1,2-diaminodecane | 13880-30-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,2-diaminodecane
• 英文别名: 1,2-Diamino-decan；1,2-Decanediamine；decane-1,2-diamine
• CAS: 13880-30-3
• 化学式: C₁₀H₂₄N₂
• 分子量: 172.314
• InChiKey: ZTEKCBPGTUUQOB-UHFFFAOYSA-N

物化性质

• 沸点：
  259.0±8.0 °C(Predicted)
• 密度：
  0.855±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-diaminodecane 在 sodium methylate 、 sodium carbonate 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 144.5h， 生成
  参考文献：
  名称：

  Unsymmetrical Azo Initiators Increase Efficiency of Radical Generation in Aqueous Dispersions, Liposomal Membranes, and Lipoproteins

  摘要：

  Lipid peroxidation studies often employ the use of azo initiators to produce a slow, steady source of free radicals, but the lack of initiators capable of efficiently generating radicals in lipid aggregates such as micelles and membranes has created persistent problems in these investigations. We report here the synthesis and study of unsymmetrically substituted (hydrophilic/hydrophobic) azo initiators C-8, C-12, and C-16 that increase the efficiency of radical generation in lipophilic regions of aqueous emulsions such as micelles and liposomes. Radical generation from these initiators was monitored in micelles? liposomes, and lipoproteins by the use of two radical scavengers, one that scavengers lipophilic peroxyl radicals and one that scavenges hydrophilic peroxyls. The lipophilic radical scavenger used was the well-known antioxidant alpha-tocopherol and thr hydrophilic radical scavenger used was uric acid. Two peroxyl radicals are trapped by each of these scavengers, tocopherol presumably being biased toward reacting with lipid soluble radicals, uric acid presumably reacting preferentially with water-soluble radicals. In Triton X-100 micelles the unsymmetrical initiators C-8 and C-16 display an increase in both alpha-TOH (alpha-tocopherol) trapping and in overall radical generation efficiency compared to the symmetrical initiators C-0 (hydrophilic) and MeOAMVN (lipophilic). The unsymmetrical azo initiators performance in liposomes was excellent (increased cage escape with lipid compartment access). In low-density lipoprotein oxidations, the initiators C-8, C-12, and C-16 also provided advantages over C-0 and MeOAMVN. The hydrophilic/hydrophobic character of the two radicals generated from the unsymmetrical initiators is an important factor for separating the geminate radical pair, These initiators, when compared to the widely used symmetrical azo initiators, provide an advantage of free radical production, lipophilic access, and constant radical generation in the investigation of lipid peroxidation in various media.

  DOI：

  10.1021/ja9934605
• 作为产物：
  描述：

  正癸烯 在 Lindlar's catalyst sodium azide 、 氢气 、 manganese triacetate 作用下， 以 乙醇 、 溶剂黄146 为溶剂， 25.0~116.0 ℃ 、344.73 kPa 条件下， 反应 23.0h， 生成 1,2-diaminodecane
  参考文献：
  名称：

  Conversion of alkenes to 1,2-diazides and 1,2-diamines

  摘要：

  DOI：

  10.1021/jo00219a049

文献信息

• Convenient Method for One-pot Preparation of 1,2-Diamines from Nitroolefins
  作者：Kiyomi Imagawa、Eiichiro Hata、Tohru Yamada、Teruaki Mukaiyama

  DOI：10.1246/cl.1996.291

  日期：1996.4

  Convenient method for preparation of 1,2-diamine from the corresponding nitroolefin was established by successive reactions of Michael addition of O-ethylhydroxylamine to nitroolefin and reduction ...

  通过O-乙基羟胺与硝基烯烃的迈克尔加成反应和还原反应，建立了由相应的硝基烯烃制备1,2-二胺的简便方法。
• MICROCAPSULES AND PRODUCTION THEREOF
  申请人：Last Klaus

  公开号：US20130137626A1

  公开（公告）日：2013-05-30

  The invention relates to microcapsules, the capsule walls of which comprise a resin that can be obtained by reacting a) at least one compound selected from the group consisting of a1) amines and a2) aromatic or heteroaromatic compounds which are unsubstituted or substituted with one or more substituents from the group consisting of C 1 -C 20 -alkyl, OH, OR, COOH, SH, SR, NHCOR, OCOR, halogen, or an aromatic compound, where R is a C 1 -C 10 -alkyl group, with b) at least one aldehydic component that contains at least two carbons atoms per molecule, in the presence of c) at least one copolymer which contains units of 2-acrylamido-2-methylpropane sulphonic acid or salts (AMPS) thereof and/or 2-acrylamido-2-methylpropane phosphonic acid or salts (AMPP) thereof and units of one or more (meth)acrylates.

  本发明涉及微胶囊，其胶囊壁包含一种树脂，该树脂可以通过以下反应获得：a)至少选择自a1)胺和a2)芳香或杂环芳香化合物中的一种，其未被取代或被取代，所述取代基从C1-C20烷基，OH，OR，COOH，SH，SR，NHCOR，OCOR，卤素或芳香化合物中选择，其中R是C1-C10烷基，与b)至少一种含有每个分子至少两个碳原子的醛类组分反应，在c)至少一种共聚物的存在下进行反应，该共聚物包含2-丙烯酰胺基-2-甲基丙磺酸或其盐（AMPS）和/或2-丙烯酰胺基-2-甲基丙磷酸或其盐（AMPP）的单元和一种或多种（甲基）丙烯酸酯单元。
• Polymers with hydrophobe bunches
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0096882A1

  公开（公告）日：1983-12-28

  A water-soluble, thermoplastic, organic polymer is disclosed having segments of bunched monovalent hydrophobic groups. These polymers provide superior thickening and leveling in aqueous systems, through micelle-like associations, and aid suspension of particulate materials in non-aqueous systems.

  本发明公开了一种水溶性热塑性有机聚合物，这种聚合物具有成串的单价疏水基团，通过胶束状结合，在水性体系中具有优异的增稠和流平效果，并有助于颗粒材料在非水性体系中的悬浮。
• Corrosion inhibited oxgenated fuel systems
  申请人：PETROLITE CORPORATION

  公开号：EP0299119A1

  公开（公告）日：1989-01-18

  This invention relates to a corrosion inhibited system comprising I An oxygenated fuel and II the reaction products of (1) an alkenyl or alkyl succinic acid or anhydride or the polymer thereof; and (2) an amine.

  本发明涉及一种缓蚀系统，包括 I 含氧燃料和 II 下列物质的反应产物 (1) 烯基或烷基丁二酸或酐或其聚合物；以及 (2) 一种胺。
• Verbesserte Mikrokapseln und ihre Herstellung
  申请人：Follmann & Co. Gesellschaft für Chemie-Werkstoffe und -Verfahrenstechnik mbH & Co. KG

  公开号：EP2364773A1

  公开（公告）日：2011-09-14

  Die Erfindung betrifft Mikrokapseln, deren Kapselwände ein Harz umfassen, welches durch Umsetzung a) mindestens einer Verbindung ausgewählt aus der Gruppe der a1) Amine und a2) aromatischen oder heteroaromatischen Verbindungen, welche unsubstituiert oder mit einem oder mehreren Substituenten aus Gruppe C1-C20-Alkyl, OH, OR, COOH, SH, SR, NHCOR, OCOR, Halogen, Aromat substituiert sind, wobei R eine C1-C10-Alkyl Gruppe darstellt, mit b) mindestens einer aldehydischen Komponente, die mindestens zwei C-Atome pro Molekül aufweist, in Gegenwart c) mindestens eines Copolymeren, welches Einheiten von 2-Acrylamido-2-methyl-propansulfonsäure oder dessen Salzen (AMPS) und/oder 2-Acrylamido-2-methyl-propanphosphonsäure oder dessen Salzen (AMPP) und Einheiten von einem oder mehreren (Meth)Acrylaten enthält, erhältlich ist.

  本发明涉及微胶囊，其囊壁由一种树脂组成，该树脂通过以下反应获得 a) 至少一种选自以下组别的化合物 a1) 胺和 a2) 未被取代或被一个或多个取代基取代的芳香族或杂芳族化合物，取代基可从以下组中 选出：C1-C20-烷基、OH、OR、COOH、SH、SR、NHCOR、OCOR、卤素、芳香族，其中 R 为 C1-C10 烷基、 与 b) 至少一种醛组分，其每个分子至少有两个碳原子，存在条件为 c) 至少一种共聚物，该共聚物含有 2-丙烯酰胺基-2-甲基丙磺酸或其盐 （AMPS）和/或 2-丙烯酰胺基-2-甲基丙膦酸或其盐（AMPP）和一种或多种 （甲基）丙烯酸酯单元、 即可获得。