di(ethylene glycol) di(5-norbornene-2-carboxylate) | 864537-25-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: di(ethylene glycol) di(5-norbornene-2-carboxylate)
• 英文别名: diethylene glycol di(5-norbornene-2-carboxylate)；2-[2-(Bicyclo[2.2.1]hept-5-ene-2-carbonyloxy)ethoxy]ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
• CAS: 864537-25-7
• 化学式: C₂₀H₂₆O₅
• 分子量: 346.423
• InChiKey: RGPGDRJGLUORSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  di(ethylene glycol) di(5-norbornene-2-carboxylate) 在 过氧乙酸 、 sodium acetate 作用下， 以 二氯甲烷 、 溶剂黄146 为溶剂， 反应 4.5h， 以96%的产率得到diethylene glycol di(5,6-epoxy-2-norbornane carboxylate)
  参考文献：
  名称：

  [EN] USE OF EPOXIDES AS FUNGICIDES
  [FR] UTILISATION D'EPOXIDES EN TANT QUE FONGICIDES

  摘要：

  本发明涉及将一个或多个环氧化合物用作防止霉菌生长的剂，其中环氧化合物为脂肪族环氧酯或醚或环氧乙酸酯或醚，并涉及一种防止霉菌生长的方法。

  公开号：

  WO2005089549A1
• 作为产物：
  描述：

  5-降冰片烯-2-酰氯 、 二乙二醇 在 吡啶 作用下， 反应 4.0h， 以95%的产率得到di(ethylene glycol) di(5-norbornene-2-carboxylate)
  参考文献：
  名称：

  [EN] USE OF EPOXIDES AS FUNGICIDES
  [FR] UTILISATION D'EPOXIDES EN TANT QUE FONGICIDES

  摘要：

  本发明涉及将一个或多个环氧化合物用作防止霉菌生长的剂，其中环氧化合物为脂肪族环氧酯或醚或环氧乙酸酯或醚，并涉及一种防止霉菌生长的方法。

  公开号：

  WO2005089549A1

文献信息

• Compositions curable by ring opening metathesis polymerarization at low temperatures and their application in the dental field
  申请人：3M Innovative Properties Company

  公开号：EP1942125A1

  公开（公告）日：2008-07-09

  The invention relates to a composition which is polymerizable by ring-opening metathesis polymerization (ROMP) comprising at least one monomer that is polymerizable by ROMP, at least one initiator of the Hoveyda-Grubbs type for initiating the ROMP and at least one retarder selected from the group consisting of heterocyclic a means having a ring with at least one N-atom and five or less atoms constituting the ring bearing the at least one N-atom. The invention further relates to a process for the preparation of a composition which is polymerizable by ROMP, a dental material obtainable by polymerizing a composition according to the invention and the use of a substance selected from the group consisting of heterocyclic amines having a ring with at least one N-atom and five or less atoms constituting the ring bearing the at least one N-atom or of a mixture of two or more of such substances as a retarder in ROMP.

  本发明涉及一种可通过开环偏聚聚合反应（ROMP）聚合的组合物，该组合物包含至少一种可通过ROMP聚合的单体、至少一种用于引发ROMP的Hoveyda-Grubbs型引发剂和至少一种选自具有至少一个N原子的环和五个或更少的原子构成具有至少一个N原子的环的杂环组成的组的缓凝剂。本发明还涉及一种可通过 ROMP 聚合的组合物的制备方法、一种可通过聚合根据本发明制备的组合物而获得的牙科材料，以及在 ROMP 中使用一种选自杂环胺的物质作为缓凝剂，该杂环胺具有至少一个 N 原子和五个或更少的原子组成的环，或两种或更多种此类物质的混合物。
• Solid materials obtainable by the ring-opening methathesis polymerization
  申请人：3M Innovative Properties Company

  公开号：EP1815838B1

  公开（公告）日：2010-09-08
• COMPOSITIONS CURABLE BY RING OPENING METATHESIS POLYMERIZATION AT LOW TEMPERATURES AND THEIR APPLICATION IN THE DENTAL FIELD
  申请人：3M Innovative Properties Company

  公开号：EP2094760B1

  公开（公告）日：2017-05-31
• SOLID MATERIALS OBTAINABLE BY RING-OPENING METATHESIS POLYMERIZATION
  申请人：Luchterhandt Thomas

  公开号：US20090088494A1

  公开（公告）日：2009-04-02

  The invention describes solid materials, especially for dental purposes like, e.g., composite milling blocks (CMBs), which can be obtained by ring-opening metathesis polymerization (ROMP). Also described is a method for obtaining such milling blocks, their use and applications of the compositions.
• TELECHELIC BASED NETWORKS FROM NOVEL MACROMONOMERS, COMPOSITIONS, PREPARATION AND USES THEREOF
  申请人：University of Massachusetts

  公开号：US20140296425A1

  公开（公告）日：2014-10-02

  The invention provides highly resilient synthetic hydrogels, which can be prepared, for example, by using the efficient thiol-norbornene chemistry to cross-link hydrophilic poly(ethylene glycol) (PEG) and hydrophobic polydimethylsiloxane (PDMS) polymer chains. The simple hydrogel system with enhanced mechanical properties is useful in many applications, including in the biomedical field and in the design of protective and corrective wear.