反式环丁烷-1,2-d2 | 780821-74-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 3,4-二氢香豆素
• 中文名称: 反式环丁烷-1,2-d2
• 英文名称: 4,4'-spirodi[7-hydroxychroman-2-one]
• 英文别名: 7,7'-dihydroxy-[4,4']spirobichromene-2,2'-dione；7,7'-Dihydroxy-[4,4']spirobichromen-2,2'-dion；7,7'-dihydroxy-4,4'-spirobi[chromene]-2,2'(3H,3'H)-dione；7,7'-dihydroxy-4,4'-spirobi[3H-chromene]-2,2'-dione
• CAS: 780821-74-1
• 化学式: C₁₇H₁₂O₆
• mdl: MFCD06008371
• 分子量: 312.279
• InChiKey: RMQHSNYXQLJJFO-UHFFFAOYSA-N

物化性质

• 熔点：
  308.5-309.5 °C(Solv: acetonitrile (75-05-8))
• 沸点：
  576.5±50.0 °C(Predicted)
• 密度：
  1.60±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  反式环丁烷-1,2-d2 在 二月桂酸二丁基锡 作用下， 以 乙酸乙酯 为溶剂， 反应 8.0h， 生成 2-[2-[2-[[7'-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethylcarbamoyloxy]ethoxy]-2,2'-dioxo-4,4'-spirobi[chromane]-7-yl]oxy]ethoxycarbonylamino]ethoxy]ethyl-2-methylprop-2-enoate
  参考文献：
  名称：

  [EN] POLYMERIZABLE 4,4'-SPIROBI[CHROMANE]-2,2'-DIONES AND CURABLE COMPOSITIONS INCLUDING THE SAME
  [FR] 4,4'-SPIROBI[CHROMANE]-2,2'-DIONES POLYMÉRISABLES ET COMPOSITIONS DURCISSABLES LES COMPRENANT

  摘要：

  A polymerizable compound is represented by the formula (I). Each R1independently represents a monovalent group having from 3 to 12 carbon atoms that comprises at least one of an epoxy group, an acryl group, or a methacryl group. Each R2independently represents H, F, C1, Br, C1-C12alkyl, C2-C3carbonylalkyl, or C2-C5carboalkoxy. Each R3independently represents H, F, C1, Br, C1-C12alkyl, C2-C3carbonylalkyl, or C2-C5carboalkoxy. Each n is independently 0, 1, 2, 3, or 4. Curable compositions including the polymerizable compound are also disclosed.

  公开号：

  WO2022195364A1
• 作为产物：
  描述：

  柠檬酸 在 四磷十氧化物 、 硫酸 作用下， 以 水 为溶剂， 反应 3.0h， 生成 反式环丁烷-1,2-d2
  参考文献：
  名称：

  [EN] POLYMERIZABLE 4,4'-SPIROBI[CHROMANE]-2,2'-DIONES AND CURABLE COMPOSITIONS INCLUDING THE SAME
  [FR] 4,4'-SPIROBI[CHROMANE]-2,2'-DIONES POLYMÉRISABLES ET COMPOSITIONS DURCISSABLES LES COMPRENANT

  摘要：

  A polymerizable compound is represented by the formula (I). Each R1independently represents a monovalent group having from 3 to 12 carbon atoms that comprises at least one of an epoxy group, an acryl group, or a methacryl group. Each R2independently represents H, F, C1, Br, C1-C12alkyl, C2-C3carbonylalkyl, or C2-C5carboalkoxy. Each R3independently represents H, F, C1, Br, C1-C12alkyl, C2-C3carbonylalkyl, or C2-C5carboalkoxy. Each n is independently 0, 1, 2, 3, or 4. Curable compositions including the polymerizable compound are also disclosed.

  公开号：

  WO2022195364A1

文献信息

• 4,4′-Spirodichroman-2-ones as unexpected products from the condensation of resorcinols and dimethyl acetonedicarboxylate
  作者：I. P. Dubovik、M. M. Garazd、V. P. Khilya

  DOI：10.1007/s10593-007-0041-x

  日期：2007.3
• Dixit; Kankudti; Mulay, Journal of the Indian Chemical Society, 1945, vol. 22, p. 207,210
  作者：Dixit、Kankudti、Mulay

  DOI：——

  日期：——
• [EN] POLYMERIZABLE 4,4'-SPIROBI[CHROMANE]-2,2'-DIONES AND CURABLE COMPOSITIONS INCLUDING THE SAME<br/>[FR] 4,4'-SPIROBI[CHROMANE]-2,2'-DIONES POLYMÉRISABLES ET COMPOSITIONS DURCISSABLES LES COMPRENANT
  申请人：[en]3M INNOVATIVE PROPERTIES COMPANY

  公开号：WO2022195364A1

  公开（公告）日：2022-09-22

  A polymerizable compound is represented by the formula (I). Each R1independently represents a monovalent group having from 3 to 12 carbon atoms that comprises at least one of an epoxy group, an acryl group, or a methacryl group. Each R2independently represents H, F, C1, Br, C1-C12alkyl, C2-C3carbonylalkyl, or C2-C5carboalkoxy. Each R3independently represents H, F, C1, Br, C1-C12alkyl, C2-C3carbonylalkyl, or C2-C5carboalkoxy. Each n is independently 0, 1, 2, 3, or 4. Curable compositions including the polymerizable compound are also disclosed.