3-(6-hydroxyhexyl)-thiophene | 88940-95-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3-(6-hydroxyhexyl)-thiophene
• 英文别名: 3-(6-hydroxyhexyl)thiophene；6-thiophen-3-ylhexan-1-ol；3-thiophenehexanol；6-(Thiophen-3-yl)hexan-1-ol
• CAS: 88940-95-8
• 化学式: C₁₀H₁₆OS
• 分子量: 184.302
• InChiKey: DIAJAQCMSQHEBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  48.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(6-hydroxyhexyl)-thiophene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以82%的产率得到2,5-Dibromo-3-(6-hydroxyhexyl)thiophene
  参考文献：
  名称：

  A regioregular polyalkylthiophene bearing covalently-linked biotin, and its interaction with avidin in solution and in thin films

  摘要：

  3-己基噻吩和 3-(6-羟基己-1-基)噻吩的立体规整共聚物已用生物素酰肼功能化；抗生物素蛋白与生物素部分的结合导致溶液中聚合物的吸收光谱以及薄膜中聚合物的电化学和电导率发生巨大变化。

  DOI：

  10.1039/b408935a
• 作为产物：
  描述：

  3-(6-bromohexyl)thiophene 在 sodium acetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 3-(6-hydroxyhexyl)-thiophene
  参考文献：
  名称：

  具有黄绿色发光特性和良好的热稳定性的新型交联导电聚噻吩

  摘要：

  成功合成了一种新型的共轭聚噻吩衍生物，其具有通过烷基间隔基连接到聚合物主链上的聚甲基丙烯酸酯。制备了甲基丙烯酸酯取代的噻吩单体3-（甲基丙烯酸己酯）噻吩，并通过自由基聚合反应进行聚合，然后进行电化学聚合反应。所得的聚合物为黄绿色发光体，在光电领域具有潜在的应用。

  DOI：

  10.1002/cjoc.201180345
• 作为试剂：
  描述：

  6-(3-thiophenyl)-5-hexyn-1-ol 在 钯 3-(6-hydroxyhexyl)-thiophene 作用下， 以 乙醇 为溶剂， 反应 8.0h， 以to give 6.9 g (80%) of 3-thiophenehexanol, bp 135°-147° C./0.2 mm的产率得到3-(6-hydroxyhexyl)-thiophene
  参考文献：
  名称：

  Pyrido[2,1-b]quinazoline derivatives useful as agents for treatment of

  摘要：

  本文描述了式子##STR1##中R.sub.1，R.sub.2和R.sub.3的衍生物。 公式I和II的化合物可用作过敏症的治疗剂以及涉及血栓形成的血管障碍的治疗剂。

  公开号：

  US04551460A1

文献信息

• Novel Cross-Linked Conducting Polythiophene with Yellow-Green-Light-Emitting Properties and Good Thermal Stability
  作者：Cunyuan Lai、Wenjuan Guo、Xinde Tang、Guangyou Zhang、Qiwei Pan、Meishan Pei

  DOI：10.1002/cjoc.201180345

  日期：2011.9

  A novel conjugated polythiophene derivative with polymethacrylate attaching to the polymer backbone via an alkyl spacer was successfully synthesized. A methacrylate‐substituted thiophene monomer, 3‐(hexyl methacrylate)thiophene was prepared and polymerized by free radical polymerization, followed by an electrochemical polymerization. The resulting polymer as a yellow‐green‐light emitter, has potential

  成功合成了一种新型的共轭聚噻吩衍生物，其具有通过烷基间隔基连接到聚合物主链上的聚甲基丙烯酸酯。制备了甲基丙烯酸酯取代的噻吩单体3-（甲基丙烯酸己酯）噻吩，并通过自由基聚合反应进行聚合，然后进行电化学聚合反应。所得的聚合物为黄绿色发光体，在光电领域具有潜在的应用。
• [EN] POLYTHIOPHENE-BASED SENSORS<br/>[FR] DETECTEURS A BASE DE POLYTHIOPHENE
  申请人：SECR DEFENCE

  公开号：WO2005019210A1

  公开（公告）日：2005-03-03

  Disclosed are methods of producing defined polythiophene polymers for use as electrochemical sensors. Copolymerising receptor bearing monomers with varied proportions of underivatised monomers produces polymers with a defined density of receptor side-chains and improved consistency and sensitivity as sensors. Also disclosed are improved methods of polymerising regioregular polythiophene providing a regioregular array of receptors in a conducting polymer, suitable for use as a biosensor. Specific monomers and receptor moieties are also provides.

  公开了一种制备用作电化学传感器的定义聚噻吩聚合物的方法。将带有受体的单体与不同比例的未衍生单体共聚，可产生具有受体侧链密度的定义聚合物，并具有改进的一致性和传感器灵敏度。还公开了改进的聚合方法，用于聚合具有规则对称的聚噻吩，在导电聚合物中提供受体的规则对称阵列，适用于用作生物传感器。还提供了特定的单体和受体基团。
• Conductive organic thin film, process for producing the same, electronic device employing the same, electrical cable, electrode, pyrrolyl compound, and theienyl compound
  申请人：——

  公开号：US20040109954A1

  公开（公告）日：2004-06-10

  It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (&rgr;) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×10 5 S/cm, and preferably at least 1×10 7 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

  本发明旨在提供一种导电有机薄膜，其有机分子包括末端配位基共价键结合到基板表面的一端，位于有机分子的任意部分并与其他分子聚合的共轭键合基，以及不包含活性氢且位于末端配位基和共轭键合基之间的极性功能基，其中有机分子被定向并且它们的共轭键合基被聚合，形成导电网络。该导电有机薄膜在室温（25℃）下的电导率（σ）至少为5.5×105S/cm，最好至少为1×107S/cm，不含掺杂剂，具有比黄金和银等金属更高的电导率。特别是，通过电解氧化聚合聚合的聚吡咯或聚噻吩共轭键合基的薄膜具有高导电性。
• Organic electronic device and its manufacturing method
  申请人：Yamamoto Shinichi

  公开号：US20050145839A1

  公开（公告）日：2005-07-07

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、形成在基板上的至少两个电极、形成在基板上并电性连接电极的导电有机薄膜以及用于涂覆电极至少一部分的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。
• Organic electronic device and method for manufacturing the same
  申请人：Yamamoto Shinichi

  公开号：US20070085076A1

  公开（公告）日：2007-04-19

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、至少两个形成在基板上的电极、形成在基板上并电性连接电极的导电有机薄膜，以及用于涂覆至少一部分电极的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。