1,8-bis(4-hydroxyphenoxy)-3,6-dioxaoctane | 29239-84-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,8-bis(4-hydroxyphenoxy)-3,6-dioxaoctane
• 英文别名: 4-[2-[2-[2-(4-Hydroxyphenoxy)ethoxy]ethoxy]ethoxy]phenol
• CAS: 29239-84-7
• 化学式: C₁₈H₂₂O₆
• 分子量: 334.369
• InChiKey: FQTFPTOIFPTROU-UHFFFAOYSA-N

物化性质

• 熔点：
  115-118 °C(Solv: methanol (67-56-1))
• 沸点：
  522.2±50.0 °C(Predicted)
• 密度：
  1.220±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,8-bis(4-hydroxyphenoxy)-3,6-dioxaoctane 在 四氮唑 、 palladium 10% on activated carbon 、 氢气 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 乙腈 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  化学计量控制和序列定义的超分子聚合物的可调粘附从 Cyanostar 稳定的阴离子 - 阴离子键中分层出现

  摘要：

  序列控制的超分子聚合物为生成具有增强功能的刺激响应大分子提供了新的设计范式。超分子链接的动态特性对扩展超分子大分子中的序列定义提出了挑战，设计原则仍然处于起步阶段。在这里，我们展示了第一个使用化学计量控制来指定线性超分子聚合物中单体序列的例子，方法是从相同的乙二醇取代的氰基星大环和亚苯基连接的二磷酸单体合成均聚物和交替共聚物。大环化合物和二磷酸盐之间的化学计量比为 2:1 产生通式 (A)n 的超分子均聚物，该均聚物由氰星稳定的磷酸盐-磷酸盐二聚体的重复单元组成。使用 1:1 的化学计量比，产生交替的 (AB)n 结构，其中一半的磷酸盐二聚体现在被额外的抗衡阳离子稳定，这些阳离子在形成更强的 cyanostar 稳定的磷酸盐二聚体后分层出现。这些新的聚合物材料和结合基序足以承受法向和剪切应力，以促进显着和可调的粘合性能。均聚物 (A)n 由 cyanostar 稳定的抗静电键组成，其粘合强

  DOI：

  10.1021/jacs.9b12645
• 作为产物：
  描述：

  4-苄氧基苯酚 在 palladium on activated charcoal 氢气 、 caesium carbonate 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 25.0~80.0 ℃ 、303.98 kPa 条件下， 反应 11.0h， 生成 1,8-bis(4-hydroxyphenoxy)-3,6-dioxaoctane
  参考文献：
  名称：

  Weber, Edwin; Koehler, Hans-Juergen; Panneerselvam, Kaliyamoorthy, Journal of the Chemical Society. Perkin transactions II, 1990, # 9, p. 1599 - 1605

  摘要：

  DOI：

文献信息

• Golden crowns: cation binding by macrocyclic gold(I) crown ether derivatives
  作者：Fabian Mohr、Richard J Puddephatt

  DOI：10.1016/j.jorganchem.2003.10.025

  日期：2004.1

  The polyether bis(alkynes) α,ω-bis(O-propargyl)triethylene glycol and α,ω-bis(O-4-propargyloxyphenoxy)triethylene glycol reacted with [AuCl(SMe2)] in the presence of base to form the corresponding oligomeric gold(I) acetylide complexes (AuCCCH2O(CH2CH2O)3CH2CCAu)n and (AuCCCH2OC6H4O(CH2CH2O)3C6H4OCH2CCAu)n. These digold(I) diacetylide complexes reacted with diphosphine ligands to give macrocyclic digold(I)

  聚醚双（炔烃）α，ω-双（O-炔丙基）三甘醇和α，ω-双（O -4-炔丙基氧基苯氧基）三甘醇在碱存在下与[AuCl（SMe 2）]反应，形成相应的低聚乙炔金（I）络合物（AuCCCH 2 O（CH 2 CH 2 O）3 CH 2 CCAu）n和（AuCCCH 2 OC 6 H 4 O（CH 2 CH 2 O）3 C 6 H 4 OCH 2 CCAu）ñ。这些乙二醛（I）二乙炔化物配合物与二膦配体反应，得到类型为[Au 2（μ-CC）（μ-PP）]的大环乙二醛（I）配合物，其中CC为二乙炔化物，PP为二膦配体。如通过电喷雾质谱法研究的，这些digold（I）配合物结合了阳离子Li +，Na +，K +和Cs +。
• Diversity-oriented approach to cyclophanes via Claisen rearrangement and ring-closing metathesis as key steps
  作者：Sambasivarao Kotha、Gopalkrushna T. Waghule

  DOI：10.1016/j.tetlet.2014.05.129

  日期：2014.7

  reactions to prepare cyclophane derivatives, Claisen rearrangement reaction is very useful. We have prepared cyclophanes containing ethylene oxy bridge by double Claisen rearrangement reaction and ring-closing metathesis reaction as key steps.

  在制备环烷衍生物的众多反应中，克莱森重排反应非常有用。我们通过双重克莱森重排反应和闭环易位反应制备了含有乙烯氧基桥环的环烷作为关键步骤。
• Molecular Meccano. 2. Self-Assembly of [n]Catenanes
  作者：David B. Amabilino、Peter R. Ashton、Christopher L. Brown、Emilio Cordova、Luis A. Godinez、Timothy T. Goodnow、Angel E. Kaifer、Simon P. Newton、Marek Pietraszkiewicz

  DOI：10.1021/ja00109a011

  日期：1995.2

  The mutual molecular recognition between different: structural components in large rings has led to the template-directed synthesis of a wide range of catenanes composed of from two to five interlocked rings, The molecular self-assembly processes rely upon the recognition between (i) pi-electron rich and pi-electron deficient aromatic units and (ii) hydrogen bond donors and accepters, in the different components. In order to increase Our knowledge of the factors involved in such molecular self-assembly processes, a homologous series of [2]catenanes has been constructed using macrocyclic polyethers of the bis(p-phenylene)-(3n+4)-crown-n (n = 9-14) type as templates for the formation of the tetracationic cyclophane, cyclobis(paraquat-p-phenylene). Increasing the size of the tetracationic cyclophane to cyclobis(paraquat-4,4'-bitolyl) allows the simultaneous entrapment of two hydroquinone ring-containing macrocyclic polyethers affording a series of [3]catenanes, and one [4]catenane incorporating a cyclic dimer of the expanded cyclophane and three bis(p-phenylene)-34-crown-10 components. By analogy; increasing the number of hydroquinone rings in the macrocyclic polyether permits the self-assembly of more than one tetracationic cyclophane around the templates present in the macrocyclic polyether. In this context, the template-directed synthesis of two [3]catenanes, incorporating two cyclobis(paraquat-p-phenylene) components and either (i) tris(p-phenylene)51-crown-15 or (ii) tetrakis (p-phenylene)-68-crown-20, has been achieved and is reported. A combination of these two approaches has led to the successful self-assembly, in two steps, of a linear [4]catenane, together with a small amount of a [5]catenane: The creation of these intricate molecular compounds lends support to the contention that self-assembly is a viable paradigm for the construction of nanometer-scale molecular architectures incorporating a selection of simple components.
• WEBER, EDWIN;KOHLER, HANS-JURGEN;PANNEERSELVAM, KALIYAMOORTHY;CHACKO, KIZ+, J. CHEM. SOC. PERKIN TRANS. PT 2,(1990) N, C. 1599-1605
  作者：WEBER, EDWIN、KOHLER, HANS-JURGEN、PANNEERSELVAM, KALIYAMOORTHY、CHACKO, KIZ+

  DOI：——

  日期：——
• [EN] AMINE-CURED TYPE EPOXY RESIN ELECTROLYTE HAVING A SULFONIC ACID GROUP AND METHOD FOR PREPARATION THEREOF<br/>[FR] ELECTROLYTE EN RESINE EPOXYDE DE TYPE DURCI PAR AMINES COMPRENANT UN GROUPE D'ACIDE SULFONIQUE ET SON PROCEDE DE PREPARATION
  申请人：EBARA CORP

  公开号：WO2004078822A1

  公开（公告）日：2004-09-16

  Provided are a sulfonic-acid-containing amine-cured type epoxy resin having at least one structure selected from structures represented by the following formulas (1)and (2) (wherein, R1 and R3 each independently represents a hydrocarbon chain having 1 to 50 carbon atoms, or a hydrocarbon chain having 1 to 50 carbon atoms and having a hydroxyl group, amino group, ether bond or imine bond, and R2 represents a hydrocarbon chain having 3 or 4 carbon atoms); electrolyte or electrolyte membrane containing the resin; method for preparation thereof; electrochemical device using the membrane. The electrolyte and electrolyte membrane according to the present invention have electrolyte properties such as ion conductivity enough for use in electrochemical devices, have heat resistance and mechanical strength, and can be prepared at a low cost. In addition, bonding or adhesion to electrodes is excellent owing to suppressed swelling of the membrane when impregnated with a solvent.