5-Methyl-2-methylmercapto-1-methoxy-benzol | 23385-58-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5-Methyl-2-methylmercapto-1-methoxy-benzol
• 英文别名: 3-methoxy-4-methylsulfanyl-toluene；3-Methoxy-4-methylmercapto-toluol；Methyl-(2-methoxy-4-methyl-phenyl)-sulfid；(2-Methoxy-4-methylphenyl)(methyl)sulfane；2-methoxy-4-methyl-1-methylsulfanylbenzene
• CAS: 23385-58-2
• 化学式: C₉H₁₂OS
• 分子量: 168.26
• InChiKey: CTYZRGOHGHRZBS-UHFFFAOYSA-N

物化性质

• 沸点：
  244.0±28.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-Methyl-2-methylmercapto-1-methoxy-benzol 在 甲基碘化镁 作用下， 以 xylene 为溶剂， 生成 6-(甲硫基)间甲酚
  参考文献：
  名称：

  Cabiddu,S. et al., Gazzetta Chimica Italiana, 1969, vol. 99, p. 397 - 410

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲氧基-4-甲基苯硫醇 在 sodium hydroxide 、 硫酸二甲酯 作用下， 生成 5-Methyl-2-methylmercapto-1-methoxy-benzol
  参考文献：
  名称：

  CLXIV.—4-磺基-3-羟基苯甲酸

  摘要：

  DOI：

  10.1039/jr9300001293

文献信息

• Selective Dealkylation of Alkyl Aryl Sulfides
  作者：S. Cabiddu、S. Melis、P. P. Piras、F. Sotgiu

  DOI：10.1055/s-1982-29868

  日期：——
• CABIDDU, S.;MELIS, S.;PIRAS, P. P.;SOTGIU, F., SYNTHESIS, BRD, 1982, N 7, 583-584
  作者：CABIDDU, S.、MELIS, S.、PIRAS, P. P.、SOTGIU, F.

  DOI：——

  日期：——
• HERBIZID WIRKSAME 3-PHENYLISOXAZOLINDERIVATE
  申请人：Bayer CropScience AG

  公开号：EP2900645A1

  公开（公告）日：2015-08-05
• Aromatic block copolymer, decomposition method thereof and analysis method using the decomposition method
  申请人：Takigawa Hiroshi

  公开号：US20090197763A1

  公开（公告）日：2009-08-06

  Provided is a decomposition method of an aromatic block copolymer, wherein the aromatic block copolymer comprises a segment 1 represented by the following general formula (1) and a segment 2 comprising a structural unit represented by the following general formula (2) and/or a structural unit represented by the following general formula (3), and the segment 2 is subjected to chemical decomposition. (wherein m represents an integer of 5 or more, Ar 1 represents a divalent aromatic group that may have a substituent, and Ar 1 s of 5 or more may be the same as or different from each other,) Ar 10 —X 10   (2) Ar 20 —Y 20 —Ar 21 —X 20   (3) (wherein Ar 10 , Ar 20 and Ar 21 each independently represent a divalent aromatic group that may have a substituent, X 10 and X 20 each independently represent an oxygen atom, a sulfur atom, an alkylene group having 1 to 10 carbon atoms or a fluorine-substituted alkylene group having 1 to 10 carbon atoms, and Y 20 represents a sulfonyl group, a carbonyl group or a fluorine-substituted alkylene group having 1 to 20 carbon atoms).
• Condensed ring-containing polymer electrolyte and application thereof
  申请人：Yamada Takashi

  公开号：US20100239947A1

  公开（公告）日：2010-09-23

  The polymer electrolyte of the present invention comprises a structural unit represented by the following general formula (1) in weight fraction of 1 to 30% by weight: (in the formula, A-ring and B-ring each independently represent an optionally-substituted aromatic hydrocarbon ring or an optionally-substituted heterocyclic ring; X 1 and X 2 each independently represent —CO—, —SO— or —SO 2 —; n and m each independently represent 0, 1 or 2, and n+m is not less than 1; when n is 2, two X 1 s may be the same as or different from each other; when m is 2, two X 2 s may be the same as or different from each other; and X represents a direct bond or a divalent group). The polymer electrolyte has excellent water resistance while having high ion-conductivity.