[PbNa(nitrilotriacetate)] | 53113-58-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [PbNa(nitrilotriacetate)]
• 英文别名: [PbNa(NTA)]
• CAS: 53113-58-9
• 化学式: C₆H₆NO₆*Na*Pb
• 分子量: 418.307
• InChiKey: FTKYILYDTWFKBX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -8.84
• 重原子数：
  15.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  123.63
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  sodium hydroxide 、 次氮基三乙酸 、 lead acetate 以 水 为溶剂， 生成 [PbNa(nitrilotriacetate)]
  参考文献：
  名称：

  Two chiral metal–organic frameworks showing unprecedented pcu-type topology based on the vertex-shared bowl-like MNa3 SBUs

  摘要：

  In the presence of NaOH, the self-assembly of M(CH3COO)(2) and nitrilotriacetate generated two metal-organic polymers, MNa(NTA), (M = Pb(1), Sr(2), NTA(3+) = the anion of nitrilotriacetate). The single crystal X-ray diffraction shows that polymers 1 and 2 are isostructural and display the chiral P2(1)3 space group with the Flack factor of -0.001(16) for 1 and 0.023(14) for 2. By topology analysis, the complicated architecture of 1 and 2 is simplified to be the 6-connected pcu-type net, which is built on the vertex-shared, bowl-like MNa3 SBUs (pcu = primitive centered cubic, SBU = secondary building unit). (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.11.006

文献信息

• Davidovich; Logvinova; Kaidalova, Russian Journal of Coordination Chemistry, 1998, vol. 24, # 7, p. 467 - 472
  作者：Davidovich、Logvinova、Kaidalova

  DOI：——

  日期：——