tetradeca-(4E,9Z)-4,9-dien-1-ol | 108609-19-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: tetradeca-(4E,9Z)-4,9-dien-1-ol
• 英文别名: (E4,Z9)-tetradecadienol；(4E,9Z)-tetradeca-4,9-dien-1-ol
• CAS: 108609-19-4
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: RTVRBZVCOFYNLX-GWZUCBFCSA-N

物化性质

• 沸点：
  312.0±11.0 °C(Predicted)
• 密度：
  0.860±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tetradeca-(4E,9Z)-4,9-dien-1-ol 在 dilithium tetrachlorocuprate 吡啶 、 三溴化磷 、 对甲苯磺酸 、 magnesium 作用下， 以 甲醇 、 乙醚 为溶剂， 反应 13.0h， 生成 (6E,11Z)-6,11-hexadecadien-1-ol
  参考文献：
  名称：

  Sharma; Sabharwal; Vohra, Journal of the Indian Chemical Society, 1990, vol. 67, # 1, p. 31 - 33

  摘要：

  DOI：
• 作为产物：
  描述：

  1-bromo-non-4-yne 在 lithium aluminium tetrahydride 、 正丁基锂 、 dimethyl sulfide borane 、 对甲苯磺酸 、 环己烯 作用下， 以 四氢呋喃 、 甲醇 、 二乙二醇二甲醚 为溶剂， 反应 28.33h， 生成 tetradeca-(4E,9Z)-4,9-dien-1-ol
  参考文献：
  名称：

  摘要：

  The Iepidopteran genus Saturnia has three representatives in North America, S. walterorum, S.mendocino, and S. albofasciata. (E4,Z9)-Tetradecadienal (E4,Z9-14 : Ald) was identified as a sex pheromone component for all three species by combinations of coupled gas chromatography-electroantennogram detection (GC-EAD), GC-mass spectrometry (MS), and field trials. In field trials, all three species were strongly attracted to (E4,Z9-14 : Ald) as a single component. Small amounts of (Z)-9-tetradecenal (Z9-14: Ald) also were found in extracts of all three species, but blends of this compound with E4,Z9-14 : Aid were no more attractive to male moths than E4,Z9-14 : Aid alone. Extracts of pheromone glands of female S. walterorum occasionally contained a third, trace compound eliciting responses from male antennae in GC-EAD experiments, but this compound was not identified. It is suggested that the three species can use the same, single component as a sex attractant because the flight period of S. albofasciata (Fall) is different than that of the other two species (spring), whereas the geographic distributions of S. mendocino and S. walterorum overlap over only small portions of their ranges. Furthermore, the latter two species readily hybridize, so there may be minimal fitness cost to cross-attraction.

  DOI：

  10.1023/a:1010310204552

文献信息

• Tomida, Ichiro; Iwakoshi, Kenji; Kono, Satoshi, Agricultural and Biological Chemistry, 1987, vol. 51, # 3, p. 939 - 940
  作者：Tomida, Ichiro、Iwakoshi, Kenji、Kono, Satoshi、Takahashi, Takeshi、Matsunaga, Taiki、Kayahara, Hiroshi

  DOI：——

  日期：——
• SHARMA, SANJIV;SABHARWAL, ARUN;VOHRA, NEELAM;SHARMA, M. L.;VIG, O. P.;KAD+, J. INDIAN CHEM. SOC., 67,(1990) N, C. 31-33
  作者：SHARMA, SANJIV、SABHARWAL, ARUN、VOHRA, NEELAM、SHARMA, M. L.、VIG, O. P.、KAD+

  DOI：——

  日期：——
• US9981898B1
  申请人：——

  公开号：US9981898B1

  公开（公告）日：2018-05-29