A bioinspired clickable selenylation reaction of indole has been developed by using benzoselenazole as selenylation reagent under nonmetallic B(C6F5)3 catalysis. The practical application of the reaction has been well demonstrated in on-DNA and on-microplate parallel synthesis of indole-selenides.
以苯并
硒唑为
硒化试剂,在非
金属 B(C 6 F 5 ) 3催化下,开发了一种仿生可点击的
吲哚可点击
硒化反应。该反应的实际应用已在
吲哚-
硒化物的 DNA 上和微孔板上平行合成中得到很好的证明。