methyl (Z)-3-iodo-2-octenoate | 160729-74-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methyl (Z)-3-iodo-2-octenoate
• 英文别名: E-2-Octenoic acid, 3-iodo-, methyl ester；methyl (Z)-3-iodooct-2-enoate
• CAS: 160729-74-8
• 化学式: C₉H₁₅IO₂
• 分子量: 282.121
• InChiKey: CHRLONQLNKNSHS-FPLPWBNLSA-N

物化性质

• 沸点：
  270.4±23.0 °C(Predicted)
• 密度：
  1.463±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl (Z)-3-iodo-2-octenoate 在 水 作用下， 以 四氢呋喃 、 N-甲基吡咯烷酮 、 乙醚 为溶剂， 反应 1.0h， 以92%的产率得到反式-2-辛烯甲酯
  参考文献：
  名称：

  Research on a compact adsorption room air conditioner

  摘要：

  A novel compact adsorption room air conditioner with a cooling capacity of 1 kW has been designed, and two prototypes have been built. A two bed, continuous adsorption refrigeration cycle with heat recovery and mass recovery is adopted. Micropore spherical silica gel and water are selected as the working pair. A gravity heat pipe with methanol as working medium is designed to output the cooling. Experimental investigations have indicated that under typical air conditioning conditions, for the first prototype, a cooling capacity of 687 W and a COP (coefficient of performance) of 0.307 can be obtained. However, for the improved one, a cooling capacity of 790 W and a COP of 0.446 can be reached. It is also proved that the operating temperatures have strong influences on the performance. The designed room air conditioner can be driven by a low grade heat source (< 90 degrees C) and has small dimensions of 300 mm (depth), 500 mm (width) and 950 mm (height). (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.enconman.2005.12.005
• 作为产物：
  描述：

  辛酸甲酯 在 三甲基氯硅烷 、 水 、 sodium iodide 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以81%的产率得到methyl (Z)-3-iodo-2-octenoate
  参考文献：
  名称：

  Luo, Fen-Tair; Hsieh, Li-Chen, Journal of the Chinese Chemical Society, 1994, vol. 41, # 6, p. 871 - 873

  摘要：

  DOI：

文献信息

• New procedures for the selective synthesis of 2(2H)-pyranone derivatives and 3-aryl-4-iodoisocoumarins
  作者：Matteo Biagetti、Fabio Bellina、Adriano Carpita、Paolo Stabile、Renzo Rossi

  DOI：10.1016/s0040-4020(02)00469-6

  日期：2002.6

  5-Iodo-2(2H)-pyranone derivatives have been selectively synthesized by reaction of stereodefined methyl 2-en-4-ynoates with iodine in MeCN, CH2Cl2 or C6H6 at 20degreesC (Method C) or by treatment of these esters with ICl in CH2Cl2 at 20degreesC (Method B). Methods B and C proved also to be suitable for the preparation of 3-aryl-4-iodoisocoumarins from the corresponding methyl 2-(arylethynyl)benzoates. Interestingly, the high selectivity of iodolactonization of stereodefined methyl 2-en-4-ynoates by Method B allowed preparation in moderate yields of 2(2H)-pyranone derivatives by a one-pot sequence of iodolactonization and Stille-type reactions. (C) 2002 Elsevier Science Ltd. All rights reserved.
• Luo, Fen-Tair; Hsieh, Li-Chen, Journal of the Chinese Chemical Society, 1994, vol. 41, # 6, p. 871 - 873
  作者：Luo, Fen-Tair、Hsieh, Li-Chen

  DOI：——

  日期：——
• Research on a compact adsorption room air conditioner
  作者：G.Z. Yang、Z.Z. Xia、R.Z. Wang、Daou Keletigui、D.C. Wang、Z.H. Dong、X. Yang

  DOI：10.1016/j.enconman.2005.12.005

  日期：2006.9

  A novel compact adsorption room air conditioner with a cooling capacity of 1 kW has been designed, and two prototypes have been built. A two bed, continuous adsorption refrigeration cycle with heat recovery and mass recovery is adopted. Micropore spherical silica gel and water are selected as the working pair. A gravity heat pipe with methanol as working medium is designed to output the cooling. Experimental investigations have indicated that under typical air conditioning conditions, for the first prototype, a cooling capacity of 687 W and a COP (coefficient of performance) of 0.307 can be obtained. However, for the improved one, a cooling capacity of 790 W and a COP of 0.446 can be reached. It is also proved that the operating temperatures have strong influences on the performance. The designed room air conditioner can be driven by a low grade heat source (< 90 degrees C) and has small dimensions of 300 mm (depth), 500 mm (width) and 950 mm (height). (c) 2006 Elsevier Ltd. All rights reserved.