1,1,8-trihydroperfluorononyl 2-hydroxyethyl ether

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,8-trihydroperfluorononyl 2-hydroxyethyl ether
• 英文别名: 2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluorononoxy)ethanol
• 化学式: C₁₁H₈F₁₆O₂
• 分子量: 476.158
• InChiKey: VAURTEQJQLFIBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  29
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  碳酸乙烯酯 、 1H,1H,9H-十六氟-1-壬醇 在 四丁基碘化铵 作用下， 反应 40.0h， 以39%的产率得到1,1,8-trihydroperfluorononyl 2-hydroxyethyl ether
  参考文献：
  名称：

  O-Hydroxyethylation of 1,1-dihydroperfluorinated alcohols

  摘要：

  A convenient transformation of 1,1-dihydroperfluorinated alcohols into O-hydroxyethyl derivatives (RFCH2OCH2CH2OH) is described in which ethylene carbonate is utilized as the alkylating agent. Tetraalkylammonium iodides and trialkylamines are effective catalysts.

  DOI：

  10.1016/s0022-1139(00)80333-4

文献信息

• OPTICAL COMPENSATORY FILM, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Yoshizawa Masataka

  公开号：US20090273740A1

  公开（公告）日：2009-11-05

  An optical compensatory film comprising an optically anisotropic layer composed of a liquid crystal composition including a liquid crystal compound, wherein the liquid crystal composition contains a copolymer including a repeating unit derived from a monomer of formula [1] and a repeating unit derived from a monomer of formula [2]: wherein R 0 represents a hydrogen atom, a halogen atom or an alkyl group, L represents a divalent linking group, and n represents an integer of 1-18; wherein R 11 represents a hydrogen atom, a halogen atom or an alkyl group, L 11 represents a divalent linking group, and R 13 , R 14 and R 15 represents a hydrocarbon group or an aromatic heterocyclic group.
• US8153246B2
  申请人：——

  公开号：US8153246B2

  公开（公告）日：2012-04-10
• O-Hydroxyethylation of 1,1-dihydroperfluorinated alcohols
  作者：S.M. Heilmann、G.J. Drtina、E.P. Janulis、L.R. Krepski、J.K. Rasmussen、S.A. Babirad、D.M. Moren、D.S. Bonham、S.V. Pathre、G.W. Greening

  DOI：10.1016/s0022-1139(00)80333-4

  日期：1992.12

  A convenient transformation of 1,1-dihydroperfluorinated alcohols into O-hydroxyethyl derivatives (RFCH2OCH2CH2OH) is described in which ethylene carbonate is utilized as the alkylating agent. Tetraalkylammonium iodides and trialkylamines are effective catalysts.