1-羟基苯并(a)蒽 | 69847-26-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 1-羟基苯并(a)蒽
• 英文名称: 1-Hydroxy-benzanthracen
• 英文别名: 1-Hydroxybenz[a]anthracene；benzo[a]anthracen-1-ol
• CAS: 69847-26-3
• 化学式: C₁₈H₁₂O
• 分子量: 244.293
• InChiKey: PBPCCBLJHAAYFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

SDS

反应信息

• 作为反应物：
  描述：

  1-羟基苯并(a)蒽 、 碘甲烷 生成 1-Methoxybenzanthracene
  参考文献：
  名称：

  WEEKS, STEPHAN;GILLES, STEVEN;DOBSON, ROY;SENNE, SCOTT;DSILVA, ARTHUR P., ANAL. CHEM., 62,(1990) N4, C. 1472-1477

  摘要：

  DOI：
• 作为产物：
  描述：

  12-nitrobenzanthracene 生成 1-羟基苯并(a)蒽
  参考文献：
  名称：

  JOHANSEN, HEGE;DOEL, JO;GREIBROKK, TYGE, RAPORTTISAR. MAT.-LUONNONTICTEELLIS. TIEDEKUNNAN ,(1989) N9, C. 24-27

  摘要：

  DOI：

文献信息

• Tetraphenolic compounds and polycarbonates containing the same
  申请人：General Electric Company

  公开号：US04277600A1

  公开（公告）日：1981-07-07

  Novel tetraphenolic compounds are disclosed. These compounds have utility as branching agents in the production of novel, randomly branched polycarbonates.

  揭示了一种新型四苯酚化合物。这些化合物在生产新型、随机分支聚碳酸酯中作为分支剂具有实用性。
• DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID
  申请人：Alabugin Igor

  公开号：US20110237798A1

  公开（公告）日：2011-09-29

  A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.

  提供了一种制备芳香羧酸芳基酯或N-芳基芳香羧酰胺的方法。该方法包括将O,O-二芳基硫代碳酸酯或O-芳基-N-芳基硫代氨基甲酸酯与能够选择性地与硫反应的试剂接触，这种接触导致O-新叶基重排，从而分别形成芳香羧酸芳基酯或N-芳基芳香羧酰胺。
• Polyphenolic compounds
  申请人：General Electric Company

  公开号：US04514334A1

  公开（公告）日：1985-04-30

  Novel polyphenolic compounds are disclosed. These compounds have utility as branching agents in the production of novel, randomly branched polycarbonates.

  本发明揭示了新型多酚类化合物。这些化合物在生产新型随机支化聚碳酸酯中具有分支剂的实用性。
• Ambient temperature curable hydroxyl containing polymer/silicon compositions
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0011782A1

  公开（公告）日：1980-06-11

  Ambient temperature curable compositions comprising a hydroxyl containing organic polymer and an aminosilicon compound, said compositions being useful as protective coating compositions.

  常温固化组合物，包括含羟基的有机聚合物和氨基硅化合物，所述组合物可用作保护涂层组合物。
• Process for the preparation of polyglycidyl ethers of polyhydric phenols and polyglycidyl ethers so prepared
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0018040A1

  公开（公告）日：1980-10-29

  Liquid polyglycidyl ethers of polyhydric phenols are prepared by (A) reacting the polyhydric phenol and an excess of epichlorohydrin in the presence of a condensation catalyst with formation of chlorohydrin ethers by addition reactions and glycidyl ethers and dichlorohydrin by transepoxidation reactions, until at least 95% of the phenolic groups have reacted, (B) distilling off epichlorohydrin and dichlorohydrin, with addition of supplementary dichlorohydrin, at temperatures at which glycidyl ethers are reconverted into chlorohydrin ethers by reaction with dichlorohydrin, (C) dissolving the residue after removal of volatile components in organic solvent and dehydrohalogenating with aqueous alkali metal hydroxide with separation of the aqueous alkali chloride solution, and isolating the polyglycidyl ether.

  多氢酚液体聚缩水甘油醚的制备方法是：(A)在缩合催化剂存在下，使多氢酚和过量环氧氯丙烷反应，通过加成反应生成氯醇醚，通过瞬时氧化反应生成缩水甘油醚和二氯丙醇，直到至少 95%的酚基团发生反应；(B)蒸馏掉环氧氯丙烷和二氯丙醇，同时加入补充的二氯丙醇，在此温度下，缩水甘油醚通过与二氯丙醇反应重新转化为氯醇醚；(C)溶解残留物、(C) 将除去挥发性成分后的残留物溶解在有机溶剂中，并用碱金属氢氧化物水溶液脱氢，分离出氯化碱水溶液，分离出聚缩水甘油醚。