Methyl 2,3-dihydroxy-4-(octylcarbamoyl)benzoate | 364364-88-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methyl 2,3-dihydroxy-4-(octylcarbamoyl)benzoate
• 英文别名: methyl 2,3-dihydroxy-4-(octylcarbamoyl)benzoate
• CAS: 364364-88-5
• 化学式: C₁₇H₂₅NO₅
• 分子量: 323.389
• InChiKey: KSARSGVORRCFEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  95.9
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  Methyl 2,3-dihydroxy-4-(octylcarbamoyl)benzoate 在 氢氧化钾 作用下， 以 水 为溶剂， 反应 2.0h， 以74%的产率得到2,3-Dihydroxy-4-(octylcarbamoyl)benzoic acid
  参考文献：
  名称：

  A Streamlined Synthesis for 2,3-Dihydroxyterephthalamides

  摘要：

  [GRAPHICS]2,3-Dihydroxyterephthalamides have been synthesized through a route that avoids the protection and deprotection of the phenol groups. The procedure allows for symmetric and unsymmetric amide linkages. This synthetic sequence significantly decreases the time and cost of preparation and increases the overall yield of this class of metal chelators.

  DOI：

  10.1021/ol016253u
• 作为产物：
  描述：

  2,3-二羟基-1,4-苯二羧酸二甲酯 在 氯化亚砜 、 碳酸氢钠 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 26.0h， 生成 Methyl 2,3-dihydroxy-4-(octylcarbamoyl)benzoate
  参考文献：
  名称：

  A Streamlined Synthesis for 2,3-Dihydroxyterephthalamides

  摘要：

  [GRAPHICS]2,3-Dihydroxyterephthalamides have been synthesized through a route that avoids the protection and deprotection of the phenol groups. The procedure allows for symmetric and unsymmetric amide linkages. This synthetic sequence significantly decreases the time and cost of preparation and increases the overall yield of this class of metal chelators.

  DOI：

  10.1021/ol016253u

文献信息

• Organic Luminescent Element
  申请人：Tanabe Junichi

  公开号：US20080217580A1

  公开（公告）日：2008-09-11

  The present invention relates to compounds of formula (I) a process for their production and to their use for coloring high molecular weight organic materials, as fluorescent tracers, in solid dye lasers, EL lasers, in EL devices and lighting. The compounds of formula I show unique broadband luminescence in visible region.

  本发明涉及公式（I）的化合物，其制备方法以及它们用于着色高分子量有机材料、作为荧光示踪剂、在固态染料激光器、EL激光器、EL器件和照明中的用途。公式I的化合物在可见区域显示出独特的宽带发光。
• A Streamlined Synthesis for 2,3-Dihydroxyterephthalamides
  作者：Christine J. Gramer、Kenneth N. Raymond

  DOI：10.1021/ol016253u

  日期：2001.9.1

  [GRAPHICS]2,3-Dihydroxyterephthalamides have been synthesized through a route that avoids the protection and deprotection of the phenol groups. The procedure allows for symmetric and unsymmetric amide linkages. This synthetic sequence significantly decreases the time and cost of preparation and increases the overall yield of this class of metal chelators.