1-(3,5-diallyloxyphenyl)-1-methylethanol | 1318616-95-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(3,5-diallyloxyphenyl)-1-methylethanol
• CAS: 1318616-95-3
• 化学式: C₁₅H₂₀O₃
• 分子量: 248.322
• InChiKey: UUYYDUKBYXCITL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.04
• 重原子数：
  18.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  38.69
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  1-(3,5-diallyloxyphenyl)-1-methylethanol 在 sodium tetrahydroborate 、 四(三苯基膦)钯 、 甲基锂 、 caesium carbonate 作用下， 以 四氢呋喃 、 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 51.0h， 生成 N,N'-bis[[1-(3,5-diglycidoxyphenyl)-1-methylethoxy]carbonyl]toluene-2,4-diamine
  参考文献：
  名称：

  Thermally Activated, Single Component Epoxy Systems

  摘要：

  A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used.

  DOI：

  10.1021/ma200673v
• 作为产物：
  描述：

  甲基溴化镁 、 3,5-双(烯丙氧基)苯羧酸甲酯 以 四氢呋喃 、 乙醚 为溶剂， 以73%的产率得到1-(3,5-diallyloxyphenyl)-1-methylethanol
  参考文献：
  名称：

  Thermally Activated, Single Component Epoxy Systems

  摘要：

  A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a diamine held latent by thermally degradable carbamate linkages. These bis-carbamate "single molecule epoxies" have an essentially infinite shelf life and access a significant range in curing temperatures related to the structure of the carbamate linkages used.

  DOI：

  10.1021/ma200673v