2-乙基十一醇 | 54381-03-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-乙基十一醇
• 英文名称: 2-ethylundecan-1-ol
• 英文别名: 2-ethyl-undecan-1-ol；3-Hydroxymethyl-dodecan；2-Aethyl-undecan-1-ol
• CAS: 54381-03-2
• 化学式: C₁₃H₂₈O
• 分子量: 200.365
• InChiKey: OVNMDGHHVKQVQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-乙基十一醇 在 草酰氯 、 二甲基亚砜 作用下， 以 二氯甲烷 为溶剂， 反应 0.25h， 以97%的产率得到2-乙基十一烷醛
  参考文献：
  名称：

  Massy-Westropp, Ralph A.; Warren, Richard F.O., Australian Journal of Chemistry, 1984, vol. 37, # 5, p. 1023 - 1034

  摘要：

  DOI：
• 作为产物：
  描述：

  十一醛 在 乙醚 、 乙醇 、 sodium amide 、 铂 作用下， 生成 2-乙基十一醇
  参考文献：
  名称：

  Stoll, Helvetica Chimica Acta, 1947, vol. 30, p. 997

  摘要：

  DOI：

文献信息

• [EN] BRANCHED ADIPIC ACID BASED ESTERS AS NOVEL BASE STOCKS AND LUBRICANTS<br/>[FR] ESTERS À BASE D'ACIDE ADIPIQUE RAMIFIÉ UTILISÉS EN TANT QUE NOUVELLES HUILES DE BASE ET LUBRIFIANTS
  申请人：BASF SE

  公开号：WO2019110355A1

  公开（公告）日：2019-06-13

  The presently claimed invention is directed to the use of branched adipic acid esters as lubricants as well as lubricant compositions containing the branched adipic acid esters.

  目前所声称的发明涉及使用分支脂肪族己二酸酯作为润滑剂，以及包含分支脂肪族己二酸酯的润滑剂组合物。
• Ascorbic acid derivatives and skin-whitening cosmetics
  申请人：Shibayama Hiroharu

  公开号：US20060264407A1

  公开（公告）日：2006-11-23

  It is an object to provide an L-ascorbic acid derivative which can keep the L-ascorbic acid stable to heat and light and thus has a long shelf life, which is high in permeability into the skin, which can be quickly hydrolyzed by phosphatase, an enzyme that is ubiquitous in vivo, and which exhibits physiological activities that are inherent to L-ascorbic acid and beneficial to health, a method for producing such an L-ascorbic acid derivative, and a skin-whitening cosmetic material. There is provided an ascorbic acid derivative comprising an L-ascorbic acid-2-phosphate ester or a salt thereof wherein the phosphate ester has a branched alkyl group, the L-ascorbic acid-2-phosphate ester being of formula [13]. The ascorbic acid derivative is produced by a method comprising reacting a branched alkanol with phosphorus oxychloride to synthesize monoalkyldichlorophosphate or dialkylmonochlorophosphate, reacting the thus obtained substance with 5,6-O-isopropylidene-L-ascorbic acid obtained by reacting L-ascorbic acid with acetone, and subjecting the thus obtained substance to acid hydrolysis. There is also provided a cosmetic material containing such an ascorbic acid derivative by 0.05 to 80 percent by weight. (wherein each of R 1 and R 2 is a hydrogen (H) atom or an alkyl group having branches and including 3 to 30 carbon atoms, but not both of R 1 and R 2 are hydrogen (H) atoms)

  本发明旨在提供一种L-抗坏血酸衍生物，该衍生物可以使L-抗坏血酸在热和光下保持稳定性，因此具有长时间的保质期，其渗透性高，可以快速被磷酸酶水解，磷酸酶是普遍存在于体内的酶，并且具有固有于L-抗坏血酸的生理活性和有益于健康的功效，以及生产这种L-抗坏血酸衍生物的方法和美白皮肤的化妆品材料。提供一种抗坏血酸衍生物，包括L-抗坏血酸-2-磷酸酯或其盐，其中磷酸酯具有支链烷基，L-抗坏血酸-2-磷酸酯的化学式为[13]。通过将支链醇与氧化氯磷反应合成单烷基二氯磷酸酯或双烷基单氯磷酸酯，将所得物质与通过将L-抗坏血酸与丙酮反应得到的5,6-O-异丙基-L-抗坏血酸反应，并将所得物质进行酸水解制备出该抗坏血酸衍生物。还提供了一种化妆品材料，其中包含0.05至80重量百分比的抗坏血酸衍生物。（其中R1和R2中的每一个是氢（H）原子或具有分支的烷基，包括3至30个碳原子，但R1和R2中不同时存在氢（H）原子）
• RESIN COMPOSITION
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3438992A1

  公开（公告）日：2019-02-06

  A resin composition for insulating coating material, comprises: a polyimide resin and/or a precursor thereof; and a polymer having a heterocyclic ring at a side chain, wherein the content of the polymer having a heterocyclic ring at a side chain is 0.1 to 7 parts by weight relative to 100 parts by weight of the polyimide resin and/or the precursor thereof. By adding a prescribed amount of the polymer having a heterocyclic ring at a side chain, there can be obtained a resin composition for insulating coating material still maintaining heat resistance and together having excellent bending resistance.

  一种用于绝缘涂层材料的树脂组合物包括：聚酰亚胺树脂和/或其前体；以及侧链上具有杂环的聚合物，其中相对于 100 重量份的聚酰亚胺树脂和/或其前体，侧链上具有杂环的聚合物的含量为 0.1 至 7 重量份。通过添加规定量的侧链上具有杂环的聚合物，可获得一种用于绝缘涂层材料的树脂组合物，该树脂组合物仍能保持耐热性，同时具有优异的抗弯曲性。
• LIQUID HAND DISHWASHING DETERGENT COMPOSITION
  申请人：The Procter & Gamble Company

  公开号：EP3919594A1

  公开（公告）日：2021-12-08

  The need for a liquid detergent composition suitable for washing dishes, fitting both in-sink as well as direct application habits, which provides reduced smearing when used in direct application dishwashing methods, while having good suds mileage especially under in-sink application habit, and good viscosity, is met by formulating the liquid detergent composition to comprise a surfactant system, which comprises an alkyl sulfate anionic surfactant comprising C13 alkyl sulfate anionic surfactant, the C13 alkyl sulfate anionic surfactant comprising a specific fraction of 2-branched C13 alkyl sulfate anionic surfactant, with a specific distribution of the 2-branching.

  需要一种适用于清洗餐具的液体洗涤剂组合物，既适合水槽内使用，也适合直接使用的习惯，在直接使用的餐具清洗方法中使用时，可减少沾污，同时具有良好的起泡里程，特别是在水槽内使用的习惯下，以及良好的粘度、通过配制包含表面活性剂体系的液体洗涤剂组合物，该表面活性剂体系由硫酸烷基阴离子表面活性剂组成，硫酸烷基阴离子表面活性剂包括 C13硫酸烷基阴离子表面活性剂，C13硫酸烷基阴离子表面活性剂包括特定比例的 2-支链C13硫酸烷基阴离子表面活性剂，2-支链的具体分布情况。
• Concentrated shampoo dosage of foam for providing hair care benefits comprising an anionic/zwitterionic surfactant mixture
  申请人：The Procter & Gamble Company

  公开号：US10653590B2

  公开（公告）日：2020-05-19

  Described herein is dosage of foam including from about 5 cm3 to about 70 cm3 of the foam. The foam includes from about 0.5 g to about 4 g of a detersive surfactant; from about 0.001 g to about 4 g propellant; a foam density of from about 0.04 g/cm3 to about 0.23 g/cm3; and a bubble size distribution having an R32 of from about 30 μm to about 60 μm.

  本文描述的泡沫用量包括约 5 cm3 至约 70 cm3 的泡沫。泡沫包括约 0.5 克至约 4 克的去污表面活性剂；约 0.001 克至约 4 克的推进剂；约 0.04 克/立方厘米至约 0.23 克/立方厘米的泡沫密度；以及 R32 为约 30 微米至约 60 微米的气泡大小分布。