3-Butoxymethylthiophene | 119142-27-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3-Butoxymethylthiophene
• 英文别名: 3-(butoxymethyl)thiophene
• CAS: 119142-27-7
• 化学式: C₉H₁₄OS
• 分子量: 170.276
• InChiKey: DSYJIIYBVGZWBR-UHFFFAOYSA-N

物化性质

• 沸点：
  217.9±15.0 °C(Predicted)
• 密度：
  1.015±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  37.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-Butoxymethylthiophene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 溶剂黄146 为溶剂， 以66%的产率得到2-bromo-3-(butoxymethyl)thiophene
  参考文献：
  名称：

  Synthesis of Bridged Oligothiophenes:  Toward a New Class of Thiophene-Based Electroactive Surfactants

  摘要：

  A series of bridged oligothiophenes have been synthesized. Their novel molecular architecture, comprising two oligothiophenes linked together by a bridge at one a-extremity and one binding group at the other a-extremity, is expected to improve their utility as electroactive surfactants for semiconducting nanoparticles or organic electronics.

  DOI：

  10.1021/ol034398q
• 作为产物：
  描述：

  3-噻吩甲醇 、 正溴丁烷 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 以84%的产率得到3-Butoxymethylthiophene
  参考文献：
  名称：

  Synthesis of Bridged Oligothiophenes:  Toward a New Class of Thiophene-Based Electroactive Surfactants

  摘要：

  A series of bridged oligothiophenes have been synthesized. Their novel molecular architecture, comprising two oligothiophenes linked together by a bridge at one a-extremity and one binding group at the other a-extremity, is expected to improve their utility as electroactive surfactants for semiconducting nanoparticles or organic electronics.

  DOI：

  10.1021/ol034398q

文献信息

• Polythiophene electronic devices
  申请人：Xerox Corporation

  公开号：US07718999B2

  公开（公告）日：2010-05-18

  An electronic device with a semiconductor layer of (I) wherein X is O or NR′; m represents the number of methylenes; M is a conjugated moiety; R and R′ are selected from the group consisting of at least one of hydrogen, a suitable hydrocarbon, and a suitable hetero-containing group; a represents the number of 3-substituted thiophene units; b represents the number of conjugated moieties, and n represents the number of polymer repeating units.

  一种具有半导体层的电子设备(I)，其中X为O或NR′；m表示亚甲基的数量；M为共轭基；R和R′从至少一个氢，适当的碳氢化合物和适当的含杂原子基团的组中选择；a表示3-取代噻吩单元的数量；b表示共轭基的数量，n表示聚合重复单元的数量。
• Solution processible forms of neutral and electrically conductive poly(substituted heterocycles)
  申请人：ALLIED CORPORATION

  公开号：EP0203438A1

  公开（公告）日：1986-12-03

  This invention relates to solutions comprising doped and undoped poly(substituted heterocycles) and an organic solvent which can be used to form conducting polymer articles, including films.

  本发明涉及由掺杂和未掺杂的聚（取代杂环）和有机溶剂组成的溶液，可用于形成导电聚合物制品，包括薄膜。
• Polythiophene Electronic Devices
  申请人：Xerox Corporation

  公开号：EP1932865A2

  公开（公告）日：2008-06-18

  An electronic device with a semiconductor layer of (1) wherein X is O or NR'; m represents the number of methylenes; M is a conjugated moiety; R and R' are selected from the group consisting of at least one of hydrogen, a suitable hydrocarbon, and a suitable hetero-containing group; a represents the number of 3-substituted thiophene units; b represents the number of conjugated moieties, and n represents the number of polymer repeating units.,

  一种电子设备，其半导体层为(1) 其中 X 是 O 或 NR'；m 代表亚甲基的数目；M 是共轭分子；R 和 R'选自由氢、合适的烃和合适的含杂基团中的至少一种；a 代表 3-取代噻吩单元的数目；b 代表共轭分子的数目；n 代表聚合物重复单元的数目、
• US7718999B2
  申请人：——

  公开号：US7718999B2

  公开（公告）日：2010-05-18