2-(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenoxy)ethyl 2-((3r,5r,7r)-adamantan-1-yl)acetate | 1092408-17-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenoxy)ethyl 2-((3r,5r,7r)-adamantan-1-yl)acetate
• CAS: 1092408-17-7
• 化学式: C₃₃H₃₂N₄O₃
• 分子量: 532.642
• InChiKey: HGSYFLGSLLRVRC-YFFNMRTGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.85
• 重原子数：
  40.0
• 可旋转键数：
  7.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  89.99
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  Ru(phen)₂Cl₂ 、 2-(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenoxy)ethyl 2-((3r,5r,7r)-adamantan-1-yl)acetate 以 乙醇 为溶剂， 以71%的产率得到[Ru(1,10-phenanthroline)2(C13H7N4C6H4OCH2CH2OCOCH2C10H15)]Cl2
  参考文献：
  名称：

  A Tunable Photosensor

  摘要：

  A pyrene-modified beta-cyclodextrin (pyrenecyclodextrin)-decorated single-walled carbon nanotube (SWNT) field-effect transistor (FET) device was fabricated, which can serve as a tunable photosensor to sense a fluorescent adamantyl-modified Ru complex (ADA-Ru). When the light is on (l = 40 W m(-2) and lambda = 280 nm), the transfer curve of the pyrenecyclodextrin-SWNT/FET device shifts toward a negative gate voltage by about 1.6 V and its sheet resistance increases quickly, indicating a charge-transfer process from the pyrenecyclodextrins to the SWNTs. In contrast, the transfer curve of the pyrenecyclodextrin SWNT/FET device in the presence of the ADA-Ru complex shifts toward a positive gate voltage by about 1.9 V and its sheet resistance decreases slowly when the light is on (l = 40 W m(-2) and lambda = 490 nm), showing a charge-transfer process from the pyrenecyclodextrin-SWNT hybrids to the ADA-Ru complex. Because these photoresponse processes are recoverable following the removal of the light, the present photosensor exhibits a promising application in the area of tunable light detection.

  DOI：

  10.1021/ja805393b
• 作为产物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 2-(4-formylphenoxy)ethyl 2-(adamantan-1-yl)acetate 在 ammonium acetate 、 溶剂黄146 作用下， 反应 3.0h， 以62%的产率得到2-(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenoxy)ethyl 2-((3r,5r,7r)-adamantan-1-yl)acetate
  参考文献：
  名称：

  A Tunable Photosensor

  摘要：

  A pyrene-modified beta-cyclodextrin (pyrenecyclodextrin)-decorated single-walled carbon nanotube (SWNT) field-effect transistor (FET) device was fabricated, which can serve as a tunable photosensor to sense a fluorescent adamantyl-modified Ru complex (ADA-Ru). When the light is on (l = 40 W m(-2) and lambda = 280 nm), the transfer curve of the pyrenecyclodextrin-SWNT/FET device shifts toward a negative gate voltage by about 1.6 V and its sheet resistance increases quickly, indicating a charge-transfer process from the pyrenecyclodextrins to the SWNTs. In contrast, the transfer curve of the pyrenecyclodextrin SWNT/FET device in the presence of the ADA-Ru complex shifts toward a positive gate voltage by about 1.9 V and its sheet resistance decreases slowly when the light is on (l = 40 W m(-2) and lambda = 490 nm), showing a charge-transfer process from the pyrenecyclodextrin-SWNT hybrids to the ADA-Ru complex. Because these photoresponse processes are recoverable following the removal of the light, the present photosensor exhibits a promising application in the area of tunable light detection.

  DOI：

  10.1021/ja805393b