(E/Z)-10-hexadecenal

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E/Z)-10-hexadecenal
• 英文别名: 10-Hexadecenal, (10Z)-；hexadec-10-enal
• 化学式: C₁₆H₃₀O
• 分子量: 238.414
• InChiKey: NBLCOWKIHZCSCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  17
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  methyl 10,11-dihydroxyundecanoate 在 sodium periodate 、 lithium aluminium tetrahydride 、 正丁基锂 、 pyridinium chlorochromate 作用下， 以 乙醚 、 二氯甲烷 、 水 、 乙腈 为溶剂， 反应 10.5h， 生成 (E/Z)-10-hexadecenal
  参考文献：
  名称：

  Hassarajani, S. A.; Subaraman, A. S.; Mamdapur, V. R., Organic Preparations and Procedures International, 1994, vol. 26, # 5, p. 571 - 573

  摘要：

  DOI：

文献信息

• [EN] TETRAZOLINONE COMPOUNDS AND ITS USE AS PEST CONTROL AGENTS<br/>[FR] COMPOSÉS TÉTRAZOLINONE ET LEUR UTILISATION EN TANT QU'AGENTS DE LUTTE CONTRE LES NUISIBLES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2018097318A1

  公开（公告）日：2018-05-31

  The present invention provides a tetrazolinone represented by formula (I) and a pest control agent comprising the same, and their use thereof. Formula (I) [wherein, W1 represents an oxygen atom or a sulfur atom; W2 represents a hydrogen atom, or a C1-C6 chain hydrocarbon group; R15 and R16 represent a halogen atom and the like; u is 0, 1, 2 or 3; the combination of E, G, X1, Y1 and Z1 represents any one of the combinations of the following a and the like: a: a combination wherein E represents #-C(X1)(Y1)-O-N=C(Z1)-, #-C(X1)(Y1)-S-N=C(Z1)-, #-C(X1)(Y1)-O-N=C(Z1)-O-CH2-, #-C(X1)(Y1)-O-N=C(Z1)-S-CH2-, #-C(X1)(Y1)-S-N=C(Z1)-O-CH2-, #-C(X1)(Y1)-S-N=C(Z1)-S-CH2-, #-C(Z1)=N-N=C(Z2)-, #-C(X1)=C(Y1)-C(Z1)=N-O-CH2- or #-C(X1)=C(Y1)-C(Z1)=N-S-CH2-; G represents a C1-C6 chain hydrocarbon group, a (C1-C6 alkoxy)C1-C6 alkyl group, a (C1-C6 alkylthio)C1-C6 alkyl group the C1-C6 chain hydrocarbon group, the (C1-C6 alkoxy)C1-C6 alkyl group, and the (C1-C6 alkylthio)C1-C6 alkyl group may have one or more substituents selected from Group S} or R1-T1-, X1 and Y1, which are identical to or different from each other, independently represents substituents selected from Group T, and Z1 represents a substituent selected from Group V.]

  本发明提供了一种由式(I)表示的四唑酮化合物，以及包含该化合物的杀虫剂，以及它们的使用。式(I)中，W1代表氧原子或硫原子；W2代表氢原子或C1-C6链烃基；R15和R16代表卤素原子等；u为0、1、2或3；E、G、X1、Y1和Z1的组合代表以下a等组合中的任意一种：a：E代表#-C(X1)(Y1)-O-N=C(Z1)-、#-C(X1)(Y1)-S-N=C(Z1)-、#-C(X1)(Y1)-O-N=C(Z1)-O-CH2-、#-C(X1)(Y1)-O-N=C(Z1)-S-CH2-、#-C(X1)(Y1)-S-N=C(Z1)-O-CH2-、#-C(X1)(Y1)-S-N=C(Z1)-S-CH2-、#-C(Z1)=N-N=C(Z2)-、#-C(X1)=C(Y1)-C(Z1)=N-O-CH2-或#-C(X1)=C(Y1)-C(Z1)=N-S-CH2-；G代表C1-C6链烃基、(C1-C6烷氧基)C1-C6烷基、(C1-C6烷硫基)C1-C6烷基C1-C6链烃基、(C1-C6烷氧基)C1-C6烷基和(C1-C6烷硫基)C1-C6烷基中的每一种可能具有来自S族的一个或多个取代基}或R1-T1-，X1和Y1互相相同或不同，独立地代表来自T族的取代基，Z1代表来自V族的取代基。
• AGRICULTURAL PHEROMONE COMPOSITIONS COMPRISING POSITIONAL ISOMERS
  申请人：PROVIVI, INC.

  公开号：US20170135343A1

  公开（公告）日：2017-05-18

  The present disclosure provides pheromone compositions. In some aspects, the compositions taught herein comprise a pheromone chemically corresponding to the pheromone naturally produced by a given insect, along with at least one positional isomer of said pheromone. In various aspects, pheromone compositions of the present disclosure are able to modulate the response of the insect based on the ratio of natural pheromone to its positional isomer.

  本公开提供信息素组合物。在某些方面，本文所教授的组合物包括一种与某种昆虫自然产生的信息素在化学上相对应的信息素，以及至少一种该信息素的位置异构体。在各个方面，本公开的信息素组合物能够通过自然信息素与其位置异构体的比例来调节昆虫的反应。
• Novel bisexual attractants, aggregants and arrestants for adults and larvae of codling moth and other species of lepidoptera
  申请人：——

  公开号：US20020061324A1

  公开（公告）日：2002-05-23

  Novel bisexual attractants for lepidopterous insect pests isolated from pears or apples. A method for monitoring and control of codling moth and other species of Lepidoptera comprising a lure and kill, mating disruption or mass trapping strategy. A method of using a formulation containing the bisexual attractants with or without an insecticide and/or pheromone for control of the insect pests.

  从梨或苹果中分离出的新型双性吸引剂，用于吸引鳞翅目害虫。一种监测和控制苹果蠹和其他鳞翅目物种的方法，包括诱杀、交配干扰或大规模捕捉策略。一种使用含有双性吸引剂的配方（带或不带杀虫剂和/或信息素）来控制害虫的方法。
• Mating disruption methods for the control of insect pests
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP1075791A1

  公开（公告）日：2001-02-14

  The present invention provides a mating disruption method for the control of insect pests by means of a sex pheromone which can maintain the sex pheromone concentration in the air surrounding a group of plants at a high level for a long period of time while controlling the release rate of the sex pheromone from dispensers at an economical level, and can hence produce a more powerful mating-disrupting effect by use of a given amount of the sex pheromone. Specifically, using dispensers, a sex pheromone is released in a field sprinkled with water so that the soil has a water content of 20 to 100% during the breeding period of insect pests. Thus, the sex pheromone is prevented from being adsorbed to the soil and, as a result, the sex pheromone concentration in the air can be maintained at a high level for a long period of time. Alternatively, a sex pheromone is released in an open field where the surface of the soil is covered with a covering material that is less apt to adsorb sex pheromones than the surface of the soil, or in a house field where the surface of the soil and all or part of the inner surface of the house are covered with a covering material that is less apt to adsorb sex pheromones than the surface of the soil. Thus, the sex pheromone is prevented from being adsorbed to the soil and, as a result, the sex pheromone concentration in the air can be maintained at a high level for a long period of time.

  本发明提供了一种利用性信息素防治害虫的交配干扰方法，该方法可以将植物群周围空气中的性信息素浓度长期保持在较高水平，同时将分配器释放性信息素的速度控制在经济水平，因此使用一定量的性信息素可以产生更强的交配干扰效果。具体来说，在害虫繁殖期，使用分配器在洒水的田地里释放性信息素，使土壤含水量达到 20%至 100%。这样，性信息素就不会被土壤吸附，因此，空气中的性信息素浓度可以长期保持在较高水平。或者，在露天田地里释放性信息素，土壤表面覆盖着比土壤表面更不容易吸附性信息素的覆盖材料，或者在房屋田地里释放性信息素，土壤表面和房屋的全部或部分内表面覆盖着比土壤表面更不容易吸附性信息素的覆盖材料。这样，性信息素就不会被土壤吸附，从而使空气中的性信息素浓度长期保持在较高水平。
• Attractant composition containing ethyl 3-methylbutanoate and (E,E)-8-,10-dodecadien-1-ol
  申请人：BASF SE

  公开号：EP2735230A1

  公开（公告）日：2014-05-28

  The present invention relates to a composition for controlling undesired insect infestation comprising (E,E)-8,10-dodecadien-1-ol and ethyl 3-methylbutanoate. The invention further relates to a process for the preparation of said composition and a method for controlling undesired insect infestation with said composition.

  本发明涉及一种用于控制虫害的组合物，该组合物由(E,E)-8,10-十二碳二烯-1-醇和 3-甲基丁酸乙酯组成。本发明还涉及一种制备所述组合物的工艺和一种用所述组合物控制虫害的方法。