1-butyl-3-methylimidazolium propionate | 914497-10-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-butyl-3-methylimidazolium propionate
• 英文别名: 1-butyl-3-methylimidazol-3-ium;propanoate
• CAS: 914497-10-2
• 化学式: C₃H₅O₂*C₈H₁₅N₂
• 分子量: 212.292
• InChiKey: BJMHXLGHJQKGNI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.26
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  48.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-丁基-3-甲基咪唑溴盐 在 水 作用下， 以 水 为溶剂， 生成 1-butyl-3-methylimidazolium propionate
  参考文献：
  名称：

  Viscosities and Conductivities of 1-Butyl-3-methylimidazolium Carboxylates Ionic Liquids at Different Temperatures

  摘要：

  In recent years, 1-butyl-3-methylimidazolium carboxylates ionic liquids (ILs) have been reported to be powerful solvents for the dissolution of cellulose and chitosan. However, very few studies have been conducted to investigate their basic physicochemical properties such as viscosity and conductivity. In this work, we have synthesized 1-butyl-3-methylimidazolium carboxylates ILs: 1-butyl-3-methylimidazolium formate ([C(4)mim][HCOO]), 1-butyl-3-methylimidazolium acetate ([C(4)mim][CH3COO]), 1-butyl-3-methylimidazolium propionate ([C(4)mim][CH3CH2COO]), and 1-butyl-3-methylimidazolium butyrate ([C(4)mim][CH3(CH2)(2)COO]), in which the alkyl chain length in the anions is varied. The experimental viscosities (eta) and conductivities (sigma) for these as have been determined at different temperatures, and well correlated by the Vogel-Fulcher-Tammann (VFT) equation. Walden plots indicate an increase in ion pairs and/or ionic aggregates in the ILs with increasing alkyl chain length. Furthermore, the effect of alkyl chain length in carboxylate anions on viscosities and conductivities of the ILs has been discussed in light of the contribution from van der Waals interactions. Such knowledge would be useful for the understanding of the structure-property relation:hip of ILs and for the rational design of novel task-specific ILs.

  DOI：

  10.1021/je300507h
• 作为试剂：
  描述：

  氯雷他定 在 1-butyl-3-methylimidazolium propionate 、 C₁₆H₂₇N₄O₃⁽¹⁺⁾*BF₄^(1-) 作用下， 反应 0.5h， 以96.2%的产率得到地氯雷他定
  参考文献：
  名称：

  一种地氯雷他定的制备方法

  摘要：

  本发明提供一种地氯雷他定的制备方法，所述制备方法为：将氯雷他定溶于离子液体中，在搅拌下反应，得到所述地氯雷他定；其中所述离子液体为1‑丁基‑3‑甲基咪唑丙酸盐离子液体和式I所示的离子液体的混合物。本发明所述方法简单、易于操作，产率高，后处理简单，且绿色环保，安全性高。

  公开号：

  CN112047923A

文献信息

• PRODUCTION OF IONIC LIQUIDS
  申请人：Buchanan Charles Michael

  公开号：US20080194834A1

  公开（公告）日：2008-08-14

  Ionic liquids and processes and apparatus for their production. The ionic liquids can be low sulfur and low halide carboxylated ionic liquids. The ionic liquids can be produced via formation of at least one intermediate carboxylated ionic liquid, and thereafter subjecting the intermediate carboxylated ionic liquid to at least one anion exchange process.

  离子液体及其生产的方法和装置。这些离子液体可以是低硫和低卤代羧酸盐离子液体。这些离子液体可以通过形成至少一种中间羧酸盐离子液体，然后将中间羧酸盐离子液体经过至少一次阴离子交换过程来生产。
• Interactions of 1-butyl-3-methylimidazolium carboxylate ionic liquids with glucose in water: a study of volumetric properties, viscosity, conductivity and NMR
  作者：Kelei Zhuo、Yujuan Chen、Jing Chen、Guangyue Bai、Jianji Wang

  DOI：10.1039/c1cp20948e

  日期：——

  Extensive applications of ionic liquids (ILs) may result in their accumulation in the ecological environment and organisms. Although ILs are popularly called “green solvents”, their toxicity, in fact, has been exhibited. Therefore the interaction of ILs with biomolecules is a cutting-edge research subject. Herein, the interactions of 1-butyl-3-methylimidazolium carboxylate ionic liquids ([C4mim][HCOO], [C4mim][CH3COO] and [C4mim][CH3CH2COO]) with glucose in water were studied for their volumetric properties, viscosity, conductivity and NMR spectra. Limiting apparent molar volumes (V0Φ,IL), viscosity B-coefficients, limiting molar conductivities (Λ0) and Walden products (Λ0η0) were evaluated for the ILs in glucose + water solutions. Volumetric interaction parameters were also obtained from the transfer volumes of the ionic liquids. The contributions of the solvent properties (B1) and the ionic liquid–solvent interactions (B2) to the B-coefficient were extracted, together with molar activation energies (Δμ0≠IL) of the ionic liquids for viscous flow of the aqueous glucose + IL solution. In addition, the 13C and 1H NMR spectra of methyl β-D-glucopyranoside and ILs in β-D-glucopyranoside + IL + D2O were studied. The NMR results show that no special and strong interactions were observed between glucopyranoside and the ILs. However, it was confirmed that the H2 on the imidazolium ring has more activity (acidity) than atoms H4 and H5. The macro-properties and their changes were also discussed in terms of the size, structure and solvation of the ILs and glucose.

  离子液体（ILs）的广泛应用可能会导致其在生态环境和生物体内积累。虽然离子液体被普遍称为 "绿色溶剂"，但事实上其毒性已经显现。因此，IL 与生物大分子的相互作用是一个前沿研究课题。本文研究了 1-丁基-3-甲基咪唑羧酸盐离子液体（[C4mim][HCOO]、[C4mim][CH3COO]和[C4mim][CH3CH2COO]）与葡萄糖在水中的相互作用，包括它们的体积特性、粘度、电导率和核磁共振光谱。评估了葡萄糖 + 水溶液中的 IL 的极限表观摩尔体积 (V0Φ,IL)、粘度 B 系数、极限摩尔电导率 (Λ0)和瓦尔登积 (Λ0η0)。还从离子液体的转移体积中获得了体积相互作用参数。提取了溶剂特性（B1）和离子液体-溶剂相互作用（B2）对 B 系数的贡献，以及离子液体在葡萄糖+IL 水溶液粘性流动中的摩尔活化能（Δμ0≠IL）。此外，还研究了 β-D-Glucopyranoside + IL + D2O 中甲基 β-D-Glucopyranoside 和 IL 的 13C 和 1H NMR 光谱。核磁共振结果表明，在吡喃葡萄糖苷和 IL 之间没有观察到特殊和强烈的相互作用。不过，经证实，咪唑环上的 H2 比 H4 和 H5 原子具有更强的活性（酸性）。此外，还从 ILs 和葡萄糖的大小、结构和溶解度方面讨论了它们的宏观特性及其变化。
• IONIC COMPOUNDS IN LITHIUM BROMIDE/WATER ABSORPTION CYCLE SYSTEMS
  申请人：Shiflett Mark Brandon

  公开号：US20120011886A1

  公开（公告）日：2012-01-19

  Disclosed herein are compositions comprising lithium bromide, water, and at least one ionic compound. These compositions are useful as working fluids in absorption cycle systems. The ionic compound additive has been demonstrated to reduce crystallization in such absorption cycle systems.

  本文公开了包含溴化锂、水和至少一种离子化合物的组合物。这些组合物在吸收循环系统中作为工作流体是有用的。已经证明，离子化合物添加剂可以减少这种吸收循环系统中的结晶。
• Regioselectively substituted cellulose esters produced in a carboxylated ionic liquid process and products produced therefrom
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：US10174129B2

  公开（公告）日：2019-01-08

  This invention relates to novel compositions comprising regioselectively substituted cellulose esters. One aspect of the invention relates to processes for preparing regioselectively substituted cellulose esters from cellulose dissolved in ionic liquids. Another aspect of the invention relates to the utility of regioselectively substituted cellulose esters in applications such as protective and compensation films for liquid crystalline displays.

  本发明涉及由区域选择性取代的纤维素酯组成的新型组合物。本发明的一个方面涉及从溶解在离子液体中的纤维素制备区域选择性取代的纤维素酯的工艺。本发明的另一方面涉及区域选择性取代的纤维素酯在液晶显示器保护膜和补偿膜等应用中的实用性。
• Assessing solvent properties of amino acid-based ionic liquids and their DMSO solutions through solvatochromism
  作者：Nicolas Keppeler、Narciso Rodrigo S. Vagula、Mariela Akina Komesu、Naved I. Malek、Omar A. El Seoud

  DOI：10.1016/j.molliq.2024.124130

  日期：2024.3

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