1,1'-(2,7-二甲基-2,6-辛二烯-4-炔-3,6-二基)二苯 | 22498-86-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,1'-(2,7-二甲基-2,6-辛二烯-4-炔-3,6-二基)二苯
• 英文名称: 2,7-dimethyl-3,6-diphenyl-2,6-octadien-4-yne
• 英文别名: Benzene, 1,1'-[1,4-bis(1-methylethylidene)-2-butyne-1,4-diyl]bis-；(2,7-dimethyl-6-phenylocta-2,6-dien-4-yn-3-yl)benzene
• CAS: 22498-86-8
• 化学式: C₂₂H₂₂
• 分子量: 286.417
• InChiKey: CMNUOXZWGRAXKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  异丁酰苯 在 hexacarbonyl molybdenum 对甲苯磺酸 、 对氯苯酚 作用下， 以 四氢呋喃 、 1,2-二氯乙烷 、 甲苯 为溶剂， 反应 24.0h， 生成 1,1'-(2,7-二甲基-2,6-辛二烯-4-炔-3,6-二基)二苯
  参考文献：
  名称：

  Alkyne metathesis: toward simplicity and efficiency

  摘要：

  No catalyst pre-activation, no suicide alkyne, and no additive is required in an extremely simple procedure for the metathesis of alkyl-, alkenyl-, and aryl-propynes: just mix MO(CO)6, p-chlorophenol, and the alkyne in 1,2-dichloroethane, heat at 85 degrees C for 9-24 h, and the symmetrical alkyne is produced in ca. 95%, yield. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.01.120

文献信息

• Palladium-Catalyzed Bond Reorganization of 1,3-Diynes: An Entry to Diverse Functionalized 1,5-Dien-3-ynes
  作者：Wanqing Wu、Yang Gao、Huanfeng Jiang、Yubing Huang

  DOI：10.1021/jo400276e

  日期：2013.5.3

  A mild and efficient method for the synthesis of functionalized 1,5-dien-3-ynes from 1,3-diynes under PdII catalysis is described. The process allows quick and atom-economical assembly of various dihalo-, haloacyl-, and diacyl-substituted 1,5-dien-3-ynes in high yields. The switch of selectivity in the formation of these dienyne products can be controlled by the choice of catalysis system and reaction

  描述了在Pd II催化下从1,3-二炔合成功能化的1,5-二烯-3-炔的温和而有效的方法。该方法允许以高收率快速且原子经济地组装各种二卤代，卤代酰基和二酰基取代的1，5-二烯-3-炔。通过选择催化体系和反应条件，可以控制这些二烯炔产物形成过程中的选择性转换。
• Kuznetsov; Kuchuk; Tunik, Russian Journal of Organic Chemistry, 1998, vol. 34, # 2, p. 245 - 249
  作者：Kuznetsov、Kuchuk、Tunik

  DOI：——

  日期：——
• Kuznetsov, M. A.; Dorofeeva, Yu. V.; Semenovskii, V. V., Journal of general chemistry of the USSR, 1991, vol. 61, # 10, p. 2122 - 2134
  作者：Kuznetsov, M. A.、Dorofeeva, Yu. V.、Semenovskii, V. V.、Gindin, V. A.、Studienikov, A. N.

  DOI：——

  日期：——
• Synthesis of 3,3-dimethyl-1-phenyl-2-phenylethynylcyclopropene - the first conjugated alkynylcyclopropene
  作者：M.A. Kuznetsov、Yu.V. Dorofeeva、V.V. Semenovskii、V.A. Gindin、A.N. Studenikov

  DOI：10.1016/s0040-4020(01)90789-6

  日期：1992.1

  The 1,3-cycloaddition reaction of 2-diazopropane with diphenyldiacetylene leads to the mixture of 3,3-dimethyl-5-phenyl-4-phenylethynyl-3H-pyrazole, 3,3-dimethyl-4-phenyl-5-phenylethynyl-3H-pyrazole, and 3,3,3',3'-tetramethyl-4',5-diphenyl-4,5'-bi-3H-pyrazolyl. Photolysis of both 3H-pyrazoles gives the title phenylethynylcyclopropene.
• Alkyne metathesis: toward simplicity and efficiency
  作者：Valérie Maraval、Christine Lepetit、Anne-Marie Caminade、Jean-Pierre Majoral、Remi Chauvin

  DOI：10.1016/j.tetlet.2006.01.120

  日期：2006.3

  No catalyst pre-activation, no suicide alkyne, and no additive is required in an extremely simple procedure for the metathesis of alkyl-, alkenyl-, and aryl-propynes: just mix MO(CO)6, p-chlorophenol, and the alkyne in 1,2-dichloroethane, heat at 85 degrees C for 9-24 h, and the symmetrical alkyne is produced in ca. 95%, yield. (c) 2006 Elsevier Ltd. All rights reserved.

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