4,6-二氯-5-甲基-2-(2’,4’-二特戊基苯氧基异丁酰胺基)苯酚 | 31037-84-0

• 物质功能分类: 染料及颜料 - 染料 - 成色剂
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,6-二氯-5-甲基-2-(2’,4’-二特戊基苯氧基异丁酰胺基)苯酚
• 中文别名: 成色剂青-398；4,6-二氯-5-甲基-2-(2',4'-二特戊基苯氧基异丁酰胺基)苯酚；4,6-二氯-5-甲基-2-(2",4"-二特戊基苯氧基异丁酰胺基)苯酚
• 英文名称: 2-(2,4-di-tert-pentyl-phenoxy)-butyric acid-(3,5-dichloro-2-hydroxy-4-methyl-anilide)
• 英文别名: 2-(2,4-Di-tert-pentyl-phenoxy)-buttersaeure-(3,5-dichlor-2-hydroxy-4-methyl-anilid)；2-(2,4-bis(tert-pentyl)phenoxy)-N-(3,5-dichloro-2-hydroxy-p-tolyl)butyramide；2-[2,4-Bis(tert-pentyl)phenoxy]-N-(3,5-dichloro-2-hydroxy-P-tolyl)butyramide；2-[2,4-bis(2-methylbutan-2-yl)phenoxy]-N-(3,5-dichloro-2-hydroxy-4-methylphenyl)butanamide
• CAS: 31037-84-0
• 化学式: C₂₇H₃₇Cl₂NO₃
• mdl: MFCD00128794
• 分子量: 494.502
• InChiKey: GRPPLTVZUQVNQK-UHFFFAOYSA-N

物化性质

• 沸点：
  584.2±50.0 °C(Predicted)
• 密度：
  1.151

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  33
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.518
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-氨基-4,6-二氯-5-甲基苯酚盐酸盐 、 2-[2,4-双(1,1-二甲基丙基)苯氧基]丁酰氯 生成 4,6-二氯-5-甲基-2-(2’,4’-二特戊基苯氧基异丁酰胺基)苯酚
  参考文献：
  名称：

  Photographic color former dispersions

  摘要：

  公开号：

  US02801171A1

文献信息

• Light-sensitive silver halide photographic material
  申请人：KONICA CORPORATION

  公开号：EP0076705A1

  公开（公告）日：1983-04-13

  There is disclosed a light-sensitive silver halide photographic material having a white pigment containing layer and at least one silver halide emulsion layer provided successively on a support, being characterized in that there is provided a colorant containing layer capable of being made substantially colorless by a photographic treatment between said support and said white pigment containing layer. The present invention provides a light-sensitive silver halide photographic material having a reflective support improved to a great extent in sharpness substantially without bringing about lowering in sensitivity.

  本发明公开了一种感光型卤化银感光材料，该材料具有一个含白色颜料层和至少一个卤化银乳剂层，这两个层依次设置在一个支撑物上，其特征在于，在所述支撑物和所述含白色颜料层之间设置了一个含着色剂层，该着色剂层能够通过照相处理使其基本无色。本发明提供了一种感光卤化银感光材料，它具有一个反光支座，在很大程度上提高了清晰度，而不会降低感光度。
• A new universally applicable detection system based 0n ultra small colloidal metal particles
  申请人：JANSSEN PHARMACEUTICA N.V.

  公开号：EP0317001A1

  公开（公告）日：1989-05-24

  An aggregate for qualitatively or quantitatively determining bindable substances. Said aggregate comprises an ultra small colloidal particle and a specific binding agent characterized in that the mean diameter of the colloidal particle is below 2 nm. Preferably the size of the metal particle is selected so that the aggregate is capable of penetrating in standard biological specimens. A universally applicable detection system for determining bindable substances in particular in living material. Further there is provided a process for preparing said aggregate.

  一种用于定性或定量测定可结合物质的聚合体。所述聚合体由超小胶体颗粒和特异性结合剂组成，其特征在于胶体颗粒的平均直径低于 2 纳米。最好选择金属颗粒的尺寸，以便该聚合体能够穿透标准生物样本。一种普遍适用的检测系统，用于确定可结合物质，特别是生物材料中的可结合物质。此外，还提供了制备所述聚合体的工艺。
• Process for producing aromatic amide compounds useful as cyan coupler for color photographes
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0608896A1

  公开（公告）日：1994-08-03

  There is disclosed a process for producing an aromatic amide compound of the general formula (4), including the steps of subjecting an o-nitrophenol compound of the general formula (1) to catalytic reduction in acetone or an aromatic hydrocarbon solvent under the presence of a nickel catalyst to give an o-aminophenol compound of the general formula (2); and (b) subjecting the o-aminophenol compound of the general formula (2) to condensation with an acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) in acetone or an aromatic hydrocarbon solvent under an atmosphere of an inert gas having an oxygen concentration of 1% or less. The acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) may be obtained by allowing a carboxylic acid compound of the general formula (5) to react with thionyl chloride and by concentrating the reaction mixture. Also disclosed is another process for producing an aromatic amide compound of the general formula (4), including the step of subjecting an o-aminophenol hydrochloride salt of the general formula (6) to condensation with an acid chloride compound having a sulfur content of 0.8% or less, based on the weight of the acid chloride compound, of the general formula (3) in an inert solvent.

  本发明公开了一种生产通式(4)的芳香族酰胺化合物的工艺，包括以下步骤：(a) 在镍催化剂存在下，将通式(1)的邻硝基苯酚化合物在丙酮或芳香烃溶剂中进行催化还原，得到通式(2)的邻氨基苯酚化合物；(b) 将通式(2)的邻氨基苯酚化合物与硫含量为 0.5%或更低的通式(3)的酸性氯化物在丙酮或芳香烃溶剂中，在氧浓度为 1%或更低的惰性气体气氛下进行缩合。硫含量为 0.5%或更低的通式（3）的酸性氯化物可以通过让通式（5）的羧酸化合物与亚硫酰氯反应并浓缩反应混合物来获得。还公开了另一种生产通式(4)芳香族酰胺化合物的工艺，包括在惰性溶剂中使通式(6)的邻氨基苯酚盐酸盐与硫含量为 0.8%或以下（以氯化酸化合物重量为基准）的通式(3)氯化酸化合物缩合的步骤。
• Color photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0127162B1

  公开（公告）日：1989-11-15
• Process for forming direct positive images, direct positive silver halide elements, compositions and compounds as characteristic feature of such processes and elements
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0168730B1

  公开（公告）日：1991-08-21