2-chloro-3-methyl-1-nitro-butane | 89211-85-8

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 2-chloro-3-methyl-1-nitro-butane
• 英文别名: 2-Chlor-3-methyl-1-nitro-butan；2-chloro-3-methyl-1-nitrobutane
• CAS: 89211-85-8
• 化学式: C₅H₁₀ClNO₂
• 分子量: 151.593
• InChiKey: YMRDRFKTNMJGJF-UHFFFAOYSA-N

物化性质

• 沸点：
  89 °C
• 密度：
  1.147 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.53
• 重原子数：
  9.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2-chloro-3-methyl-1-nitro-butane 在 盐酸 、 tin(ll) chloride 作用下， 生成 2-chloro-3-methyl-butylamine
  参考文献：
  名称：

  Ville; Dupont, Bulletin de la Societe Chimique de France, 1956, p. 804,806

  摘要：

  DOI：
• 作为产物：
  描述：

  异丁烯 在 乙醚 、 亚硝酰氯 作用下， 生成 2-chloro-3-methyl-1-nitro-butane
  参考文献：
  名称：

  The long-term outcome of volar plate arthroplasty of the proximal interphalangeal joint

  摘要：

  The ultimate effectiveness of an arthroplasty is most accurately determined by a long-term review of the joints' function and freedom from pain. We examined 17 patients an average of 11.5 years (range, 4-26 years) following volar plate arthroplasty for a fracture-dislocation of the proximal interphalangeal joint. All surgeries were performed by the same surgeon. The average age was 36 years (range, 17-61 years). No patient complained of pain at rest or with activity. Patients having arthroplasty within 4 weeks of injury attained a total active range of motion of 85 degrees (50 degrees to 110 degrees). Patients having arthroplasty more than 4 weeks after injury (average, 20 weeks) included several elderly women and averaged 61 degrees (30 degrees to 90 degrees) total active range of motion. Four patients showed some degree of joint narrowing at the follow-up examination. This review suggests that volar plate arthroplasty continues to be of benefit on a long-term basis and provides satisfactory function and pain-free motion. (J Hand Surg 2000; 25A:429-437. Copyright (C) 2000 by the American Society for Surgery of the Hand.).

  DOI：

  10.1016/s0363-5023(00)70026-8

文献信息

• Ogloblin, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 264;engl.Ausg.S.268
  作者：Ogloblin

  DOI：——

  日期：——