬浮液（SC），其包括（a）50至400克/升的至少一种农作物保护活性化合物；（b）50至500克/升的至少一种辅助剂，其在喷雾稀释液中降低表面张力至40mN/m或以下，并且不促进农作物保护活性化合物的颗粒生长；（c）至少一种从组（c1）和（c2）中选择的表面活性剂：（c1）5至75克/升的一种或多种非离子分散剂，（c2）10至100克/升的一种或多种阴离子分散剂；（d）多达150克/升的一种或多种防冻剂；（e）多达25克/升的一种或多种消泡剂；（f）多达25克/升的一种或多种防腐剂；和（g）200至800克/升的水，其中辅助剂（b）选自胺烷氧基化物，聚氧烷三酸甘油酯，烷基多聚糖苷，烯基琥珀酸酐衍生物，聚乙烯吡咯烷酮，全氟烷基酸衍生物和其混合物的组。本发明还涉及将这种浓缩悬浮液用作杀虫剂的用途。
• 6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines
  申请人：BASF Corporation

  公开号：US20020061882A1

  公开（公告）日：2002-05-23

  6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines of formula I 1 in which R 1 and R 2 independently denote hydrogen or alkyl, alkenyl, alkynyl, alkadienyl, or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or where R 1 and R 2 radicals may be unsubstituted or substituted as defined in the specification; or R 1 and R 2 together with the interjacent nitrogen atom represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted as defined in the specification; R 3 is hydrogen, halogen, alkyl, alkoxy and haloalkyl; and X is halogen; processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic fungi are described.

  公式I1中的6-(2-三氟甲基苯基)-三唑嘧啶，其中R1和R2独立地表示氢或烷基，烯基，炔基，烷二烯基或卤代烷基，环烷基，双环烷基，苯基，萘基或5-或6-成员杂芳基，含有一到四个氮原子或一个氮原子和一个硫或氧原子，或5-或6-成员杂芳基，含有一到四个氮原子或一个氮原子和一个硫或氧原子，或其中R1和R2基团可以未被取代或按规范中定义被取代；或R1和R2与相邻的氮原子一起代表一个5-或6-成员杂环，其中包含一到四个氮原子或一个氮原子和一个硫或氧原子，可以按规范中定义被取代；R3是氢，卤素，烷基，烷氧基和卤代烷基；X是卤素；描述了制备这些化合物的过程和中间体，包含它们的组合物以及它们用于控制植物病原真菌的用途。