4,10-bis(2-cyclopenta-2,4-dien-1-yloxyethyl)-1,7-dioxa-4,10-diazacyclododecane;iron(2+) | 211119-26-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 4,10-bis(2-cyclopenta-2,4-dien-1-yloxyethyl)-1,7-dioxa-4,10-diazacyclododecane;iron(2+)
• CAS: 211119-26-5
• 化学式: C₂₂H₃₂FeN₂O₄
• 分子量: 444.354
• InChiKey: FIHCHSLTIVLELL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4,10-bis(2-cyclopenta-2,4-dien-1-yloxyethyl)-1,7-dioxa-4,10-diazacyclododecane;iron(2+) 、 三氟甲磺酸钠 以 乙腈 为溶剂， 以99%的产率得到sodium;4,10-bis(2-cyclopenta-2,4-dien-1-yloxyethyl)-1,7-dioxa-4,10-diazacyclododecane;iron(2+);trifluoromethanesulfonate
  参考文献：
  名称：

  An Artificial Regulatory System with Coupled Molecular Switches

  摘要：

  The availability of sodium ions can be regulated indirectly (through electron transfer reactions) and reversibly through the addition and removal of zinc ions. In this cyclic process (depicted on the right) a redox-responsive ferrocene substituted with two dipicolylamino ligands (Fcdpa) coordinates two Zn2+ ions, while a redox-switchable ferrocene cryptand (Fccrypt) only forms stable complexes with Na+ when the ligand is in its reduced form. L is a strong ligand such as 1,4,8,11-tetraazacyclotetradecane.

  DOI：

  10.1002/(sici)1521-3773(19980605)37:10<1397::aid-anie1397>3.0.co;2-1
• 作为产物：
  描述：

  5-(2-iodoethoxy)cyclopenta-1,3-diene;iron(2+) 、 4,10-二氮杂-12-冠4-醚 在 sodium carbonate 作用下， 以 not given 为溶剂， 以80%的产率得到4,10-bis(2-cyclopenta-2,4-dien-1-yloxyethyl)-1,7-dioxa-4,10-diazacyclododecane;iron(2+)
  参考文献：
  名称：

  An Artificial Regulatory System with Coupled Molecular Switches

  摘要：

  The availability of sodium ions can be regulated indirectly (through electron transfer reactions) and reversibly through the addition and removal of zinc ions. In this cyclic process (depicted on the right) a redox-responsive ferrocene substituted with two dipicolylamino ligands (Fcdpa) coordinates two Zn2+ ions, while a redox-switchable ferrocene cryptand (Fccrypt) only forms stable complexes with Na+ when the ligand is in its reduced form. L is a strong ligand such as 1,4,8,11-tetraazacyclotetradecane.

  DOI：

  10.1002/(sici)1521-3773(19980605)37:10<1397::aid-anie1397>3.0.co;2-1