7,8,9,10-Tetrakis(4-dodecylphenyl)fluoranthene | 352532-70-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 7,8,9,10-Tetrakis(4-dodecylphenyl)fluoranthene
• 英文别名: 7,8,9,10-tetrakis(4-dodecylphenyl)fluoranthene
• CAS: 352532-70-8
• 化学式: C₈₈H₁₂₂
• 分子量: 1179.94
• InChiKey: VLXPQYNNYPSAJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  35.9
• 重原子数：
  88
• 可旋转键数：
  48
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  7,8,9,10-Tetrakis(4-dodecylphenyl)fluoranthene 在 三氯化铁 作用下， 以 硝基甲烷 、 二氯甲烷 为溶剂， 反应 0.5h， 以45%的产率得到11,16,25,30,49,54,63,68-Octadodecyltricosacyclo[41.33.2.22,5.03,39.04,36.06,35.07,20.08,13.014,19.018,23.021,34.022,27.028,33.040,77.044,73.045,58.046,51.052,57.056,61.059,72.060,65.066,71.074,78]octaconta-1,3,5,7(20),8(13),9,11,14(19),15,17,21(34),22(27),23,25,28(33),29,31,35,37,39,41,43,45(58),46(51),47,49,52(57),53,55,59(72),60(65),61,63,66(71),67,69,73,75,77,79-tetracontaene
  参考文献：
  名称：

  Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route

  摘要：

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.

  DOI：

  10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g
• 作为产物：
  描述：

  1,2-bis(4-dodecylphenyl)ethane-1,2-dione 在 氢氧化钾 作用下， 以 乙醇 、 xylene 为溶剂， 反应 16.08h， 生成 7,8,9,10-Tetrakis(4-dodecylphenyl)fluoranthene
  参考文献：
  名称：

  Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route

  摘要：

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.

  DOI：

  10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g

文献信息

• Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route
  作者：Mike Wehmeier、Manfred Wagner、Klaus Müllen

  DOI：10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g

  日期：2001.5.18

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.