di(ethylene glycol) bis(2-anthracenecarboxylate) | 773885-86-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: di(ethylene glycol) bis(2-anthracenecarboxylate)
• 英文别名: 2-[2-(Anthracene-2-carbonyloxy)ethoxy]ethyl anthracene-2-carboxylate；2-[2-(anthracene-2-carbonyloxy)ethoxy]ethyl anthracene-2-carboxylate
• CAS: 773885-86-2
• 化学式: C₃₄H₂₆O₅
• 分子量: 514.577
• InChiKey: VOSZFYVYXWADRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  39
• 可旋转键数：
  10
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (乙烯二胺)钯(II)二硝酸盐 、 di(ethylene glycol) bis(2-anthracenecarboxylate) 、 3-Pyridin-3-yl-5-[5-[[4-[4-[[5-(5-pyridin-3-ylpyridin-3-yl)pyridin-3-yl]methoxy]phenyl]phenoxy]methyl]pyridin-3-yl]pyridine 以 氘代乙腈 、 重水 为溶剂， 生成
  参考文献：
  名称：

  A 3.5-nm Coordination Nanotube

  摘要：

  A 3.5-nm coordination nanotube was self-assembled from 12 Pd(II) ions and four tape-shaped ligands with the aid of a 3.0-nm template. This tubular structure was unambiguously determined by the single-crystal X-ray analysis. Being cooperatively sustained by 24 Pd(II)-pyridine interactions, the framework was kinetically stable even when the template was removed. The empty tube was, of course, capable of binding other molecules in the cavity.

  DOI：

  10.1021/ja047048n
• 作为产物：
  描述：

  2-蒽甲酸 在 吡啶 、 氯化亚砜 作用下， 以 四氢呋喃 为溶剂， 反应 60.0h， 生成 di(ethylene glycol) bis(2-anthracenecarboxylate)
  参考文献：
  名称：

  A 3.5-nm Coordination Nanotube

  摘要：

  A 3.5-nm coordination nanotube was self-assembled from 12 Pd(II) ions and four tape-shaped ligands with the aid of a 3.0-nm template. This tubular structure was unambiguously determined by the single-crystal X-ray analysis. Being cooperatively sustained by 24 Pd(II)-pyridine interactions, the framework was kinetically stable even when the template was removed. The empty tube was, of course, capable of binding other molecules in the cavity.

  DOI：

  10.1021/ja047048n

文献信息

• A 3.5-nm Coordination Nanotube
  作者：Takumi Yamaguchi、Shohei Tashiro、Masahide Tominaga、Masaki Kawano、Tomoji Ozeki、Makoto Fujita

  DOI：10.1021/ja047048n

  日期：2004.9.1

  A 3.5-nm coordination nanotube was self-assembled from 12 Pd(II) ions and four tape-shaped ligands with the aid of a 3.0-nm template. This tubular structure was unambiguously determined by the single-crystal X-ray analysis. Being cooperatively sustained by 24 Pd(II)-pyridine interactions, the framework was kinetically stable even when the template was removed. The empty tube was, of course, capable of binding other molecules in the cavity.