1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-9-prop-2-enoxynonane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-9-prop-2-enoxynonane
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluoro-9-prop-2-enoxynonane
• 化学式: C₁₂H₈F₁₆O
• 分子量: 472.169
• InChiKey: BYCOLOXUSDUQDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  29
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  1H,1H,9H-十六氟-1-壬醇 、 3-溴丙烯 在 氢氧化钾 作用下， 以 乙腈 为溶剂， 以83%的产率得到1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-9-prop-2-enoxynonane
  参考文献：
  名称：

  Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis

  摘要：

  Perfluoroolefins react with isopropyl alcohol under the conditions of radical initiation to form partially fluorinated aliphatic alcohols. The reactions of these alcohols with hexafluoropropylene and compounds containing labile halogen atoms (in particular, with allyl bromide and epichlorohydrin) were studied.

  DOI：

  10.1134/s1070427207030123

文献信息

• Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis
  作者：A. A. Il’in、A. N. Il’in、Yu. L. Bakhmutov、G. G. Furin、L. M. Pokrovskii

  DOI：10.1134/s1070427207030123

  日期：2007.3

  Perfluoroolefins react with isopropyl alcohol under the conditions of radical initiation to form partially fluorinated aliphatic alcohols. The reactions of these alcohols with hexafluoropropylene and compounds containing labile halogen atoms (in particular, with allyl bromide and epichlorohydrin) were studied.