1-(4-glycidoxyphenyl)ethanol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(4-glycidoxyphenyl)ethanol
• 英文别名: 2,3-Epoxypropyl p-β-hydroxyethylphenyl ether；1-[4-(hydroxyethyl)phenoxy]-2,3-epoxypropane；1-[4-(Oxiran-2-ylmethoxy)phenyl]ethanol
• 化学式: C₁₁H₁₄O₃
• 分子量: 194.23
• InChiKey: AZLYVNHKHYMJEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  42
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(4-glycidoxyphenyl)ethanol 、 1,6-己二异氰酸酯 以 甲苯 为溶剂， 以61%的产率得到N,N'-bis[[1-(4-glycidoxyphenyl)ethoxy]-carbonyl]hexane-1,6-diamine
  参考文献：
  名称：

  Thermally Activated, Single Component Epoxy Systems

  摘要：

  A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used.

  DOI：

  10.1021/ma200673v
• 作为产物：
  描述：

  乙酮,1-[4-(噁丙环基甲氧基)苯基]- 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以96%的产率得到1-(4-glycidoxyphenyl)ethanol
  参考文献：
  名称：

  Thermally Activated, Single Component Epoxy Systems

  摘要：

  A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used.

  DOI：

  10.1021/ma200673v

文献信息

• Stable free radical polymers
  申请人：Firestone Polymers, LLC

  公开号：EP1473312A2

  公开（公告）日：2004-11-03

  A functional polymer having at least one substituent capable of forming a stable free radical is formed by polymerizing a diene monomer, such as butadiene, to form a first polymer block of the functional polymer. The first polymer block has a weight average molecular weight of less than 150,000. A vinyl aromatic monomer, such as styrene, is polymerized to form at least a second polymer block of the functional polymer. The copolymer is contacted with a stable free radical providing compound to form the functional polymer. By adding sufficient vinyl aromatic monomer, a low molecular weight functional rubber polymer can be rendered processable at ambient temperatures, while maintaining a solution viscosity which is suited to subsequent free radical catalyzation of vinyl aromatic monomers.

  通过聚合二烯单体（如丁二烯）形成功能聚合物的第一聚合物嵌段，从而形成具有至少一个能够形成稳定自由基的取代基的功能聚合物。第一聚合物嵌段的重量平均分子量小于 15 万。聚合乙烯基芳香族单体（如苯乙烯），至少形成功能聚合物的第二聚合物嵌段。将共聚物与提供稳定自由基的化合物接触，形成官能聚合物。通过添加足够的乙烯基芳香族单体，可使低分子量的功能性橡胶聚合物在环境温度下进行加工，同时保持溶液粘度，以适合乙烯基芳香族单体的后续自由基催化。
• PROCESS FOR THE SELECTIVE ALKYLATION OF EPOXY-ALCOHOLS
  申请人：Abbott Laboratories

  公开号：EP0925290B1

  公开（公告）日：2003-11-19
• US4450172A
  申请人：——

  公开号：US4450172A

  公开（公告）日：1984-05-22
• US5942633A
  申请人：——

  公开号：US5942633A

  公开（公告）日：1999-08-24
• US6967228B2
  申请人：——

  公开号：US6967228B2

  公开（公告）日：2005-11-22